• Swarts fluorination is a process whereby the chlorine atoms in a compound – generally an organic compound, but experiments have been performed using silanes...
    2 KB (233 words) - 04:42, 23 December 2023
  • Thumbnail for Antimony trifluoride
    hydrolyzing slowly in water. With fluorine, it is oxidized to give antimony pentafluoride. SbF3 + F2 → SbF5 It is used as a fluorination reagent in organic chemistry...
    6 KB (459 words) - 05:43, 18 February 2024
  • Thumbnail for Fluorine
    Swarts fluorination, in which chlorocarbon chlorines are substituted for fluorines by hydrogen fluoride under catalysts. Electrochemical fluorination subjects...
    157 KB (15,331 words) - 01:54, 3 November 2024
  • Thumbnail for Trifluoroacetic acid
    potassium permanganate. The trifluorotrichloropropene can be prepared by Swarts fluorination of hexachloropropene. TFA is the precursor to many other fluorinated...
    15 KB (1,305 words) - 05:53, 1 November 2024
  • Thumbnail for Thiophosgene
    photodimer, an example of a 1,3-dithietane, is a colourless solid. Swarts fluorination of the dimer and then cracking is the principal route to thiocarbonyl...
    7 KB (536 words) - 00:15, 4 November 2024
  • Theodore Swarts (chemist, *1839 Antwerpen; †1911 Kortenberg, Belgium) and a colleague of Leo Baekeland. Kauffman, George B. (1955). "Frederic Swarts: Pioneer...
    2 KB (170 words) - 05:07, 22 May 2023
  • on the degree and regiochemistry of fluorination sought and the nature of the precursors. The direct fluorination of hydrocarbons with F2, often diluted...
    41 KB (4,534 words) - 14:34, 22 September 2024
  • Thumbnail for Bromofluoromethane
    debromination with a Swarts reagent. From a dihalomethane by an halogen exchange reaction or from a halomethane by catalyzed bromination or fluorination. The method...
    3 KB (202 words) - 13:09, 7 September 2024
  • Thumbnail for Trifluoromethyl group
    compounds by treatment with antimony trifluoride/antimony pentachloride (the Swarts reaction). Another route to trifluoromethyl aromatics is the reaction of...
    4 KB (417 words) - 12:19, 6 August 2024
  • Thumbnail for Vinyl fluoride
    prepared in 1901 by Frédéric Swarts, the Belgian chemist who was the first to prepare chlorofluorocarbons in 1892. Swarts used the reaction of zinc with...
    4 KB (243 words) - 19:58, 29 October 2024
  • Thumbnail for Trifluoroacetonitrile
    carbon tetrachloride. This synthesis route was first described by Frédéric Swarts in 1922. Trifluoroacetonitrile can also be produced by reacting 1,1,1-trichloro-2...
    3 KB (278 words) - 13:20, 25 November 2021
  • Einhorn–Brunner reaction Elbs persulfate oxidation Elbs reaction Electrochemical fluorination Electrocyclic reaction Electrophilic halogenation Electrophilic amination...
    37 KB (3,419 words) - 11:08, 19 October 2024
  • Thumbnail for Mercury(I) fluoride
    hydrofluoric acid: Hg2F2 + H2O → Hg + HgO + 2 HF It can be used in the Swarts reaction to convert alkyl halides into alkyl fluorides: 2 R-X + Hg2F2 →...
    5 KB (316 words) - 08:38, 12 July 2024
  • Thumbnail for Bromotrifluoroethylene
    CF2CHBr + KBr + H2O}}} It was first prepared by the Belgian chemist Frédéric Swarts in 1899. Bromotrifluoroethylene forms metal complexes with substituted phosphine...
    3 KB (282 words) - 20:33, 1 November 2024
  • review appeared in 1958. An early synthetic method was developed by Frédéric Swarts in 1892, based on antimony fluoride. In this reaction benzotrichloride was...
    43 KB (4,064 words) - 06:38, 27 April 2024
  • Thumbnail for Hydrogen bond
    acceptor atoms are the period 2 elements nitrogen (N), oxygen (O), and fluorine (F). Hydrogen bonds can be intermolecular (occurring between separate molecules)...
    46 KB (5,459 words) - 23:38, 3 October 2024
  • Thumbnail for Molecule
    Heijden, Nadine J.; Ondráček, Martin; Van Der Lit, Joost; Mutombo, Pingo; Swart, Ingmar; Jelínek, Pavel (2016). "Mapping the electrostatic force field of...
    33 KB (3,694 words) - 15:30, 1 November 2024
  • doi:10.1002/(SICI)1521-3749(199910)625:10<1599::AID-ZAAC1599>3.0.CO;2-J. Swart E.R. (1964). "The direct conversion of wood charcoal to lithium carbide...
    8 KB (770 words) - 10:55, 31 July 2024
  • Trifluorides are compounds in which one atom or ion has three fluorine atoms or ions associated. Many metals form trifluorides, such as iron, the rare-earth...
    4 KB (372 words) - 07:56, 17 January 2024
  • Thumbnail for Methyl fluoroacetate
    substance. MFA was first synthesized in 1896 by the Belgian chemist Frédéric Swarts by reacting methyl iodoacetate with silver fluoride. It can also be synthesized...
    18 KB (2,344 words) - 02:22, 5 June 2024
  • Thumbnail for List of nominees for the Nobel Prize in Chemistry
    April 2020. Retrieved 11 November 2020. "Nomination Archive – Frédéric Swarts". NobelPrize.org. April 2020. Retrieved 11 November 2020. "Nomination Archive...
    358 KB (12,268 words) - 05:53, 4 November 2024
  • Journal. 366: 412–421. Bibcode:1991ApJ...366..412G. doi:10.1086/169575. de Swart, J. G.; Bertone, G.; van Dongen, J. (2017). "How dark matter came to matter"...
    45 KB (5,434 words) - 18:27, 2 November 2024