A trihalide in chemistry is an organohalide consisting of three halide atoms bonded to a single atom or compound. An example of a trihalide is chloroform...
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reinforced by its exothermic reactivity toward Lewis bases. In the boron trihalides, BX3, the length of the B–X bonds (1.30 Å) is shorter than would be expected...
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that this bonding involves only s- and p-orbitals. All four symmetrical trihalides are well known: gaseous PF3, the yellowish liquids PCl3 and PBr3, and...
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oxide, and it forms all four trihalides. Antimony forms antimony(III) oxide and antimonite but not oxyacids. Its trihalides, antimony trifluoride, antimony...
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Gold halide (section Trihalides)
quantum chemical study of monomeric and dimeric gold monohalide and gold trihalide molecules, AuX, Au2X2, AuX3, and Au2X6 (X = F, Cl, Br, I)", Chemistry...
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Gallium halides (section Trihalides)
There are three sets of gallium halides, the trihalides where gallium has oxidation state +3, the intermediate halides containing gallium in oxidation...
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black α-form and a dark brown β-form: the trihydrate is red. Of the known trihalides, trifluoride is dark brown and decomposes above 650 °C, tribromide is...
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heat→ Al2O3 + 6 HCl + 9 H2O All four trihalides are well known. Unlike the structures of the three heavier trihalides, aluminium fluoride (AlF3) features...
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similarly analogous to the hydrohalic acids. All four simple nitrogen trihalides are known. A few mixed halides and hydrohalides are known, but are mostly...
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triiodide also finds use in organic chemistry, as a mild oxygen acceptor. The trihalides are fairly readily oxidized by chalcogens to give the corresponding oxyhalides...
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The most commonly studied perovskite absorber is methylammonium lead trihalide (CH3NH3PbX3, where X is a halogen ion such as iodide, bromide, or chloride)...
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reaction is typically catalyzed by the corresponding iron or aluminum trihalide. The Friedel–Crafts reaction can be performed either as an acylation or...
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peroxide Nickel hydrazine nitrate Nickel hydrazine perchlorate Nitrogen trihalides: Nitrogen trichloride Nitrogen tribromide Nitrogen triiodide Nitroglycerin...
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kalgoorlieite, and the anion As2Te− is known as a ligand in cobalt complexes. All trihalides of arsenic(III) are well known except the astatide, which is unknown....
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897 Weinhold 2005, pp. 275–306 Pimentel, G. C. (1951). "The Bonding of Trihalide and Bifluoride Ions by the Molecular Orbital Method". The Journal of Chemical...
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sesquisulfides, and sesquiselenides are known, as well as IrS 3. Binary trihalides, IrX 3, are known for all of the halogens. For oxidation states +4 and...
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valence 6s and 6p orbitals of thallium with the 1s orbital of hydrogen. The trihalides are more stable, although they are chemically distinct from those of the...
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bromine and iodine, Ga 2Br 6 and Ga 2I 6.: 133 Like the other group 13 trihalides, gallium(III) halides are Lewis acids, reacting as halide acceptors with...
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J. A. Ibers, "Nature of the donor-acceptor bond in acetonitrile-boron trihalides. The structures of the boron trifluoride and boron trichloride complexes...
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Scandium bromide, or ScBr3, is a trihalide, hygroscopic, water-soluble chemical compound of scandium and bromine. ScBr3 is produced through the burning...
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8S 13]2− . Antimony forms two series of halides: SbX 3 and SbX 5. The trihalides SbF 3, SbCl 3, SbBr 3, and SbI 3 are all molecular compounds having trigonal...
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reactive towards water. Boron reacts with halogens to give the corresponding trihalides. Boron trichloride is, however, produced industrially by direct chlorination...
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attack yttrium, but other strong acids do. With halogens, yttrium forms trihalides such as yttrium(III) fluoride (YF 3), yttrium(III) chloride (YCl 3), and...
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melts); with other halogens it yields only bismuth(III) halides. The trihalides are corrosive and easily react with moisture, forming oxyhalides with...
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boron trioxide: 4 B + 3 O2 → 2 B2O3 Boron undergoes halogenation to give trihalides; for example, 2 B + 3 Br2 → 2 BBr3 The trichloride in practice is usually...
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9: 91–124. doi:10.1039/CS9800900091. Pimentel, G. C. The Bonding of Trihalide and Bifluoride Ions by the Molecular Orbital Method. J. Chem. Phys. 1951...
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tetrahalides, CrF4, CrCl4, and CrBr4, can be produced by treating the trihalides (CrX 3) with the corresponding halogen at elevated temperatures. Such...
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tribromide is named as a bromide as it is analogous to the other nitrogen trihalides.) Bromination of metals with Br2 tends to yield lower oxidation states...
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include EsOCl, EsOBr and EsOI. These salts are synthesized by treating a trihalide with a vapor mixture of water and the corresponding hydrogen halide: for...
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NaCl + 5 H2O It is also formed as a by product of hydrolysis of boron trihalides and diborane: B2H6 + 6 H2O → 2 B(OH)3 + 6 H2 BX3 + 3 H2O → B(OH)3 + 3...
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