intermediates or transition states. For certain nucleophiles, solvolysis reactions are classified. Solvolysis involving water is called hydrolysis. Related terms...

substitution reactions at secondary carbons: Many reactions studied are solvolysis reactions where a solvent molecule (often an alcohol) is the nucleophile...

have been generated in photochemical solvolysis reactions. The figure to the right depicts photochemical solvolysis of vinyl iodonium salt, through heterolytic...

Grunwald, E.; Jones, H.W. (1951). "The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions into Mechanistic Categories". J. Am. Chem...

VX with concentrated aqueous sodium hydroxide results in two competing solvolysis reactions: cleavage of either the P–O or P–S esters. Although the P–S...

also act as nucleophiles, and the process is known as solvolysis. The Y scale correlates solvolysis reaction rates of any solvent (k) with that of a standard...

Young, D. J. Cram (1951). "The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions Into Mechanistic Categories". Journal...

Polymer degradation Proteolysis Saponification Sol–gel polymerisation Solvolysis Thermal hydrolysis IUPAC, Compendium of Chemical Terminology, 2nd ed....

demonstrated a solvolysis reaction of the hexafluorophosphate ion. The tris(solvent) rhodium complex [(η5-C5Me5)Rh(Me2CO)3](PF6)2 undergoes solvolysis when heated...

hexafluorophosphate ion is generally inert and hence a suitable counterion, its solvolysis can be induced by highly electrophilic metal centers. For example, the...

7-norbornenyl tosylate. The elimination occurs 1011 times faster than the solvolysis of anti-7-norbornyl p-toluenesulfonate. Tosylates are also protecting...

This generally occurs in highly polar solvents through a process called solvolysis. The positively charged component then reacts with a nucleophile forming...

process is referred to as solvolysis. The thermodynamic concept of solubility does not apply straightforwardly to solvolysis. When a solute dissolves,...

expulsion of a leaving group to form a nitrilium ion. This is followed by solvolysis to an imidate and then tautomerization to the amide: This nitrilium ion...

nucleophilic reactions with solvents such as alcohols and water are named solvolysis. Nucleophiles may take part in nucleophilic substitution, whereby a nucleophile...

azides and water. The very stable triphenylmethyl carbocation derived from solvolysis of the corresponding triphenylmethyl chloride reacts 100 times faster...

solution: Ph3SnCl + HCl ⟶ Ph2SnCl2 + PhH (solvolysis) Ph3COH + 3 HCl ⟶ Ph 3C+ HCl− 2 + H3O+Cl− (solvolysis) Me 4N+ HCl− 2 + BCl3 ⟶ Me 4N+ BCl− 4 + HCl...

solvent-shared ion pair results. The ion pair concept explains stereochemistry in solvolysis. The concept of intimate ion pairs is used to explain the slight tendency...

unsaturated tosylate will react more quickly (1011 times faster for aqueous solvolysis) with a nucleophile than the saturated tosylate. The carbocationic intermediate...

Scientific career Fields Chemistry Institutions University of Tokyo NAIST Toyohashi Tech Thesis Deuterium isotope effects in solvolysis reactions  (1983)...

carbon atom. Part XXIII. A kinetic demonstration of the unimolecular solvolysis of alkyl halides. (Section E) a general discussion". Journal of the Chemical...

Kochi, Jay Kazuo (1952). The application of the Hammett equation to the solvolysis of benzyl tosylates (Ph.D.). Iowa State University. OCLC 908156744 – via...

H. H. Zeiss, he proposed the Doering-Zeiss mechanistic hypothesis for solvolysis reactions. He first articulated the notion that cyclic systems with (4n...

p-TsCl, DMAP, and pyridine (90% yield). The tosylate 2 then undergoes solvolysis as it is treated with pyridine and anhydrous MeOH to give a 5:1 ratio...

Singleton A (February 2005). "Isotope effects, dynamics, and the mechanism of solvolysis of aryldiazonium cations in water". Journal of the American Chemical Society...

difficulty in dealing with simultaneous hydrolysis. With alcohols, partial solvolysis may occur. UCl4 + xROH ⇌ UCl4−x(OR)x + xHCl Uranium tetrachloride dissolves...

ion locked in a designed cage structure by Lectka and coworkers. Recent solvolysis experiments and NMR spectroscopic studies on a metastable [C–F–C]+ fluoronium...

esters and amides can also be completely depolymerized by hydrolysis or solvolysis; this can be a purely chemical process but may also be promoted by enzymes...

the 2-norbornyl cation through this route as an intermediate towards solvolysis. The starting material for this route is a β-(Δ3-cyclopentenyl)-ethane...

calculations of isotope effects in model processes of neopentyl ester solvolysis". The Journal of Organic Chemistry. 49 (4): 631–635. doi:10.1021/jo00178a010...