Organosodium chemistry is the chemistry of organometallic compounds containing a carbon to sodium chemical bond. The application of organosodium compounds...

organometallic chemistry include: Period 2 elements: organolithium chemistry, organoberyllium chemistry, organoborane chemistry Period 3 elements: organosodium chemistry...

acetylene and acetone. Alkylation Methylation Organolithium reagent Organosodium chemistry Sonogashira coupling Glaser coupling Cadiot–Chodkiewicz coupling...

such as Grignard (organomagnesium), organolithium, organocopper, and organosodium reagents. These compounds typically can add to an electron-deficient...

Na+-phenyl interactions. As such the salt could be classified as an organosodium compound. Addition of sodium tetraphenylborate to a solution of a tertiary...

stable in ionic compounds. It can also form intermetallic compounds and organosodium compounds. Sodium compounds are often soluble in water. Metallic sodium...

halide, increasing the probability that the alkyl halide will form the organosodium bond first and thus act more effectively as a nucleophile toward the...

cryptands to solutions of sodium in ammonia via disproportionation. Many organosodium compounds have been prepared. Because of the high polarity of the C-Na...

alkali metals are predominantly ionic. The application of organosodium compounds in chemistry is limited in part due to competition from organolithium...

anion sodium naphthalene to styrene. The results in the formation of an organosodium species, which rapidly added styrene to form a "two – ended living polymer...

organometallic compound with the idealized formula NaC4H9. Like other simple organosodium compounds, it is polymeric and highly basic. In contrast to n-butyllithium...

base of dimethyl sulfoxide. This unusual salt has some uses in organic chemistry as a base and nucleophile. Since the first publication in 1965 by Corey...

and [NMe4]+[PhCH2]−, respectively, by metathesis of the corresponding organosodium reagent with tetramethylammonium chloride. Since tetramethylammonium...

Sodium cyclopentadienide is an organosodium compound with the formula C5H5Na. The compound is often abbreviated as NaCp, where Cp− is the cyclopentadienide...

reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes...

1021/jo01348a012. However, see Wurtz coupling for cases where an in situ generated organosodium reagent reacts with an alkyl halide. Lipshutz, Bruce H. (2002). Schlosser...