Schwartz's reagent is the common name for the organozirconium compound with the formula (C5H5)2ZrHCl, sometimes called zirconocene hydrochloride or zirconocene...

methylene chloride converts it to Schwartz's reagent. Zirconocene dichloride can also be used to prepare the Negishi reagent, Cp2Zr(η2-butene), which can be...

with triethylamine. In 1970, the related hydrochloride (now called Schwartz's reagent) was obtained by reduction of zirconacene dichloride (Cp2ZrCl2) with...

Early metal metallocene derivatives, e.g. Tebbe's reagent, Petasis reagent, and Schwartz's reagent are useful in specialized organic synthetic operations...

LiAlH4 → RCHO + HNRR' With further reduction the alcohol is obtained. Schwartz's reagent reduces amides to aldehydes, and so does hydrosilylation with a suitable...

involve redox at the metal centres. Bent metallocenes Tebbe's reagent Schwartz's reagent. Ansa-metallocene, X is the linker group, often (CH2)n or R2Si...

Birmingham and Wilkinson, was the first organozirconium compound. Schwartz's reagent, prepared in 1970 by P. C. Wailes and H. Weigold, is a metallocene...

(CODRh(PPh3)2+) Schultze reagent (KClO3 / HNO3) Schweinfurter Green (Cu(OAc)2·3Cu(AsO2)2) Schwartz's reagent (Cp2Zr(H)Cl) Schweizer's reagent ([Cu(NH3)4(H2O)2](OH)2)...

afford zirconocene chloride hydride (Schwartz's reagent). Alkenes undergo hydrozirconation in the presence of this reagent, affording functionalized products...

transitions. Examples: titanium tetrachloride, titanocene dichloride, Schwartz's reagent. d1 Examples: molybdenum(V) chloride, vanadyl acetylacetonate, vanadocene...

semisynthesis consists of conversion of the amide group to an amine with Schwartz's reagent through an imine followed by acidic workup and a benzoylation. In...

this method, porphobilinogen is detected by a color reaction with Ehrlich reagent and confirming that the color is not removed by chloroform. As the test...

ZrBr4 Zirconium(IV) iodide – ZrI4 Zirconium(IV) hydroxide – Zr(OH)4 Schwartz's reagent – C10H11ClZr Zirconium propionate – Zr(CH3CH2COO)4 Zirconium tungstate...

tin-methyl bond. A modified synthesis of atrane tricycle utilizes Schwartz's Reagent, triallylamine, and tin(IV) chloride in a one-pot method. Though the...

finds application in papermaking and dye industries. It is also used as a reagent in organic synthesis. The compound was discovered in the 1940s by H. I...

is added to a mixture of methanol with red phosphorus. The iodinating reagent is phosphorus triiodide that is formed in situ: 3 CH3OH + PI3 → 3 CH3I...

odiferous oil, it is a reagent used as a protected thiol. Atwal, Karnail S.; Rovnyak, George C.; O'Reilly, Brian C.; Schwartz, Joseph (1989). "Substituted...

substrates. Silanization mechanisms vary with substrate and with silanization reagent. In the usual circumstance, surface MOH groups react as nucleophiles with...

Phenol oxidation with hypervalent iodine reagents leads to the formation of quinone-type products or iodonium ylides, depending on the structure of the...

of Reagents for Organic Synthesis, 2007, John Wiley & Sons.doi:10.1002/047084289X.rs112.pub2 Chu Sun, Masami Okabe, David L. Coffen, Jeffrey Schwartz "Conjugate...

complexes arise by treating trialkyltantalum dichloride with alkyl lithium reagents. This reaction initially forms a thermally unstable tetraalkyl-monochloro-tantalum...

cooling and reacting with various reagents in a sequence of hydrometalurgical processing steps. Suitable extraction reagents include alkali metal sulfates...

applications; it has been employed as a fluorination and desilylation reagent in organic synthesis and in aqueous solution as a topical caries treatment...

boron- and phosphorus-containing compounds, respectively, into important reagents in organic synthesis" 1976 William Lipscomb Cleveland, Ohio, US "for his...

majority of PCR methods rely on thermal cycling. Thermal cycling exposes reagents to repeated cycles of heating and cooling to permit different temperature-dependent...

Mülmenstädt J, Neubauer D, Possner A, Rugenstein M, Sato Y, Schulz M, Schwartz SE, Sourdeval O, Storelvmo T, Toll V, Winker D, Stevens B (November 1,...

then preparing the appropriate Grignard reagent. Triethyl orthoformate is treated with this Grignard reagent, then hydrolyzed to give 6-nonenal. Hong...

research due to the cost and toxicity of beryllium, beryllium derivatives and reagents required for the introduction of beryllium, such as beryllium chloride...

can be produced by protonation of methyl lithium or a methyl Grignard reagent such as methylmagnesium chloride. It can also be made from anhydrous sodium...

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