Formamide is an amide derived from formic acid. It is a colorless liquid which is miscible with water and has an ammonia-like odor. It is chemical feedstock...
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Leuckart reaction (section Formamide as reagent)
formate or formamide as the nitrogen donor and reducing agent. It requires high temperatures, usually between 120 and 130 °C; for the formamide variant,...
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also be synthesized artificially. Purine is obtained in good yield when formamide is heated in an open vessel at 170 °C for 28 hours. This remarkable reaction...
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Dimethylformamide (redirect from Dimethyl formamide)
reduced pressure. As its name indicates, it is structurally related to formamide, having two methyl groups in the place of the two hydrogens. DMF is a...
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(CH3)2CHNHCHO + H2O → (CH3)2CHNH2 + HCO2H Pure ammonium formate decomposes into formamide and water when heated, and this is its primary use in industry. Formic...
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Formamide-based prebiotic chemistry is a reconstruction of the beginnings of life on Earth, assuming that formamide could accumulate in sufficiently high...
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N-Methylformamide (redirect from Methyl formamide)
as a highly polar solvent. NMF is closely related to other formamides, notably formamide and dimethylformamide (DMF). However, industrial use and production...
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Azodicarbonamide (redirect from C,C'-azodi(formamide))
Azodicarbonamide, ADCA, ACA, ADA, or azo(bis)formamide, is a chemical compound with the molecular formula C2H4O2N4. It is a yellow to orange-red, odorless...
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industrial-scale production of adenine is a modified form of the formamide method. This method heats up formamide under 120 degree Celsius conditions within a sealed...
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Diethylformamide (redirect from Diethyl formamide)
formula C5H11NO. As its name indicates, it is structurally related to formamide, having two ethyl groups in place of the two hydrogens. It is used in...
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Cyanide hydratase (redirect from Formamide hydro-lyase (cyanide-forming))
enzyme cyanide hydratase (EC 4.2.1.66) catalyzes the chemical reaction formamide ⇌ {\displaystyle \rightleftharpoons } cyanide + H2O This enzyme belongs...
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Proto-metabolism (section Formamide chemistry)
can be achieved. Formamide (NH2CHO) is the simplest naturally-occurring amide. Similar to HCN, formamide can form naturally. Formamide has specific physical...
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Formic acid (section From methyl formate and formamide)
indirectly by first treating the methyl formate with ammonia to give formamide, which is then hydrolyzed with sulfuric acid: HCO2CH3 + NH3 → HC(O)NH2...
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Isocyanide (section From formamides)
developed. Commonly, isocyanides are synthesized by dehydration of formamides. The formamide can be dehydrated with toluenesulfonyl chloride, phosphorus oxychloride...
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undergo the denaturation process through various chemical agents such as formamide, guanidine, sodium salicylate, dimethyl sulfoxide (DMSO), propylene glycol...
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(alkanoyl) group (R−C(=O)−) joined to an amine group. Common of amides are formamide (H−C(=O)−NH2), acetamide (H3C−C(=O)−NH2), benzamide (C6H5−C(=O)−NH2),...
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Formamidase (redirect from Formamide amidohydrolase)
chemical reaction formamide + H2O ⇌ {\displaystyle \rightleftharpoons } formate + NH3 Thus, the two substrates of this enzyme are formamide and H2O, whereas...
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In enzymology, a N-substituted formamide deformylase (EC 3.5.1.91) is an enzyme that catalyzes the chemical reaction N-benzylformamide + H2O ⇌ {\displaystyle...
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called the Vilsmeier reaction) is the chemical reaction of a substituted formamide (1) with phosphorus oxychloride and an electron-rich arene (3) to produce...
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N-Formylmorpholine (category Formamides)
N-Formylmorpholine is the organic compound with the formula O(C2H4)2NCHO. It is the formamide of morpholine (O(C2H4)2NH). A colorless compound, it is a useful high...
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(3,4) bonds can also be formed from N-substituted α-aminoketones and formamide with heat. The product will be a 1,4-disubstituted imidazole, but here...
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hydrogen cyanide (HCN) and ammonia. Formamide produces all four ribonucleotides when warmed with terrestrial minerals. Formamide is ubiquitous in the Universe...
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Cyanobutadiynyl radical E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne...
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Cyanobutadiynyl radical E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne...
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accidentally by Rudolf Leuckart in the reaction of benzaldehyde with formamide in a process now known as the Leuckart reaction, a general process in...
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Cyanobutadiynyl radical E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne...
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parent compound of the imidic acids. H2NCH2OH → HNCHOH + H2 (tautomer of formamide) Geminal amino alcohols with side chains similarly form imidic acids with...
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functional groups from derivatives. Primary syntheses in quantity involving formamide have been reported.: 241–242 As a class, pyrimidines are typically synthesized...
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Cyanobutadiynyl radical E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne...
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therefore, essential. Methyl formate is used primarily to manufacture formamide, dimethylformamide, and formic acid. These compounds are precursors or...
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