Organosodium chemistry is the chemistry of organometallic compounds containing a carbon to sodium chemical bond. The application of organosodium compounds...
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organometallic chemistry include: Period 2 elements: organolithium chemistry, organoberyllium chemistry, organoborane chemistry Period 3 elements: organosodium chemistry...
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Alkynylation (category Organometallic chemistry)
acetylene and acetone. Alkylation Methylation Organolithium reagent Organosodium chemistry Sonogashira coupling Glaser coupling Cadiot–Chodkiewicz coupling...
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such as Grignard (organomagnesium), organolithium, organocopper, and organosodium reagents. These compounds typically can add to an electron-deficient...
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Na+-phenyl interactions. As such the salt could be classified as an organosodium compound. Addition of sodium tetraphenylborate to a solution of a tertiary...
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Sodium compounds (section Organosodium compounds)
stable in ionic compounds. It can also form intermetallic compounds and organosodium compounds. Sodium compounds are often soluble in water. Metallic sodium...
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halide, increasing the probability that the alkyl halide will form the organosodium bond first and thus act more effectively as a nucleophile toward the...
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Sodium (section Organosodium compounds)
cryptands to solutions of sodium in ammonia via disproportionation. Many organosodium compounds have been prepared. Because of the high polarity of the C-Na...
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alkali metals are predominantly ionic. The application of organosodium compounds in chemistry is limited in part due to competition from organolithium...
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anion sodium naphthalene to styrene. The results in the formation of an organosodium species, which rapidly added styrene to form a "two – ended living polymer...
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N-Butylsodium (category Organosodium compounds)
organometallic compound with the idealized formula NaC4H9. Like other simple organosodium compounds, it is polymeric and highly basic. In contrast to n-butyllithium...
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Sodium methylsulfinylmethylide (category Organosodium compounds)
base of dimethyl sulfoxide. This unusual salt has some uses in organic chemistry as a base and nucleophile. Since the first publication in 1965 by Corey...
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and [NMe4]+[PhCH2]−, respectively, by metathesis of the corresponding organosodium reagent with tetramethylammonium chloride. Since tetramethylammonium...
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Sodium cyclopentadienide (category Organosodium compounds)
Sodium cyclopentadienide is an organosodium compound with the formula C5H5Na. The compound is often abbreviated as NaCp, where Cp− is the cyclopentadienide...
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Sodium naphthalene (category Organosodium compounds)
reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes...
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1021/jo01348a012. However, see Wurtz coupling for cases where an in situ generated organosodium reagent reacts with an alkyl halide. Lipshutz, Bruce H. (2002). Schlosser...
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