• Thumbnail for Trimethylphosphine
    Trimethylphosphine is an organophosphorus compound with the formula P(CH3)3, commonly abbreviated as PMe3. This colorless liquid has a strongly unpleasant...
    7 KB (548 words) - 09:15, 2 September 2024
  • Thumbnail for Hexakis(trimethylphosphine)tungsten
    Hexakis(trimethylphosphine)tungsten is a tungsten(0) organometallic compound with the formula W(P(CH3)3)6. It is a yellow crystalline solid soluble in...
    8 KB (700 words) - 15:40, 19 January 2025
  • Thumbnail for Tetrakis(trimethylphosphine)tungsten(II) trimethylphospinate hydride
    Tetrakis(trimethylphosphine)tungsten(II) trimethylphospinate hydride (W(PMe3)4(η2-CH2PMe2)H) is an air-sensitive organotungsten complex with tungsten in...
    60 KB (5,970 words) - 22:36, 28 January 2025
  • Thumbnail for Phosphine
    synthesis of organic compounds containing phosphorus, which he named "trimethylphosphine" and "triethylphosphine", in analogy with "amine" (organo-nitrogen...
    39 KB (3,618 words) - 07:48, 16 January 2025
  • Thumbnail for Ligand
    monodentate Triethylenetetramine (trien) C6H18N4 neutral tetradentate Trimethylphosphine P(CH3)3 neutral monodentate Tris(o-tolyl)phosphine P(o-tolyl)3 neutral...
    35 KB (3,307 words) - 14:02, 22 November 2024
  • Thumbnail for Lewis acids and bases
    Pyridine N 128 Acetonitrile N 60 DMA O 112 DMSO O 105 THF O 90.4 Et2O O 78.8 Acetone O 76.0 EtOAc O 75.5 Trimethylphosphine P 97.3 Tetrahydrothiophene S 51.6...
    22 KB (2,762 words) - 18:15, 13 January 2025
  • Thumbnail for Trimethylsulfoxonium iodide
    center. The ion has idealized C3v symmetry. It is isoelectronic with trimethylphosphine oxide. Trimethylsulfoxonium iodide is used to generate dimethyloxosulfonium...
    3 KB (148 words) - 19:13, 13 January 2025
  • Thumbnail for Tetramethylphosphonium bromide
    tetramethylphosphonium and the bromide anion. It is prepared by treating trimethylphosphine with methyl bromide. Deprotonation gives methylenetrimethylphosphine...
    2 KB (138 words) - 04:37, 11 February 2024
  • Thumbnail for Triphenylphosphine
    (SDS) Fisher Scientific Related compounds Related tertiary phosphines Trimethylphosphine Phosphine Related compounds Triphenylamine Triphenylarsine Triphenylstibine...
    18 KB (1,624 words) - 16:57, 12 June 2024
  • Thumbnail for Triphenyl phosphite
    3 HOC6H5 → P(OC6H5)3 + 3 HCl Triphenylphosphite is a precursor to trimethylphosphine, it serves as a source of P3+ that is less electrophilic than phosphorus...
    5 KB (404 words) - 02:29, 19 June 2024
  • trihydrazide 10105-42-7 C3H9OP trimethylphosphine oxide 676-96-0 C3H9PS dimethyl methylthiophosphine 35449-60-6 C3H9PS trimethylphosphine sulfide 2404-55-9 C3H9PSe...
    17 KB (28 words) - 15:50, 20 March 2022
  • Thumbnail for Monolayer-protected cluster molecules
    Masaki; Dahl, Lawrence F. (2001). "High-nuclearity palladium carbonyl trimethylphosphine clusters containing unprecedented face-condensed icosahedral-based...
    202 KB (676 words) - 15:52, 19 January 2025
  • Thumbnail for Dichlorotrimethyltantalum
    dichlorotrimethyltantalum has also been reported with trimethylphosphine by Sattler. Trimethylphosphine was introduced by vapour transfer to dichlorotrimethyltantalum...
    10 KB (1,040 words) - 14:14, 21 July 2024
  • Thumbnail for Triethylphosphine
    triethylphosphine gained acceptance earlier than did the simpler trimethylphosphine, as illustrated by the preparation of the hydride complex trans-PtHCl(PEt3)2...
    4 KB (343 words) - 20:10, 15 June 2024
  • Thumbnail for Pentaborane(9)
    It is Lewis acidic, forming double adducts with two equivalents of trimethylphosphine. Pentaborane is used for the synthesis of other boron hydride clusters...
    12 KB (1,153 words) - 12:02, 23 December 2024
  • Thumbnail for List of gases
    2]pentane 39 °C Ruthenium(VIII) oxide 40 °C Nickel carbonyl 42.1 °C Trimethylphosphine 43 °C Gallane liquid decomposes at 0 °C. Nitroxyl and diazene are...
    96 KB (4,561 words) - 11:56, 29 January 2025
  • Thumbnail for Titanocene dichloride
    "Bis(η5-2,4-cyclopentadienyl)bis(trimethylphosphine)titanium". Bis(5-2,4-cyclopentadienyl)bis(trimethylphosphine)titanium. Encyclopedia of Reagents...
    21 KB (1,771 words) - 20:25, 6 August 2024
  • Trimethyl phosphite 923 Dimethylamine 923 Pyridine 924 Trimethylamine 942 Trimethylphosphine 950 Triethylphosphine 969 Triethylamine 972 Lithium hydroxide 1008...
    15 KB (1,028 words) - 15:15, 24 April 2024
  • organolithium compounds: 3 RMgX + PCl3 → PR3 + 3 MgX2 In the case of trimethylphosphine, triphenyl phosphite is used in place of the highly electrophilic...
    16 KB (1,713 words) - 17:34, 26 December 2024
  • Thumbnail for Disulfur dioxide
    atoms linked to the metal atom. This was first shown in 2003. The bis(trimethylphosphine) thiirane S-oxide complex of platinum, when heated in toluene at 110 °C...
    14 KB (1,255 words) - 15:48, 21 December 2024
  • Thumbnail for Tributylphosphine
    in low oxidation states. It is cheaper and less air-sensitive than trimethylphosphine and other trialkylphosphines. Although its complexes are generally...
    7 KB (612 words) - 22:38, 3 December 2024
  • Thumbnail for Aziridines
    converted into aziridines with the use of trialkyl phosphines such as trimethylphosphine or tributylphosphine. Aziridines are reactive substrates in ring-opening...
    16 KB (1,680 words) - 13:29, 4 September 2024
  • Thumbnail for Trimethylborane
    dimethyldiborane: (CH3)BH2.BH3 and (CH3)2BH.BH3. It reacts as a gas with trimethylphosphine to form a solid Lewis salt with a heat of formation of −41 kcal per...
    10 KB (902 words) - 13:26, 30 October 2024
  • Thumbnail for Trimethyl phosphite
    has a smaller cone angle and better acceptor properties relative to trimethylphosphine. A representative derivative is the colorless tetrahedral complex...
    5 KB (422 words) - 09:33, 23 October 2024
  • Thumbnail for Boron hydride clusters
    acids, with concomitant opening of the cluster. An example involving trimethylphosphine: B5H9 + 2 P(CH3)3 → B5H9·2P(CH3)3 Some higher boranes, especially...
    13 KB (1,459 words) - 10:16, 8 January 2025
  • Thumbnail for Thorium(IV) nitrate
    diethyl ether, tri(n‐butyl)phosphate, butylamine, dimethylamine, and trimethylphosphine oxide. New Jersey Department of Health. Thorium Nitrate. Hazardous...
    13 KB (1,237 words) - 21:48, 18 October 2024
  • Related compounds Cacodylic acid Triphenylarsine Pentamethylarsenic Trimethylphosphine Trimethylamine Supplementary data page Trimethylarsine (data page)...
    9 KB (753 words) - 09:14, 2 September 2024
  • Thumbnail for Tin(IV) bromide
    trans-[SnBr2(H2O)4]2+. SnBr4 forms 1:1 and 1:2 complexes with ligands, e.g. with trimethylphosphine the following can be produced, SnBr4.P(CH3)3 and SnBr4.2P(CH3)3. Greenwood...
    5 KB (348 words) - 13:54, 13 December 2024
  • hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium." Organometallics, 3.2 (1984): 274–278. Tilley Group Website...
    10 KB (878 words) - 22:47, 12 August 2023
  • Thumbnail for Trimethylstibine
    produced by anaerobic bacteria in antimony-rich soils. In contrast to trimethylphosphine, trimethylstibine is a weaker Lewis base. It is used in the production...
    4 KB (171 words) - 09:16, 2 September 2024