• Thumbnail for Tridentate ligand
    A tridentate ligand (or terdentate ligand) is a ligand that has three atoms that can function as donor atoms in a coordination complex. Well-known tridentate...
    4 KB (201 words) - 12:52, 16 October 2023
  • Thumbnail for Ligand
    and three sites as tridentate. The "bite angle" refers to the angle between the two bonds of a bidentate chelate. Chelating ligands are commonly formed...
    35 KB (3,307 words) - 12:53, 22 September 2024
  • Thumbnail for Scorpionate ligand
    In coordination chemistry, a scorpionate ligand is a tridentate (three-donor-site) ligand that binds to a central atom in a fac manner. The most popular...
    11 KB (1,281 words) - 22:02, 19 July 2024
  • Thumbnail for Denticity
    Denticity (redirect from Monodentate ligand)
    example being ethylenediamine. Tridentate ligands bind with three atoms, an example being terpyridine. Tridentate ligands usually bind via two kinds of...
    5 KB (669 words) - 11:37, 1 October 2024
  • Thumbnail for Iminodiacetic acid
    imino group as the name suggests). The iminodiacetate dianion is a tridentate ligand, forming metal complexes by forming two, fused, five membered chelate...
    5 KB (371 words) - 14:28, 7 July 2024
  • anionic tridentate ligand based on three imidazole-2-thioketone groups bonded to a borohydride center. They are examples of scorpionate ligands. Various...
    4 KB (402 words) - 12:47, 4 April 2023
  • Thumbnail for PMDTA
    PMDTA (category Tridentate ligands)
    formula [(CH3)2NCH2CH2]2NCH3. PMDTA is a basic, bulky, and flexible, tridentate ligand that is a used in organolithium chemistry. It is a colorless liquid...
    7 KB (536 words) - 20:14, 28 June 2023
  • Thumbnail for Cis,cis-1,3,5-Triaminocyclohexane
    Cis,cis-1,3,5-Triaminocyclohexane (category Tripodal ligands)
    because it is a common tripodal ligand, abbreviated as tach. It is a colorless oil. It is a popular tridentate ligand in coordination chemistry. It is...
    3 KB (190 words) - 17:59, 5 November 2021
  • Turing machine, a hypothetical universal computing machine Tm ligands, a tridentate ligand used in coordination chemistry Melting point (abbreviated Tm)...
    3 KB (412 words) - 01:19, 2 May 2024
  • Thumbnail for Transition metal pincer complex
    ligand is POCOP. Many tridentate ligands types occupy three contiguous, coplanar coordination sites. The most famous such ligand is terpyridine (“terpy”)...
    15 KB (1,768 words) - 23:49, 20 December 2023
  • and ee up to 99.9%) is an iridium(I) system with a closely related tridentate ligand. Highly effective system for the asymmetric hydrogenation of ketones...
    64 KB (6,355 words) - 10:03, 21 August 2024
  • the ligand that has the bend. If three donor atoms are the same at one end of the chain, the mer- and fac- prefixes used for tridentate ligands can be...
    21 KB (1,858 words) - 07:47, 8 September 2024
  • natural copper minerals, chanabayaite and triazolite. Trizolate is a tridentate ligand, and can form complexes with metals via the three nitrogen atoms....
    2 KB (193 words) - 14:05, 19 June 2024
  • class of ligands known as scorpionate. Pyrazole itself reacts with potassium borohydride at high temperatures (~200 °C) to form a tridentate ligand known...
    13 KB (1,104 words) - 06:57, 28 October 2024
  • Thumbnail for Bis(diphenylphosphinoethyl)phenylphosphine
    Bis(diphenylphosphinoethyl)phenylphosphine (category Tridentate ligands)
    (Ph = C6H5). It is an air-sensitive white solid that function as tridentate ligands in coordination and organometallic chemistry. It is prepared by the...
    3 KB (169 words) - 22:50, 7 May 2023
  • Thumbnail for Aminopolycarboxylic acid
    acid, IDA, which is a tridentate ligand. Further substitution gives nitrilotriacetic acid, NTA, which is a tetradentate ligand. These compounds can be...
    5 KB (503 words) - 20:09, 2 January 2024
  • designed by choosing ligands which have specific stereochemical requirements. For example, terpyridine, which is a tridentate ligand forms the complex [Zn(terpy)Cl2]...
    22 KB (2,626 words) - 15:18, 21 April 2024
  • Thumbnail for Metal–organic framework
    tridentate amide linkers and cadmium salt catalyzes the Knoevenagel condensation reaction. The pyridine groups on the ligand 4-BTAPA act as ligands binding...
    178 KB (21,470 words) - 05:02, 28 August 2024
  • Thumbnail for Aza-crown ether
    aza-crowns and their complexes 1,4,7-Trimethyl-1,4,7-triazacyclononane, a tridentate ligand used in coordination chemistry. Cyclam is a tetraaza crown ether with...
    6 KB (593 words) - 16:20, 17 February 2024
  • Thumbnail for Diethylenetriamine
    groups forming crosslinks. In coordination chemistry, it serves as a tridentate ligand forming complexes such as Co(dien)(NO2)3. Like some related amines...
    7 KB (398 words) - 01:07, 28 October 2024
  • Thumbnail for Thia-crown ether
    affinities for transition metals. 1,4,7-Trithiacyclononane (9-ane-S3) is a tridentate ligand and forms complexes with many metal ions, including those considered...
    3 KB (309 words) - 13:49, 6 October 2022
  • Thumbnail for 1,4,7-Triazacyclononane
    1,4,7-Triazacyclononane (category Tridentate ligands)
    [(CH2CH2N(Ts)]3 + 3 H2O → [CH2CH2NH]3 + 3 HOTs TACN is a popular tridentate ligand. It is threefold symmetric and binds to one face of an octahedron...
    7 KB (651 words) - 02:59, 20 June 2022
  • Thumbnail for Terpyridine
    It can be prepared from bis-triazinyl pyridine. Terpyridine is a tridentate ligand that binds metals at three meridional sites giving two adjacent 5-membered...
    6 KB (497 words) - 03:10, 11 February 2024
  • Thumbnail for 1,4,7-Trithiacyclononane
    (CH2CH2S)3. This cyclic thioether is most often encountered as a tridentate ligand in coordination chemistry, where it forms transition metal thioether...
    4 KB (224 words) - 12:34, 2 February 2024
  • bi- and tridentate bis(oxazoline) ligands are used in organic synthesis Both enantiomers of BINAP BINOL, another binaphthalene-based ligand TADDOL DIPAMP...
    11 KB (1,164 words) - 20:59, 19 September 2024
  • Thumbnail for Trimethyl phosphite
    Ni(P(OMe)3)4 (m.p. 108 °C). The tridentate ligand called the Kläui ligand is derived from trimethyl phosphite. The formation of this ligand illustrates the susceptibility...
    5 KB (419 words) - 09:33, 23 October 2024
  • Thumbnail for Tris(2-aminoethyl)amine
    possible, four of which are chiral. In a few cases, tren serves as a tridentate ligand with one of the primary amine groups non-coordinated. Tren is a common...
    10 KB (632 words) - 01:38, 9 March 2024
  • iodosobenzene diacetate. The gold catalyst is based on a terpyridine tridentate ligand. Yudin, Andrei K., ed. (2007). Aziridines and Epoxides in Organic...
    11 KB (1,286 words) - 23:57, 31 May 2024
  • Thumbnail for Dipicolylamine
    secondary amine with two picolyl substituents. The compound is a common tridentate ligand in coordination chemistry. The compound can be prepared by many methods...
    2 KB (148 words) - 16:12, 7 November 2022
  • 7-triazaheptane) is a tridentate ligand and en is bidentate. The number of chelate rings is one less than the number of donor atoms in the ligand. EDTA...
    60 KB (7,604 words) - 21:10, 31 July 2024