Matrix isolation is an experimental technique used in chemistry and physics. It generally involves a material being trapped within an unreactive matrix...
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Uranium trioxide (section Matrix isolation)
some work has been done on the molecular form in the gas phase, in matrix isolations studies, and computationally. At elevated temperatures gaseous UO3...
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(16): 1008. doi:10.1039/C29700001008. Poliakoff, Martyn (1973). The matrix isolation of large molecules. The photochemistry of transition metal carbonyls...
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degrades by a bimolecular process, the species can be observed by matrix isolation techniques at temperatures below 35 K. It is thought to adopt a rectangular...
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oxytrichloride as well as with chromyl chloride. The product was obtained by matrix isolation. It has also been reported relatively stable in a water-ethanol solution...
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observation of these reactive molecules are generally accomplished by matrix-isolation methods. The simplest non-Kekulé molecules are biradicals. A biradical...
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methylene were also studied around 1960 by infrared spectroscopy using matrix isolation experiments. Many of methylene's electronic states lie relatively close...
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Kulkarni; S.R. Gadre (2002). "H-π Complexes of acetylene-ethylene: A matrix isolation and computational study". J. Phys. Chem. A. 106 (8): 1504. Bibcode:2002JPCA...
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reactive that they exist only in gas phase or have only been detected by matrix isolation. Graphene oxide and other stable polymeric carbon oxides with unbounded...
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uniquely among the lanthanides, the +5 oxidation state is attainable in matrix-isolation conditions. The 0, +1, and +2 oxidation states are rarely found. Aqueous...
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Lapinski; J. S. Kwiatkowski; J. Leszczynski (1994). "Experimental matrix isolation and theoretical ab initio HF/6-31G(d, p) studies of infrared spectra...
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atom. However, compounds of argon have been detected in inert gas matrix isolation, cold gases, and plasmas, and molecular ions containing argon have...
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can these compounds be isolated and stored, e.g. low temperatures, matrix isolation. When their existence is indicated, reactive intermediates can help...
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terbium, neodymium and dysprosium, the last two known only under matrix isolation conditions. All of the lanthanides form trihalides with fluorine, chlorine...
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Millimeters Thick Optically Transparent Solid Parahydrogen Samples for Matrix Isolation Spectroscopy – Storming Media Bowers, C. R.; Weitekamp, D. P. (1986)...
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they are held in place within a matrix of transparent, insulating plastic or within an integrated circuit. Optical isolation is generally very limited in...
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studies of boron compounds. In 1981 he finished his habilitation on matrix isolation of reactive silicon oxides. He was Professor in Münster und...
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2007, when HgF4 was first prepared using solid neon and argon for matrix isolation at a temperature of 4 K. The compound was detected using infrared spectroscopy...
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N. Khabashesku; Z. A. Kerzina; K. N. Kudin; O. M. Nefedov (1998). "Matrix isolation infrared and density functional theoretical studies of organic silanones...
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HowStuffWorks. Retrieved 3 July 2008. Dunkin, I. R. (1980). "The matrix isolation technique and its application to organic chemistry". Chem. Soc. Rev...
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science education and public service. He developed the technique of matrix isolation in low-temperature chemistry. He also developed time-resolved infrared...
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a black solid. Lithium superoxide (LiO2) has only been isolated in matrix isolation at 15 K. Sodium superoxide (NaO2) is a yellow-orange solid that melts...
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triple bond (nitride) between P and N. It can be obtained in argon matrix isolation at 16 K by laser photolysis of phosphoryl triazide, OP(N3)3. OPN and...
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chloride, Ferrocenium tetrafluoroborate 4 (d4) Fe(diars) 2Cl2+ 2, FeO(BF4)2 5 (d3) FeO3− 4 6 (d2) Potassium ferrate 7 (d1) [FeO4]– (matrix isolation, 4K)...
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spectrometry, matrix-assisted laser desorption/ionization (MALDI) is an ionization technique that uses a laser energy-absorbing matrix to create ions...
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compound with the chemical formula (InH3). It has been observed in matrix isolation and laser ablation experiments. Gas phase stability has been predicted...
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Matrix metalloproteinases (MMPs), also known as matrix metallopeptidases or matrixins, are metalloproteinases that are calcium-dependent zinc-containing...
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chemical laser. George C. Pimentel United States for development of matrix isolation spectroscopy and for the discovery of photodissociation lasers and...
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Sr2MgIrO6 and Sr2CaIrO6. iridium(VIII) oxide (IrO4) was generated under matrix isolation conditions at 6 K in argon. The highest oxidation state (+9), which...
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Bridgeman, A. J.; Young, N. A. (2008). "Mercury-fluorine interactions: a matrix isolation investigation of Hg⋯F2, HgF2 and HgF4 in argon matrices". Phys Chem...
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