• A ZieglerNatta catalyst, named after Karl Ziegler and Giulio Natta, is a catalyst used in the synthesis of polymers of 1-alkenes (alpha-olefins). Two...
    17 KB (1,843 words) - 20:03, 9 April 2024
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    Natta's work at Politecnico di Milano led to the improvement of earlier work by Karl Ziegler and to the development of the ZieglerNatta catalyst. He...
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    organometallic compounds, as well as the development of ZieglerNatta catalyst. One of many awards Ziegler received was the Werner von Siemens Ring in 1960 jointly...
    23 KB (2,670 words) - 20:15, 6 October 2023
  • in the 1950s with heterogeneous ZieglerNatta catalysts based on titanium tetrachloride and organoaluminium co-catalysts. The mixing of TiCl4 with trialkylaluminium...
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    special type of supported Ziegler-Natta catalyst or with some metallocene catalysts. Modern supported Ziegler-Natta catalysts developed for the polymerization...
    50 KB (5,799 words) - 06:59, 10 August 2024
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    With ZieglerNatta catalyst TiCl4/Al(i-C4H9)3, a more pure cis-1,4-polyisoprene similar to natural rubber is formed. With ZieglerNatta catalyst VCl3/Al(i-C4H9)3...
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    lack of branching is ensured by an appropriate choice of catalyst (e.g., ZieglerNatta catalysts) and reaction conditions. HDPE is resistant to many different...
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  • including the traditional routes using Philips catalyst and traditional heterogeneous Ziegler-Natta catalysts, which still are used to produce the bulk of...
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    the reaction requires catalysts. Three main catalysts are employed commercially: the Phillips catalyst, ZieglerNatta catalysts (based on titanium trichloride)...
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  • platinum catalysts, the fuels must be free of sulfur and carbon monoxide, unless a desulfurization system is used. Ziegler-Natta catalysts for the production...
    9 KB (1,254 words) - 10:39, 27 March 2024
  • States Ziegler House (Ketchikan, Alaska), NRHP-listed in Ketchikan Gateway Borough, Alaska, associated with A. H. and Bob Ziegler ZieglerNatta catalyst, chemical...
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    titanocene and related complexes emulated some aspects of these ZieglerNatta catalysts but with low activity. He subsequently found that high activity...
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  • Thumbnail for Diethylaluminium chloride
    (C2H5)2AlCl, it exists as a dimer, [(C2H5)2AlCl]2 It is a precursor to Ziegler-Natta catalysts employed for the production of polyolefins. The compound is also...
    7 KB (534 words) - 22:51, 25 January 2024
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    of the most common methods is via passing acetylene gas over a ZieglerNatta catalyst, such as Ti(OiPr)4/Al(C2H5)3. This method allows control over the...
    25 KB (2,617 words) - 01:37, 13 July 2024
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    bioorganometallic chemistry 1963 Nobel prize for Karl Ziegler and Giulio Natta on ZieglerNatta catalyst 1973 Nobel prize Geoffrey Wilkinson and Ernst Otto...
    31 KB (3,140 words) - 14:35, 7 August 2024
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    interest was renewed in the mid-1950s after the discovery of the ZieglerNatta catalyst. This method proved to be much better for tire manufacturing than...
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  • chain-growth polymerization. In the presence of a suitable catalyst (typically a ZieglerNatta catalyst), propene will polymerize. There are multiple ways to...
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  • common. MDPE can be produced by chromium/silica catalysts, Ziegler-Natta catalysts or metallocene catalysts. MDPE has good shock and drop resistance properties...
    3 KB (174 words) - 04:53, 29 July 2024
  • Thumbnail for Titanium
    titanium(III) chloride (TiCl3), which is used as a catalyst for production of polyolefins (see ZieglerNatta catalyst) and a reducing agent in organic chemistry...
    79 KB (8,788 words) - 08:10, 13 August 2024
  • with the development of technology for the manufacture of Ziegler-Natta polypropylene catalyst which is in use with Reliance Industries. He has authored...
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  • Thumbnail for Branching (polymer chemistry)
    complications to be solved. If the ZieglerNatta catalyst was poisoned or damaged then the chain stopped growing. Also, ZieglerNatta monomers have to be small...
    10 KB (1,187 words) - 16:25, 20 April 2024
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    most common catalysts consist of titanium(III) chloride, the so-called ZieglerNatta catalysts. Another common catalyst is the Phillips catalyst, prepared...
    59 KB (6,428 words) - 18:57, 14 August 2024
  • ZieglerNatta catalysts. Isotactic PB-1 is produced commercially using two types of heterogeneous ZieglerNatta catalysts. The first type of catalyst...
    19 KB (2,047 words) - 06:28, 27 May 2024
  • Thumbnail for Catalyst support
    a catalyst support is a material, usually a solid with a high surface area, to which a catalyst is affixed. The activity of heterogeneous catalysts is...
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  • metal-containing catalysts. The reaction is highly exothermic. Traditionally, Ziegler-Natta catalysts are used. Named after the Nobelists Karl Ziegler and Giulio...
    13 KB (1,162 words) - 11:01, 3 May 2024
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    and its ability to poison ZieglerNatta catalysts. It is selectively hydrogenated into ethylene, usually using Pd–Ag catalysts. 3 CH4 + 3 O2 → C2H2 + CO...
    44 KB (4,378 words) - 06:36, 13 May 2024
  • Scotland – steam hammer Giulio Natta (1903–1979), together with Karl Ziegler (1898–1973), Italy/Germany – ZieglerNatta catalyst William Neade (fl.1624–1637)...
    107 KB (11,985 words) - 06:53, 11 August 2024
  • stereoregularity of the polymerisation of alkenes using ZieglerNatta or metallocene catalysts. Stereoregularity is relevant for unsymmetrical alkenes...
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    chlorides are important in catalyzing polymer production, as in Ziegler Natta catalyst tertiary phosphines, which are used as ligands in homogeneous catalysis...
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  • Thumbnail for Magnesium chloride
    many application factors. Ziegler-Natta catalysts, used commercially to produce polyolefins, often contain MgCl2 as a catalyst support. The introduction...
    23 KB (2,226 words) - 14:37, 20 July 2024