Thermodynamic reaction control or kinetic reaction control in a chemical reaction can decide the composition in a reaction product mixture when competing...

all chemical reactions, the unimolecular decomposition of ions is subject to thermodynamic versus kinetic reaction control: the kinetic product forms...

phenoxide anions is kinetically favored, while carbon-attack is thermodynamically preferred (see Thermodynamic versus kinetic reaction control). Mixed oxygen/carbon...

prevails, this can be rationalised as exhibiting classic thermodynamic versus kinetic reaction control as the ortho product can form a more stable bidentate...

kelvin was defined in thermodynamic terms, but nowadays, as mentioned above, it is defined in terms of kinetic theory. The thermodynamic temperature is said...

gained is positive. In a natural thermodynamic process, the work done by an agency in the surroundings of a thermodynamic system or working body is greater...

of the desired product. A continuous reaction calorimeter is a similar instrument used to obtain thermodynamic information on continuous processes in...

state) might also be termed "kinetically persistent" if it is changing relatively slowly (and thus is not at thermodynamic equilibrium, but is observed...

This control is instrumental in enabling the exploitation of differences in reaction rates of the different species (see Thermodynamic versus kinetic reaction...

take place: the kinetic regime, where the crystal growth is controlled by minimization of the volume free energy, and the thermodynamic regime, where growth...

intermediates. Reactions can proceed along kinetic or thermodynamic pathways. Initial concentrations of kinetic intermediates are greater than thermodynamic products...

resulting in loss of particle kinetic energy. Stopping power is also interpreted as the rate at which a material absorbs the kinetic energy of a charged particle...

In thermodynamic terms, metabolism maintains order by creating disorder. As the environments of most organisms are constantly changing, the reactions of...

considered kinetically frozen. This means that none of the relaxation processes, which would drive the micelle solution towards thermodynamic equilibrium...

second law. Classical thermodynamic theory does not deal with these statistical variations. The first mechanical argument of the Kinetic theory of gases that...

thermodynamic versus kinetic control to influence reaction products. The study of chemical kinetics is used to determine the rate law for a reaction....

value lies in its tremendous internal energy that can be used for kinetic reaction through mechanical expansion against turbine blades and reciprocating...

redox reaction can be assigned to diffusion. Many redox processes observed by CV are quasi-reversible or non-reversible. In such cases the thermodynamic potential...

entropy is more "real" than temperature itself (see Thermodynamic temperature). Microscopic kinetic fluctuations among particles cause entropic loss, and...

Autochem or Kinetic PreProcessor). In this approach a set of constituents are chosen and the automatic code generator will then select the reactions involving...

ISBN 978-0-08-037941-8. Andrei Rotaru (2017): "Thermal and kinetic study of hexagonal boric acid versus triclinic boric acid in air flow." Journal of Thermal...

between the terms thermodynamically stable and kinetically stable by referring to the former as "inert." Contrarily, a kinetically unstable substance...

substituted product in thermodynamically controlled E1 reactions, it is known as Zaitsev's rule, although in many cases the kinetic product also follows...

functionalization of a primary alkane bond is due to the formation of a kinetically and thermodynamically favorable primary alkyl-metal complex over formation of a...

origins of methane. When methane clumped-isotope composition is controlled by kinetic effects, for example, for microbial methane, it has the potential...

quell the radical-mediated ring-opening of an otherwise kinetically stable but thermodynamically strained molecule via the corset effect. As of 2023, the...

the stereochemistry and activation energy of pericyclic reactions, an important class of reactions in organic chemistry. The rules originate in certain symmetries...

nanoparticles and kinetic growth factors. The temperature, gas environment and chemisorption can play an important role in both their thermodynamic stability...

selected to allow sufficient time and thermodynamic driving force for diffusion into the polymer and reaction with the functional groups left by the...

does not contain explosives, instead relying on the projectile's high kinetic energy to inflict damage. The railgun uses a pair of parallel conductors...