Titanocene Y also known as bis[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dichloride or dichloridobis(η5-(p-methoxybenzyl)cyclopentadienyl)titanium...

Titanocene dichloride is the organotitanium compound with the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common reagent...

and reduction of aldehydes. Cp2Ti(CO)2 is prepared by the reduction of titanocene dichloride with magnesium as a slurry in THT under an atmosphere of carbon...

Titanocene pentasulfide is the organotitanium compound with the formula (C5H5)2TiS5, commonly abbreviated as Cp2TiS5. This metallocene exists as a bright...

obtained. Synthesizing Rosenthal's reagent of a titanocene source yields golden-yellow crystals of the titanocene bis(trimethylsilyl)acetylene complex with...

chemistry, is an aluminium-containing derivative of titanocene that arises from the reaction of titanocene dichloride with trimethylaluminium. It is used for...

with polysulfur dichloride: H2Sx + SyCl2 → cyclo-Sx+y + 2 HCl A second strategy uses titanocene pentasulfide as a source of the S2−5 unit. This complex...

alkylated via salt metathesis reactions. Illustrative is the methylation of titanocene dichloride to give the Petasis reagent: (C5H5)2TiCl2 + 2 ClMgCH3 → (C5H5)2Ti(CH3)2...

metathesis reaction of methylmagnesium chloride or methyllithium with titanocene dichloride: Cp2TiCl2 + 2 CH3MgCl → Cp2Ti(CH3)2 + 2 MgCl2 This compound...

activated by treatment with trimethylaluminium. Kaminsky discovered that titanocene and related complexes emulated some aspects of these Ziegler–Natta catalysts...

for the methylenation of esters and ketones, is prepared from TMA and titanocene dichloride. In combination with 20 to 100 mol % Cp2ZrCl2 (zirconocene...

(or the LiBH4) on the corresponding metal halide. One example is the titanocene derivative: 2 (C5H5)2TiCl2 + 4 NaBH4 → 2 (C5H5)2TiBH4 + 4 NaCl + B2H6...

metallocene catalysts have the composition Cp2MCl2 (M = Ti, Zr, Hf) such as titanocene dichloride. Typically, the organic ligands are derivatives of cyclopentadienyl...

(Ti) and a main group metal (Al). The Tebbe reagent is synthesized from titanocene dichloride and trimethylaluminium in toluene solution. Cp2TiCl2 + 2 Al(CH3)3...

developed a light-driven "closed cycle of water splitting using ansa-titanocene(III/IV) triflate complexes". An Indium gallium nitride (InxGa1-xN) photocatalyst...

variants were initially examined with zirconocene bis(amido) complexes. Titanocene amido and sulfonamido complexes catalyze the intra-molecular hydroamination...

rings engage in degenerate ring flipping. One well-studied example is titanocene pentasulfide, where the inversion barrier is high relative to cyclohexane's...

reported in 1955 by Geoffrey Wilkinson It is commonly prepared by reducing titanocene dichloride with zinc, manganese, or magnesium. For use in organic synthesis...

related (Ph3P)2Ni(CH2)4. Another example of a metallacyclopentane is the titanocene derivative Cp2Ti(CH2)4. Metallacyclopentanes are intermediates in the...

(η5-C5H5)2VCl2 (commonly abbreviated as Cp2VCl2). It is a structural analogue of titanocene dichloride but with vanadium(IV) instead of titanium(IV). This compound...

sheet (SDS) CAMEO Chemicals MSDS Related compounds Related compounds Titanocene dichloride Hafnocene dichloride Vanadocene dichloride Niobocene dichloride...

adopts a piano stool geometry. (C5H5)TiCl3 is prepared by the reaction of titanocene dichloride and titanium tetrachloride: (C5H5)2TiCl2 + TiCl4 → 2 (C5H5)TiCl3...

to the lack of d to d transitions. Examples: titanium tetrachloride, titanocene dichloride, Schwartz's reagent. d1 Examples: molybdenum(V) chloride, vanadyl...

disulfides oxidize low valence metals, as illustrated by the oxidation of titanocene dicarbonyl: (C5H5)2Ti(CO)2 + (C6H5S)2 → (C5H5)2Ti(SC6H5)2 + 2 CO Some...

(Me = CH3, Ph = C6H5). Another example is the metalacycle derived from titanocene dichloride, (C5H5)2Ti(SiPh2)5. Transition metal silane complexes are coordination...

Closely related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride or vanadocene dichloride. Certain metallocenes and their derivatives...

thermal reaction: Pt(η2-C2H4)(PPh3)2 + C60 → Pt(η2-C60)(PPh3)2 + C2H4 Titanocene complexes have also been reported: (η5-Cp)2Ti(η2-(CH3)3SiC≡CSi(CH3)3)...

Leijun; Samuel, Edmond (1997). "Preparation and characterization of titanocene silyl hydrides [Cp2Ti(μ-HSiH2)]2 and [Cp2Ti(μ-HSiH2)(μ-H)TiCp2]". Chemical...

V.; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke (2003). "The Titanocene Complex of Bis(trimethylsilyl)acetylene: Synthesis, Structure, and Chemistry†"...

have been intensively studied. The most common organotitanium complex is titanocene dichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and...