• IUPAC definition calixarenes: Originally macrocyclic compounds capable of assuming a basket (or 'calix') shaped conformation. They are formed from p-hydrocarbyl...
    19 KB (2,105 words) - 07:28, 26 May 2024
  • Thumbnail for Cucurbituril
    is large enough to hold other molecular hosts such as a calixarene molecule. With a calixarene guest different chemical conformations (cone, 1,2-alternate...
    18 KB (2,255 words) - 13:39, 11 September 2024
  • Thumbnail for Synthetic ion channels
    orientation and geometry with respect to the membrane. Ion channels containing calixarenes of ring size 3 and 4 have both been reported. For calix[4]arene, two...
    30 KB (3,035 words) - 23:30, 16 July 2024
  • Thumbnail for Inherent chirality
    coined by Volker Boehmer in a 1994 review, to describe the chirality of calixarenes arising from their non-planar structure in 3-D space. This phenomenon...
    8 KB (964 words) - 09:21, 16 December 2023
  • Thumbnail for Macrocycle
    of twelve or more atoms. Classical examples include the crown ethers, calixarenes, porphyrins, and cyclodextrins. Macrocycles describe a large, mature...
    27 KB (3,288 words) - 22:37, 24 August 2024
  • Thumbnail for Formaldehyde
    elaborate condensations ensue. With 4-substituted phenols one obtains calixarenes. Phenol results in polymers. Many amino acids react with formaldehyde...
    89 KB (8,249 words) - 17:57, 2 August 2024
  • Thumbnail for Carcerand
    reaction with other molecules. The first generation carcerands are based on calixarene hemicarcerands with 4 alkyl substituents on the upper rim and 4 reactive...
    5 KB (576 words) - 15:12, 11 September 2024
  • substituents occupying a benzylic position. It is observed in compounds such as calixarenes and acridines. Peri-substitution occurs in naphthalenes for substituents...
    10 KB (1,049 words) - 11:18, 3 January 2024
  • compounds synthesized using the Wurtz–Fittig reaction include silylated calixarenes and vinylsilanes. Wurtz reaction Wang, Zerong (2010). "Wurtz–Fittig Reaction"...
    9 KB (915 words) - 00:40, 20 November 2023
  • Thumbnail for Inclusion compound
    and host, the attraction being generally due to van der Waals forces. Calixarenes and related formaldehyde-arene condensates are one class of hosts that...
    4 KB (440 words) - 00:45, 25 August 2024
  • of DNA and nucleotides by triazole ligation supramolecular chemistry: calixarenes, rotaxanes, and catenanes dendrimer design carbohydrate clusters and...
    48 KB (5,450 words) - 20:27, 26 August 2024
  • Thumbnail for Pillararene
    methylene bridges. They are structurally similar to the cucurbiturils and calixarenes that play an important part in host–guest chemistry. The first pillararene...
    17 KB (2,395 words) - 03:23, 9 September 2024
  • 3-trihydroxybenzene) and an aldehyde. Pyrogallolarenes are a type of calixarene, and a subset of resorcinarenes that are substituted with a hydroxyl at...
    3 KB (366 words) - 05:23, 23 August 2022
  • Thumbnail for 4-tert-Butylphenol
    trans-4-tert-butylcyclohexanol. Controlled condensation with formaldehyde gives calixarenes. OSHA records show it as an irritant and has developed suggested test...
    5 KB (484 words) - 19:50, 8 October 2023
  • Thumbnail for Ionophore
    Many synthetic ionophores are based on crown ethers, cryptands, and calixarenes. Pyrazole-pyridine and bis-pyrazole derivatives have also been synthesized...
    46 KB (4,336 words) - 21:02, 21 June 2024
  • Thumbnail for Clathrate compound
    host molecules." The term refers to many molecular hosts, including calixarenes and cyclodextrins and even some inorganic polymers such as zeolites....
    12 KB (1,314 words) - 10:21, 18 April 2024
  • Thumbnail for Artificial enzyme
    bind substrates using receptors such as cyclodextrin, crown ethers, and calixarene. Artificial enzymes based on amino acids or peptides have expanded the...
    131 KB (13,272 words) - 14:03, 7 September 2024
  • be chemically modified to fine-tune their properties. Cyclodextrins, calixarenes, cucurbiturils and crown ethers are readily synthesized in large quantities...
    35 KB (3,889 words) - 22:05, 25 November 2023
  • Thumbnail for Tetrakis(trimethylphosphine)tungsten(II) trimethylphospinate hydride
    Tungsten: Reactivity of the Calixarene Methylene CH Bond and the Facile Migration of the Metal around the Phenolic Rim of the Calixarene". Journal of the American...
    60 KB (5,991 words) - 16:44, 5 July 2024
  • (1,3-dihydroxybenzene) and an aldehyde. Resorcinarenes are a type of calixarene. Other types of resorcinarenes include the related pyrogallolarenes and...
    8 KB (923 words) - 19:56, 25 October 2023
  • Thumbnail for Gerard Parkin
    of problems in main group and transition metal chemistry, including: Calixarene complexes Retrodative bonding, especially related to boratranes Group...
    5 KB (283 words) - 14:58, 7 August 2024
  • one atom. Cycloparaphenylene, cyclic all-para-linked phenyl groups. Calixarenes B. H. Smith, Bridged Aromatic Compounds, Academic Press, New York, 1964...
    17 KB (1,857 words) - 21:31, 5 September 2024
  • Thumbnail for Timothy M. Swager
    Cope Award Swager, T. M.; Xu, B. "Liquid Crystalline Calixarenes" pages 389–398. in Calixarenes 50th Anniversary: Commemorative Issue Vicens, J.; Asfari...
    16 KB (1,476 words) - 18:09, 28 August 2024
  • Manuel; Rangelow, Ivo W (2013). "Nanolithography by scanning probes on calixarene molecular glass resist using mix-and-match lithography". Journal of...
    23 KB (2,364 words) - 19:35, 21 March 2024
  • motifs, such as crown ethers/ammonium ions, cucurbiturils/viologens, calixarene/viologens, cyclodextrins/adamantane derivatives, and pillar arene/imidazolium...
    54 KB (6,338 words) - 22:24, 2 May 2024
  • and pestle and the product recrystallised from the resulting paste. Calixarenes are the general category of macrocycle oligomers formed by hydroxyalkylation...
    17 KB (1,380 words) - 03:01, 6 August 2024
  • Thumbnail for 2,6-Dihydroxypyridine
    1016/S0021-9258(18)97197-8. PMID 5835946. Gerkensmeier, T; et al. (2001). "A New Type of Calixarene: Octahydroxypyridine[4]arenes". Chemistry: A European Journal. 7 (2):...
    6 KB (474 words) - 23:24, 27 September 2022
  • Thumbnail for Alexander Butlerov Chemistry Institute
    following fields: thio-phosphorylated derivatives of resorcinols and calixarenes; studying thio-phosphorylated unsaturated compounds using petrochemical...
    24 KB (2,692 words) - 12:12, 15 April 2024
  • Thumbnail for Kim Kimoon
    POSTECH in Pohang, Korea, that CB[n]s would be to the next decade what calixarenes have been to the previous one. 김, 하연 (28 August 2018). "포스텍 김기문 교수, 세계최초...
    31 KB (2,832 words) - 20:39, 4 February 2024
  • Thumbnail for Cavitand
    proposed by Cram includes many classes of molecules: cyclodextrins, calixarenes, pillararenes and cucurbiturils. However, modern usage in the field of...
    5 KB (453 words) - 02:33, 11 March 2023