A persistent carbene (also known as stable carbene) is an organic molecule whose natural resonance structure has a carbon atom with incomplete octet (a...

exception are the persistent carbenes, which have extensive application in modern organometallic chemistry. There are two common methods for carbene generation...

transition metal carbene complex is an organometallic compound featuring a divalent carbon ligand, itself also called a carbene. Carbene complexes have...

coinage metal center (M = Cu, Ag, Au) ligated by at least one NHC-type persistent carbene. A variety of such complexes have been synthesized through deprotonation...

Carbenes in their triplet state can be viewed as diradicals centred on the same atom, while these are usually highly reactive persistent carbenes are...

New Haven County, a county in Connecticut, US N-Heterocyclic carbene, a persistent carbene, commonly used as ligand in organometallic chemistry Nag Hammadi...

with a carbene precursor. An early pioneer was Christoph Grundmann reporting on a carbene dimerisation in 1938. In the domain of persistent carbenes the...

Cyclic(alkyl)(amino) carbenes (CAACs) are a class of stable singlet carbene ligands that feature one amino and one sp3 alkyl group adjacent to the carbene carbon atom...

The triazol-5-ylidenes are a group of persistent carbenes which includes the 1,2,4-triazol-5-ylidene system and the 1,2,3-triazol-5-ylidene system. As...

surprisingly stable, and form an important class of the persistent carbenes. They include the first stable carbenes postulated (but not isolated) by Hans-Werner...

characteristics of the carbene. The stability of the radicals has been successfully engineered to achieve kinetic persistency and thermodynamic stability...

strong bases. Unlike with olefins, the ylides traditionally called persistent carbenes instead tend to cleave the central bond, forming two phosphaalkene/phosphinidene...

synthesis of some original persistent carbenes, including bis(diisopropylamino)cyclopropenylidene, the first example of a carbene with all-carbon environment...

Retrieved January 7, 2007. A. J. Arduengo (1976). "Looking for Stable Carbenes: The Difficulty in Starting Anew". Accounts of Chemical Research. 32 (11):...

nitrogens) would yield the carbene dihydroimidazol-2-ylidene. Derivatives of the latter comprise an important class of persistent carbenes. Classified as a diamine...

chemistry at Technische Universität Berlin he is notable for work on persistent carbenes and for proposing the Wanzlick equilibrium between saturated imidazolin-2-ylidenes...

of vitamin B1: This was the first evidence for the existence of persistent carbenes. Furoin has been used as a plasticizer. Denis Lorient (1999), New...

Stable and persistent phosphorus radicals are phosphorus-centred radicals that are isolable and can exist for at least short periods of time. Radicals...

bonds are more non-polar covalent in character. Gallium(III) iodide Persistent carbene Dohmeier, Carsten; Loos, Dagmar; Schnöckel, Hansgeorg (1996). "Aluminum(I)...

in hydroboration, organometallic chemistry, chiral materials and persistent carbenes. In 2010 Crudden became head of a Natural Sciences and Engineering...

(R2Sn:) are a class of organotin(II) compounds that are analogues of carbene. Unlike carbene, which usually has a triplet ground state, stannylenes have a singlet...

species are usually encountered only as transient intermediates. However, persistent alkyl radicals with half-lives "from seconds to years" have been prepared...

Grubbs, a CRD consultant, for the metathesis work. Anthony Arduengo’s persistent carbenes opened up a new area of chemistry and they have proven to be important...

a carbene via loss of N2. Insertion generated a BC5 system, which could then undergo a subsequent insertion with another equivalent of the carbene to...

"(L)2C2P2: Dicarbondiphosphide Stabilized by N-Heterocyclic Carbenes or Cyclic Diamido Carbenes". Angewandte Chemie International Edition. 56 (21): 5744–5749...

oxidation of a carbene-coordinated pnictogen complex to obtain Bi(II) radical species was reported by Stephan Schulz and coworkers in 2022. The carbene-coordinated...

compounds include both stannylenes (formula: R2Sn, as seen for singlet carbenes) and distannylenes (R4Sn2), which are roughly equivalent to alkenes. Both...

The premier example is difluorocarbene, CF2, which is a singlet whereas carbene (CH2) has a triplet ground state. This difference is significant because...

Vinyl Allyl 1-Propenyl Crotyl Allene Cumulene Aryl Phenyl Benzyl Alkyne Carbene Only carbon, hydrogen, and oxygen (only C, H and O) Only one element, not...

that unstable phosphasilene can react with DMAP and small N-heterocyclic carbene (NHC) to afford the corresponding stable complexes. In phosphasilenes stabilized...