Palladium(II) iodide is an inorganic compound of palladium and iodine. It is commercially available, though less common than palladium(II) chloride, the...
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Palladium(II) chloride, also known as palladium dichloride and palladous chloride, are the chemical compounds with the formula PdCl2. PdCl2 is a common...
11 KB (973 words) - 14:04, 19 April 2024
Palladium(II) acetate is a chemical compound of palladium described by the formula [Pd(O2CCH3)2]n, abbreviated [Pd(OAc)2]n. It is more reactive than the...
13 KB (1,182 words) - 13:49, 4 April 2024
Palladium(II) bromide is an inorganic compound of palladium and bromine with the chemical formula PdBr2. It is a commercially available, although less...
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Palladium(II) fluoride, also known as palladium difluoride, is the chemical compound of palladium and fluorine with the formula PdF2. PdF2 is prepared...
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13709–55–2 PdI2 palladium(II) iodide 7790–38–7 Pd(NO3)2 palladium(II) nitrate 10102–05–3 PdO palladium(II) oxide 1314–08–5 PdO2 palladium(IV) oxide 12036–04–3...
139 KB (120 words) - 17:07, 15 July 2024
Sonogashira coupling (category Palladium)
reaction used in organic synthesis to form carbon–carbon bonds. It employs a palladium catalyst as well as copper co-catalyst to form a carbon–carbon bond between...
48 KB (5,436 words) - 08:05, 6 June 2024
Copper(I) iodide is an inorganic compound with the chemical formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications...
12 KB (1,128 words) - 10:02, 6 August 2024
Organopalladium chemistry (section Palladium(II))
addition of methyl iodide to Me2Pd(II)bpy. Palladium compounds owe their reactivity to the ease of interconversion between Pd(0) and palladium(II) intermediates...
9 KB (1,043 words) - 18:27, 21 March 2024
fluoride − AmF3 Americium(IV) fluoride − AmF4 Americium(II) iodide − AmI2 Americium(III) iodide − AmI3 Americium dioxide – AmO2 Ammonia – NH3 Ammonium...
119 KB (8,734 words) - 09:23, 30 July 2024
Negishi coupling (redirect from Palladium Negishi coupling)
A palladium (0) species is generally utilized as the catalyst, though nickel is sometimes used. A variety of nickel catalysts in either Ni0 or NiII oxidation...
34 KB (3,954 words) - 20:12, 15 June 2024
the Palladium(II)-Catalyzed Decarboxylative Olefination of Arene Carboxylic Acids. Crystallographic Characterization of Non-Phosphine Palladium(II) Intermediates...
25 KB (3,056 words) - 03:04, 30 March 2022
charge of +1. Refluxing dimethyl sulfoxide with methyl iodide can yield trimethylsulfoxonium iodide. Treated with sodium hydride, trimethylsulfoxonium forms...
9 KB (647 words) - 07:50, 19 May 2024
Heck reaction (category Palladium)
potassium acetate base and palladium chloride catalysis. This work was an extension of earlier work by Fujiwara (1967) on the Pd(II)-mediated coupling of arenes...
13 KB (1,355 words) - 19:29, 15 December 2023
reaction of aryl iodides with the first-generation catalyst system. Amine ligation followed by deprotonation by base produces the palladium amide. (Chelating...
31 KB (3,483 words) - 01:36, 25 April 2024
Anhydrous copper(II) chloride adopts a distorted cadmium iodide structure. In this structure, the copper centers are octahedral. Most copper(II) compounds exhibit...
29 KB (2,701 words) - 22:07, 26 July 2024
Iodine (section Hydrogen iodide)
Ιώδης, meaning 'violet'. Iodine occurs in many oxidation states, including iodide (I−), iodate (IO− 3), and the various periodate anions. As the heaviest...
106 KB (11,790 words) - 10:37, 13 August 2024
metals or salts (sodium amalgam, aluminium amalgam, magnesium, samarium(II) iodide), tin hydrides (tributyltin hydride), or transition metal complexes with...
20 KB (2,248 words) - 12:28, 15 January 2024
Palladium hexafluoride is an inorganic chemical compound of palladium metal and fluorine with the chemical formula PdF6. It is reported to be a still...
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Reagents: base potassium carbonate, solvent NMP, catalysts palladium acetylacetonate, Copper(I) iodide, MS stands for molecular sieves, ligand phenanthroline...
23 KB (2,441 words) - 02:00, 1 August 2024
Tetramethyltin is synthesized by reaction of the Grignard reagent methylmagnesium iodide, with tin tetrachloride, which is synthesized by reacting tin metal with...
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Qian; Wang, An-Qi; Zhang, Jie-Yu (2015-08-07). "Palladium-Catalyzed Acylation/Alkenylation of Aryl Iodide: A Domino Approach Based on the Catellani–Lautens...
11 KB (1,156 words) - 20:44, 8 January 2024
Frankland prepared the first organozinc compound, diethylzinc, by heating ethyl iodide in the presence of zinc metal. This reaction produced a volatile colorless...
33 KB (3,394 words) - 06:05, 9 December 2023
Suzuki reaction (category Palladium)
Suzuki reaction or Suzuki coupling is an organic reaction that uses a palladium complex catalyst to cross-couple a boronic acid to an organohalide. It...
34 KB (3,842 words) - 03:10, 9 August 2024
Period 5 element (section Palladium)
applications. Iodine is found on Earth mainly as the highly water-soluble iodide I−, which concentrates it in oceans and brine pools. Like the other halogens...
42 KB (4,989 words) - 03:33, 15 April 2024
with palladium catalyst with high E stereoselectivity. They observed using sterically bulky ligands gave higher regioselectivity for β-vinyl iodide. The...
28 KB (3,003 words) - 02:54, 18 December 2023
In combination with CrCl2 for the coupling of an aldehyde and a vinylic iodide to give allylic alcohols. For selective reductions in the presence of LiAlH4...
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Stille reaction (category Palladium)
amination, another palladium-catalyzed coupling reaction, followed by an intramolecular Stille-Kelly coupling. Note that the aryl-iodide bond will oxidatively...
47 KB (5,491 words) - 13:23, 22 February 2024
metals, notably samarium(II) iodide, chromium(II) chloride, titanium(II) chloride, cerium(III) halides such as cerium(III) iodide, and titanocene(III) chloride...
13 KB (1,269 words) - 19:55, 31 October 2023
Thiocyanate (section Test for iron(III) and cobalt(II))
of the thyroid sodium-iodide symporter. Iodine is an essential component of thyroxine. Since thiocyanates will decrease iodide transport into the thyroid...
15 KB (1,505 words) - 21:05, 20 June 2024