A transition metal oxo complex is a coordination complex containing an oxo ligand. Formally O2-, an oxo ligand can be bound to one or more metal centers...

hemoglobin, hemerythrin, and hemocyanin. Several transition metals form complexes with O2, and many of these complexes form reversibly. The binding of O2 is the...

include ketones and many related carbonyl compounds. For the transition metals, many oxo complexes are known as well as oxyhalides. The chemical formulas of...

Metal carbonyls are coordination complexes of transition metals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...

Transition metal carboxylate complexes are coordination complexes with carboxylate (RCO2−) ligands. Reflecting the diversity of carboxylic acids, the...

scholarly and practical interest. transition metal carbene complexes catalyze the olefin metathesis reaction. Metal oxo intermediates are pervasive in oxidation...

Potassium permanganate is the potassium salt of the tetrahedral transition metal oxo complex permanganate, in which four O2− ligands are bound to a manganese(VII)...

and Bi. Many of their crystal structures have been determined. Transition metal oxo complex Synthesis of individual compounds can be found in Housecroft...

In chemistry, metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant species...

Transition metal porphyrin complexes are a family of coordination complexes of the conjugate base of porphyrins. Iron porphyrin complexes occur widely...

ligands. Commonly metal-imido complexes are generated from metal oxo complexes. They arise by condensation of amines and metal oxides and metal halides: LnMO...

A transition metal alkoxide complex is a kind of coordination complex containing one or more alkoxide ligands, written as RO−, where R is the organic...

Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds...

In organic chemistry, hydroformylation, also known as oxo synthesis or oxo process, is an industrial process for the production of aldehydes (R−CH=O) from...

that is used in the production of biodiesel. Many metal alkoxide compounds also feature oxo-ligands. Oxo-ligands typically arise via the hydrolysis, often...

the solid state. Oxo bridges tend to occur when the metal oxidation state is high. An example is provided by the molybdenum(IV) complex [Mo3O4(H2O)9]4+...

A transition metal phosphido complex is a coordination complex containing a phosphido ligand (R2P, where R = H, organic substituent). With two lone pairs...

copper(II) complexes oxidized H2. The 1960s witnessed the development of well defined homogeneous catalysts using transition metal complexes, e.g., Wilkinson's...

of nonbonding electrons on the oxo ligands to empty d-levels on the metal. For heavier metals, these same transitions occur in the UV region, hence no...

Some metals, e.g. V, Cr, Nb, Ta, Mo, W, tend to exist in high oxidation states. Rather than forming hydroxides in aqueous solution, they convert to oxo clusters...

A metal carbido complex is a coordination complex that contains a carbon atom as a ligand. They are analogous to metal nitrido complexes. Carbido complexes...

necessary, without the inevitable oxidation (breaking down) of everything. Transition metal ions, due to their multiple oxidation states, were the only elements...

probe this phenomenon. Since the Snyder case, many other complexes of later transition metals have been shown to display inverted ligand field through...

functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...

1W5C, 1ILX, 1FE1, 1IZL. The oxygen-evolving complex is the site of water oxidation. It is a metallo-oxo cluster comprising four manganese ions (in oxidation...

of three or more transition metal oxyanions linked together by shared oxygen atoms to form closed 3-dimensional frameworks. The metal atoms are usually...

Mediated by Transition Metal Ions and Their Complexes". In Sigel A, Sigel H, Sigel RK (eds.). Interplay between Metal Ions and Nucleic Acids. Metal Ions in...

involving the replacement of an oxo group by two hydrogen atoms (A=O → AH2) are hydrogenolysis. Typical examples use metal catalysts and H2 as the reagent...

rate (speed of water ligands attaching and detaching) for any transition metal aquo complex. Adding aqueous sodium hydroxide causes the precipitation of...

structure, the complex is five-coordinate with idealized C4v point group symmetry. It is one of more common transition metal porphyrin complexes. Fe(TPP)Cl...