L-selectride is a organoboron compound with the chemical formula Li[(CH3CH2CH(CH3))3BH]. A colorless salt, it is usually dispensed as a solution in THF...
4 KB (404 words) - 16:17, 15 October 2024
K-selectride is the organoboron compound with the formula KBH(C4H9)3. It is the potassium salt of tri(sec-butyl)borohydride. The compound is sold as solution...
2 KB (138 words) - 00:54, 16 October 2024
{\text{catalyst}}{\ce {Pd}}}][{\text{Base}}]R1-R2}}} Borane hydrides such as 9-BBN and L-selectride (lithium tri(sec-butyl)borohydride) are reducing agents. An asymmetric...
30 KB (2,992 words) - 19:24, 18 August 2024
reductive aminations. Lithium borohydride, a more strongly reducing reagent. L-selectride (lithium tri-sec-butylborohydride), a more strongly reducing derivative...
27 KB (2,615 words) - 13:44, 24 January 2024
more effective than using either lithium tert-butoxyaluminum hydride or L-Selectride. The CBS catalyst, usually prepared from diphenylprolinol, often can...
12 KB (1,406 words) - 20:37, 22 July 2024
the addition of L-selectride to a bulky germanium(II) chloride in ether, while the other was formed by the addition of L-selectride to the same germanium(II)...
18 KB (2,198 words) - 19:43, 15 August 2024
Shieh/Carlson and in the final step the ketone is reduced to the alcohol with L-selectride. This final step is enantioselective producing the desired S,S,R compound...
15 KB (1,662 words) - 02:08, 18 September 2024
the reducing strength. superhydride (lithium triethylborohydride) and L-selectride are strong reductant. They are correspondingly hazardous to handle. The...
24 KB (2,729 words) - 18:11, 13 November 2024
which was protected in the next step as the cyclic carbonate ester (34). L-Selectride reduction of enone 34 gave ketone 35. The ketone was converted into vinyl...
15 KB (1,399 words) - 13:35, 26 August 2024
position with in two steps PPC and sodium acetate (to the enone) and with K-selectride to alcohol 43 which was protected as a TES ether in 44. The synthesis...
11 KB (1,294 words) - 19:02, 27 November 2023