A tridentate ligand (or terdentate ligand) is a ligand that has three atoms that can function as donor atoms in a coordination complex. Well-known tridentate...
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and three sites as tridentate. The "bite angle" refers to the angle between the two bonds of a bidentate chelate. Chelating ligands are commonly formed...
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In coordination chemistry, a scorpionate ligand is a tridentate (three-donor-site) ligand that binds to a central atom in a fac manner. The most popular...
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Denticity (redirect from Monodentate ligand)
example being ethylenediamine. Tridentate ligands bind with three atoms, an example being terpyridine. Tridentate ligands usually bind via two kinds of...
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imino group as the name suggests). The iminodiacetate dianion is a tridentate ligand, forming metal complexes by forming two, fused, five membered chelate...
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anionic tridentate ligand based on three imidazole-2-thioketone groups bonded to a borohydride center. They are examples of scorpionate ligands. Various...
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PMDTA (category Tridentate ligands)
formula [(CH3)2NCH2CH2]2NCH3. PMDTA is a basic, bulky, and flexible, tridentate ligand that is a used in organolithium chemistry. It is a colorless liquid...
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Cis,cis-1,3,5-Triaminocyclohexane (category Tripodal ligands)
because it is a common tripodal ligand, abbreviated as tach. It is a colorless oil. It is a popular tridentate ligand in coordination chemistry. It is...
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Turing machine, a hypothetical universal computing machine Tm ligands, a tridentate ligand used in coordination chemistry Melting point (abbreviated Tm)...
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Transition metal pincer complex (redirect from Pincher ligand)
ligand is POCOP. Many tridentate ligands types occupy three contiguous, coplanar coordination sites. The most famous such ligand is terpyridine (“terpy”)...
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Asymmetric hydrogenation (section Ligand classes)
and ee up to 99.9%) is an iridium(I) system with a closely related tridentate ligand. Highly effective system for the asymmetric hydrogenation of ketones...
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the ligand that has the bend. If three donor atoms are the same at one end of the chain, the mer- and fac- prefixes used for tridentate ligands can be...
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natural copper minerals, chanabayaite and triazolite. Trizolate is a tridentate ligand, and can form complexes with metals via the three nitrogen atoms....
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class of ligands known as scorpionate. Pyrazole itself reacts with potassium borohydride at high temperatures (~200 °C) to form a tridentate ligand known...
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Bis(diphenylphosphinoethyl)phenylphosphine (category Tridentate ligands)
(Ph = C6H5). It is an air-sensitive white solid that function as tridentate ligands in coordination and organometallic chemistry. It is prepared by the...
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acid, IDA, which is a tridentate ligand. Further substitution gives nitrilotriacetic acid, NTA, which is a tetradentate ligand. These compounds can be...
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designed by choosing ligands which have specific stereochemical requirements. For example, terpyridine, which is a tridentate ligand forms the complex [Zn(terpy)Cl2]...
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Metal–organic framework (section Ligand exchange)
tridentate amide linkers and cadmium salt catalyzes the Knoevenagel condensation reaction. The pyridine groups on the ligand 4-BTAPA act as ligands binding...
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aza-crowns and their complexes 1,4,7-Trimethyl-1,4,7-triazacyclononane, a tridentate ligand used in coordination chemistry. Cyclam is a tetraaza crown ether with...
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groups forming crosslinks. In coordination chemistry, it serves as a tridentate ligand forming complexes such as Co(dien)(NO2)3. Like some related amines...
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affinities for transition metals. 1,4,7-Trithiacyclononane (9-ane-S3) is a tridentate ligand and forms complexes with many metal ions, including those considered...
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1,4,7-Triazacyclononane (category Tridentate ligands)
[(CH2CH2N(Ts)]3 + 3 H2O → [CH2CH2NH]3 + 3 HOTs TACN is a popular tridentate ligand. It is threefold symmetric and binds to one face of an octahedron...
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It can be prepared from bis-triazinyl pyridine. Terpyridine is a tridentate ligand that binds metals at three meridional sites giving two adjacent 5-membered...
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(CH2CH2S)3. This cyclic thioether is most often encountered as a tridentate ligand in coordination chemistry, where it forms transition metal thioether...
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bi- and tridentate bis(oxazoline) ligands are used in organic synthesis Both enantiomers of BINAP BINOL, another binaphthalene-based ligand TADDOL DIPAMP...
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Ni(P(OMe)3)4 (m.p. 108 °C). The tridentate ligand called the Kläui ligand is derived from trimethyl phosphite. The formation of this ligand illustrates the susceptibility...
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Tris(2-aminoethyl)amine (redirect from Tripod ligand)
possible, four of which are chiral. In a few cases, tren serves as a tridentate ligand with one of the primary amine groups non-coordinated. Tren is a common...
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iodosobenzene diacetate. The gold catalyst is based on a terpyridine tridentate ligand. Yudin, Andrei K., ed. (2007). Aziridines and Epoxides in Organic...
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secondary amine with two picolyl substituents. The compound is a common tridentate ligand in coordination chemistry. The compound can be prepared by many methods...
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7-triazaheptane) is a tridentate ligand and en is bidentate. The number of chelate rings is one less than the number of donor atoms in the ligand. EDTA...
60 KB (7,604 words) - 21:10, 31 July 2024