Vanadium(III) acetylacetonate is the coordination compound with the formula V(C5H7O2)3, sometimes designated as V(acac)3. It is an orange-brown solid...
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epoxidation of allylic alcohols by peroxides. Vanadium(III) acetylacetonate is a dark-brown solid. Vanadium β-diketonate complexes are used as precatalysts...
25 KB (2,762 words) - 21:04, 12 August 2024
Like other charge-neutral acetylacetonate complexes, it is not soluble in water. The complex is generally prepared from vanadium(IV), e.g. vanadyl sulfate:...
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Vanadyl sulfate (redirect from Vanadium(IV) sulphate)
1016/0022-4596(70)90121-0. Bryant, Burl E.; Fernelius, W. Conard (1957), "Vanadium(IV) Oxy(acetylacetonate)", Inorganic Syntheses, vol. 5, pp. 113–16, doi:10.1002/9780470132364...
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the vanadyl center). An example is vanadyl acetylacetonate (V(O)(O2C5H7)2). In this complex, the vanadium is 5-coordinate, distorted square pyramidal...
16 KB (1,842 words) - 09:59, 21 June 2024
the vanadyl center). An example is vanadyl acetylacetonate (V(O)(O2C5H7)2). In this complex, the vanadium is 5-coordinate, distorted square pyramidal...
75 KB (8,566 words) - 05:49, 11 November 2024
in situ by treating soluble coordination complexes such as vanadium(III) acetylacetonate with organoaluminium activators. Synthesis of Organometallic...
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"An Historic and Scientific Study of the Properties of Metal(III) Tris-acetylacetonates". Structural Chemistry. 28: 201–212. doi:10.1007/s11224-016-0864-0...
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Europium (section Eu(II) vs. Eu(III))
polar organic solvents. Lipophilic europium complexes often feature acetylacetonate-like ligands, such as EuFOD. Europium metal reacts with all the halogens:...
38 KB (4,713 words) - 01:56, 30 October 2024
reagent. d1 Examples: molybdenum(V) chloride, vanadyl acetylacetonate, vanadocene dichloride, vanadium tetrachloride. d2 Examples: titanocene dicarbonyl....
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vanadium(II) iodide 15513–84–5 VI3 vanadium(III) iodide 15513–94–7 VI4 vanadium(IV) iodide 15831–18–2 VN vanadium(III) nitride 24646–85–3 VO vanadium(II)...
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"An historic and scientific study of the properties of metal(III) tris-acetylacetonates". Struct Chem. 28: 201–212. doi:10.1007/s11224-016-0864-0. Rayner-Canham...
86 KB (9,774 words) - 20:31, 22 November 2024
been used in conjunction with sodium acetate. The use of platinum(II) acetylacetonate has also been reported. Several barium platinides have been synthesized...
66 KB (7,080 words) - 22:48, 12 September 2024
vanadium(II) bromide VBr3 vanadium(III) bromide 13470-26-3 VCl2 vanadium(II) chloride 10580-52-6 VCl3 vanadium(III) chloride 7718-98-1 VI3 vanadium(III)...
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Structures of Aquahalogenovanadium(III) Complexes. Part I. X-Ray Crystal Structure of trans-Tetrakisaquadibromo-Vanadium(III) Bromide Dihydrate and the Isomorphous...
61 KB (3,477 words) - 14:14, 21 May 2024