• Thumbnail for Organozinc chemistry
    Organozinc chemistry is the study of the physical properties, synthesis, and reactions of organozinc compounds, which are organometallic compounds that...
    33 KB (3,394 words) - 06:05, 9 December 2023
  • Thumbnail for Organometallic chemistry
    organocobalt chemistry, organonickel chemistry, organocopper chemistry, organozinc chemistry, organogallium chemistry, organogermanium chemistry, organoarsenic...
    31 KB (3,140 words) - 14:35, 7 August 2024
  • Thumbnail for Zinc
    of zinc. Organozinc compounds are those that contain zinc–carbon covalent bonds. Diethylzinc ((C 2H5) 2Zn) is a reagent in synthetic chemistry. It was...
    143 KB (16,239 words) - 09:58, 22 August 2024
  • Thumbnail for Organoboron chemistry
    diethylborane, is the transmetallation of the organoboron compounds to form organozinc compounds. Some diaryl and dialkylboranes are well known. Dimesitylborane...
    30 KB (2,992 words) - 19:24, 18 August 2024
  • Thumbnail for Alexander Zaytsev (chemist)
    research at Kazan was primarily concerned with the development of organozinc chemistry and the synthesis of alcohols. The first of these reactions had been...
    7 KB (896 words) - 17:32, 9 January 2024
  • Thumbnail for Zinc chloride
    and lacking acidic protons, this complex is used in the synthesis of organozinc compounds. A related 1:2 complex is ZnCl2(NH2OH)2 (zinc dichloride di(hydroxylamine))...
    39 KB (3,992 words) - 19:51, 20 August 2024
  • cross-coupling reaction. The reaction couples organic halides or triflates with organozinc compounds, forming carbon-carbon bonds (C-C) in the process. A palladium...
    34 KB (3,954 words) - 20:12, 15 June 2024
  • Thumbnail for Finkelstein reaction
    Tirado (1999). "Copper-catalyzed Conjugate Addition of Functionalized Organozinc Reagents to α,β-Unsaturated Ketones: Ethyl 5-(3-oxocyclohexyl)pentanoate"...
    6 KB (639 words) - 15:57, 4 August 2024
  • Thumbnail for Organotitanium chemistry
    tetraalkoxides, or mixtures thereof with organolithium, organomagnesium, and organozinc compounds. Such compounds find occasional use as stoichiometric reagents...
    18 KB (1,866 words) - 09:45, 4 November 2023
  • Thumbnail for Thioester
    thioesters is the Fukuyama coupling, in which the thioester is coupled with an organozinc halide by a palladium catalyst to give a ketone. Thioesters are common...
    13 KB (1,386 words) - 18:47, 10 August 2024
  • Metalation (category Organometallic chemistry)
    Grignard reagents. However, other organometallic compounds — such as organozinc compounds — also experience common use in both laboratory and industrial...
    11 KB (722 words) - 22:00, 9 April 2023
  • Thumbnail for Mercury (element)
    usually two-coordinate and linear geometry. Unlike organocadmium and organozinc compounds, organomercury compounds do not react with water. They usually...
    118 KB (12,591 words) - 13:32, 16 August 2024
  • Thumbnail for Diethylzinc
    Diethylzinc (category Organozinc compounds)
    reactive organozinc compound consisting of a zinc center bound to two ethyl groups. This colourless liquid is an important reagent in organic chemistry. It...
    12 KB (1,156 words) - 11:54, 29 May 2024
  • Thumbnail for Main group organometallic chemistry
    main group organometallic chemistry (if one considers Zn to be a main group element) involved the synthesis of organozinc compounds diethyl zinc by Frankland...
    6 KB (627 words) - 21:43, 13 August 2024
  • Thumbnail for Ketone
    compounds. In the Fukuyama coupling, ketones form from a thioester and an organozinc compound. By the reaction of an acid chloride with organocadmium compounds...
    25 KB (2,948 words) - 09:21, 3 August 2024
  • Thumbnail for Dimethylmercury
    at elevated temperatures, whereas the corresponding organocadmium and organozinc compounds (and most metal alkyls in general) hydrolyze rapidly. The difference...
    16 KB (1,375 words) - 17:05, 10 July 2024
  • Thumbnail for Grignard reagent
    Grignard reagent (category Organometallic chemistry)
    method to synthesize Grignard reagents involves reaction of Mg with an organozinc compound. This method has been used to make adamantane-based Grignard...
    24 KB (2,664 words) - 03:57, 1 August 2024
  • Thumbnail for Organocadmium chemistry
    organocadmium reagent, an ate complex. The same salt effect can be observed with organozinc compounds. Dimethylcadmium has been used to synthesize colloidal nanocrystals...
    6 KB (721 words) - 10:53, 16 November 2023
  • Thumbnail for Rieke metal
    Rieke metal (category Reagents for organic chemistry)
    corresponding polythiophene. Rieke-Zn also reacts with bromoesters to give organozinc reagents of value for the Reformatsky reaction. Rieke magnesium reacts...
    9 KB (1,128 words) - 01:19, 15 June 2024
  • place by: hydrolysis of a nitrile to form an amide or a carboxylic acid organozinc nucleophiles in the Blaise reaction alcohols in the Pinner reaction. the...
    8 KB (910 words) - 11:22, 17 April 2024
  • of studies have been disclosed. Mechanistic proposals generally invoke organozinc intermediates, sometimes including zinc carbenoids, either as discrete...
    12 KB (1,072 words) - 19:00, 23 January 2024
  • Simmons–Smith reaction is an organic cheletropic reaction involving an organozinc carbenoid that reacts with an alkene (or alkyne) to form a cyclopropane...
    27 KB (2,894 words) - 14:32, 19 August 2024
  • Thumbnail for Dichlorobis(triphenylphosphine)nickel(II)
    Ashley M. (2005-07-01). "Nickel-Catalyzed Electrophilic Amination of Organozinc Halides". Synlett. 2005 (11): 1799–1801. doi:10.1055/s-2005-871567. Quasdorf...
    7 KB (574 words) - 16:22, 9 August 2024
  • Thumbnail for Zinc nitrate
    Na2CO3 → ZnCO3 + 2 NaNO3 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 455. ISBN 978-0-08-037941-8...
    5 KB (394 words) - 13:43, 19 June 2024
  • Thumbnail for Zinc dithiophosphate
    (Google Books excerpt). In Leslie R. Rudnick (ed.). Lubricant Additives: Chemistry and Applications. CRC Press. ISBN 9780824747404. T. Ito; T. Igarashi;...
    8 KB (909 words) - 14:34, 4 January 2024
  • Thumbnail for Ladderane
    benzoquinone and bicyclo[2.2.0]hexene. Elimination of H–Br and addition of an organozinc compound installs the alkyl alcohol. A hydrazine-mediated deoxygenation...
    16 KB (1,892 words) - 15:02, 9 August 2024
  • they are often called, are aggregates with the formula [i-PrMgCl·LiCl]2 Organozinc-LiCl complexes Li-Yuan Bao, Robert; Zhao, Rong; Shi, Lei (2015). "Progress...
    9 KB (1,020 words) - 00:52, 17 February 2024
  • coupling is a coupling reaction taking place between a thioester and an organozinc halide in the presence of a palladium catalyst. The reaction product is...
    9 KB (901 words) - 05:18, 19 June 2023
  • Thumbnail for Fenestrane
    1-iodo-3-butene 1 is converted to a cyanozinc cuprate 2 (by transmetalation of the organozinc iodide with copper cyanide) which reacts in the next step with 1-nitrocyclopentene...
    11 KB (1,331 words) - 23:54, 10 April 2022
  • organomanganese compounds can be compared to that of organomagnesium and organozinc compounds. The electronegativity of Mn (1.55) is comparable to that of...
    8 KB (977 words) - 15:07, 7 March 2024