Relative to the more commonly encountered methylmagnesium bromide and methylmagnesium iodide, methylmagnesium chloride offers the advantages of low equivalent...

organic group, normally an alkyl or aryl. Two typical examples are methylmagnesium chloride Cl−Mg−CH3 and phenylmagnesium bromide (C6H5)−Mg−Br. They are a...

(trimethylsilyl)methyl chloride with butyllithium: (CH3)3SiCH2Cl + BuLi → (CH3)3SiCH2Li + BuCl (Trimethylsilyl)methylmagnesium chloride is often functionally...

Copper(I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly...

Iron(III) chloride describes the inorganic compounds with the formula FeCl3(H2O)x. Also called ferric chloride, these compounds are some of the most important...

of isobutylene, or by a Grignard reaction between acetone and methylmagnesium chloride. Purification cannot be performed by simple distillation due to...

diphenylbismuth chloride, first by methylation with methylmagnesium chloride. Treatment of the resulting methyldiphenylbismuthine with hydrogen chloride cleaves...

protonation of methyl lithium or a methyl Grignard reagent such as methylmagnesium chloride. It can also be made from anhydrous sodium acetate and dry sodium...

Alkylmagnesium halide RMgX (X=Cl, Br, I)[note 1] -magnesium halide methylmagnesium chloride Alkylaluminium Al2R6 -aluminium trimethylaluminium Silyl ether...

sodium borohydride. Alternatively, benzaldehyde can be reacted with methylmagnesium chloride or similar organometallic compounds to afford racemic 1-phenylethanol...

gallium(III) chloride with various alkylating agents, such as dimethylzinc, trimethylaluminium, or methylmagnesium iodide. Gallium(III) chloride is an intermediate...

Trimethylsilyldiazomethane can be prepared by treating (trimethylsilyl)methylmagnesium chloride with diphenyl phosphorazidate. An isotopically labelled variant...

The Petasis reagent, Cp2Ti(CH3)2, is prepared from the action of methylmagnesium chloride or methyllithium on Cp2TiCl2. This reagent is useful for the conversion...

organolithium reagents. For example, the reaction of C60 with methylmagnesium chloride stops quantitatively at the penta-adduct with the methyl groups...

When treated with methylmagnesium iodide, it give tetramethyldiphosphine disulfide (H3C−)2P(=S)−P(=S)(−CH3)2. Thiophosphoryl chloride: trade names Thiophosphoryl...

Related compounds Related compounds Phenyllithium Magnesium bromide Methylmagnesium chloride Dibutylmagnesium Except where otherwise noted, data are given for...

lactone 20 (acetic anhydride, sodium acetate) and reaction with methylmagnesium chloride gave tetracyclic ketone 21. Treatment with periodic acid (dioxane)...

Petasis reagent is prepared by the salt metathesis reaction of methylmagnesium chloride or methyllithium with titanocene dichloride: Cp2TiCl2 + 2 CH3MgCl...

PMe3 can be prepared by the treatment of triphenyl phosphite with methylmagnesium chloride: 3 CH3MgCl + P(OC6H5)3 → P(CH3)3 + 3 C6H5OMgCl The synthesis is...

a prochiral dienophile. It is a Michael acceptor. Addition of methylmagnesium chloride produces 3-penten-2-ol. Polyurethane catalyst N,N,N′,N′-tetramethyl-1...

derived from Grignard reagents and lead chloride. For example, methylmagnesium chloride reacts with lead chloride to tetramethyllead, a water-clear liquid...

+ 3 LiCl Such reactions more commonly employ the Grignard reagents methylmagnesium halides, which are often equally effective, and less expensive or more...

protecting group. In the first step, the methyl ester is reacted with methylmagnesium bromide to form the tertiary alcohol. The acetonide is then deprotected...

dienone (2), and reaction of that compound with methylmagnesium bromide in the presence of cuprous chloride leads to addition of the methyl group to position...

structures. Methyldichloroarsine is produced by the reaction of methylmagnesium chloride and arsenic trichloride: AsCl3 + CH3MgCl → CH3AsCl2 + MgCl2 Typically...

Tc(dmpe)2(CO)2Cl, and Ni(dmpe)Cl2. It is synthesised by the reaction of methylmagnesium iodide with 1,2-bis(dichlorophosphino)ethane: Cl2PCH2CH2PCl2 + 4 MeMgI...

Kinetics of the Reaction of Dimethylmagnesium with Benzophenone and of Methylmagnesium Bromide-Magnesium Bromide with Pinacolone". The Journal of Organic...

the catecholboronate ester to trialkylborane by diethyl zinc or methylmagnesium chloride. Reaction of the trialkylborane with hydroxylamine-O-sulfonic acid...

ethyl acetoacetate gave β-keto-ester 3. A Grignard reaction involving methylmagnesium bromide provided alcohol 4, which was subjected to acid catalyzed elimination...

describing this reaction, methylmagnesium bromide is reacted with isophorone with and without 1 mole percent of added copper(I) chloride (see figure). Without...