Tris(o-tolyl)phosphine is an organophosphorus compound with the formula P(C6H4CH3)3. It is a white, water-insoluble solid that is soluble in organic solvents...
2 KB (156 words) - 17:22, 30 September 2023
metal. L ligands are Lewis bases. L ligands are represented by amines, phosphines, CO, N2, and alkenes. Examples of L ligands extend to include dihydrogen...
35 KB (3,307 words) - 13:02, 16 February 2024
"Halide and Amine Influence in the Equilibrium Formation of Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes from Palladium Aryl Halide Dimers", Organometallics...
31 KB (3,483 words) - 01:36, 25 April 2024
Triphenylphosphine (redirect from Triphenyl phosphine)
4-lithiophenyl-substituted polystyrene with chlorodiphenylphosphine (PPh2Cl). Tris(o-tolyl)phosphine Decyl(triphenyl)phosphonium Vaska's complex Wilkinson's catalyst...
18 KB (1,624 words) - 16:57, 12 June 2024
first- or second-generation phosphine ligands for Pd-catalyzed C-N bond-forming cross-coupling (e.g., tris(o-tolyl)phosphine and BINAP, respectively) necessitated...
37 KB (3,942 words) - 04:34, 19 November 2023
Herrmann's catalyst is made by reaction of palladium(II) acetate with tris(o-tolyl)phosphine. Light or heat reduce palladium acetate to give thin layers of palladium...
13 KB (1,182 words) - 13:49, 4 April 2024
Herrmann's catalyst (category Phosphine complexes)
"PdP(o-tol)3". The complex is made by reaction of tris(o-tolyl)phosphine with palladium(II) acetate: 2 Pd(OAc)2 + 2 P(o−tolyl)3 → 2 HOAc + Pd2(OAc)2[P(o−tolyl)(o−tolyl)2]2...
2 KB (177 words) - 17:18, 18 June 2024
was highlighted by Herrmann's catalyst in 1990s. Derivatives of tris(o-tolyl)phosphine proved effective in Heck reactions. There are two distinct types...
12 KB (1,142 words) - 22:10, 8 November 2023
via some linking atoms such as sulfur or phosphorus forming thiol and phosphine ligands. However, there are alkynyl and carbene protected MPCs, where...
201 KB (676 words) - 06:26, 20 August 2024
of [Ru(CO)CLH(Me2Hpz)(PR3)2] (Me2Hpz = 3,5-dimethylpyrazole; R = Ph, p-tolyl) with Acetylenes. The Crystal Structure of [Ru(CO)Cl(HC:CHCMe3)(Me2HPz)(PPh3)2]...
9 KB (949 words) - 13:06, 15 February 2024