Tris(trimethylsilyl)silane is the organosilicon compound with the formula (Me3Si)3SiH (where Me = CH3). It is a colorless liquid that is classified as...
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with tris(trimethylsilyl)silane and triflic acid with evolution of hydrogen. The aldol reaction is catalyzed by bis(trifluoromethane)sulfonimide "Tris...
9 KB (1,016 words) - 00:04, 19 July 2024
e.g. to tris(trimethylsilyl)silane ((Me3Si)3SiH). Tris(trimethylsilyl)methane Gilman, H.; Smith, C. L. (1967). "Tetrakis(trimethylsilyl)silane". Journal...
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Organosilicon chemistry (redirect from Alkyl silane)
ISBN 978-0471936237. Dickhaut, Joachim; Giese, Bernd (1992). "Tris(trimethylsilyl)silane". Org. Synth. 70: 164. doi:10.15227/orgsyn.070.0164. Lickiss,...
25 KB (2,547 words) - 00:08, 6 April 2024
[(Me3Si)3CTl]4 is a rare example of a robust organothallium(I) compound. Tris(trimethylsilyl)silane Uhl W, Graupner R, Layh M, Schütz U (1995). "In4{C(SiMe3)3}4 mit...
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TlH3 carbon: alkanes, alkenes, alkynes, and all hydrocarbons silicon: silane germanium: germane tin: stannane lead: plumbane nitrogen: ammonia ("azane"...
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substrate. For example, tris(trimethylsilyl)amine reacts with α,δ,ω-triketones to give tricyclic pyrroles. Reduction of trimethylsilyl chloride give hexamethyldisilane:...
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Tetrakis(trimethylsilyl)methane (TTMSM) is an organic compound with formula C13H36Si4, consisting of four trimethylsilyl (Si(CH3)3) groups bonded to a...
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Tributyltin hydride (redirect from Tri-n-butyltin hydride)
hydrostannylation reactions: RC2R′ + HSnBu3 → RC(H)=C(SnBu3)R′ Tributyltin Trimethylsilyl "SnBu3H - PubChem Public Chemical Database". The PubChem Project. USA:...
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examples are methylsilane H3C−SiH3 which contains carbon and silicon, tris(trimethylsilyl)germanium hydride ((CH3)3Si)3GeH which contain carbon, silicon and...
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Silanide (category Silanes)
more complex derivative anions such as tris(trimethylsilyl)silanide (hypersilyl), tris(tert-butyl)silanide, tris(pentafluoroethyl)silanide, or triphenylsilanide...
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synthetic strategies has led to the discovery and development of tris(trimethylsilyl)silane as radical-based reducing agent (Fluka prize “Reagent of the Year...
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isopropyllithium, and cyclohexanyllithium. Common lithium amides, e.g. lithium bis(trimethylsilyl)amide and lithium diisopropylamide, are also subject to aggregation...
55 KB (5,971 words) - 20:35, 22 July 2024