Dess–Martin periodinane (DMP) is a chemical reagent used in the Dess–Martin oxidation, oxidizing primary alcohols to aldehydes and secondary alcohols...
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Periodinanes also known as λ5-iodanes are organoiodine compounds with iodine in the +5 oxidation state. These compounds are described as hypervalent because...
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2-Iodoxybenzoic acid (category Periodinanes)
organic compound used in organic synthesis as an oxidizing agent. This periodinane is especially suited to oxidize alcohols to aldehydes. IBX is most often...
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Dess–Martin periodinane. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the periodinane reagent in...
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common uses is as a precursor for the preparation of IBX and Dess–Martin periodinane, both used as mild oxidants. 2-Iodobenzoic acid can be synthesized by...
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oxidation Albright-Goldman oxidation Corey–Kim oxidation Dess–Martin periodinane oxidation Ley oxidation (TPAP oxidation) TEMPO oxidation Omura, K.; Swern...
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solution of chromium trioxide in aqueous sulfuric acid. The Dess–Martin periodinane is a mild oxidant for the conversion of alcohols to aldehydes or ketones...
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oxidations, and hypervalent iodine compounds, such as the Dess–Martin periodinane. One disadvantage to the use of PCC is its toxicity, which it shares...
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C. (1991). "A useful 12-I-5 triacetoxyperiodinane (The Dess-Martin periodinane) for the selective oxidation of primary or secondary alcohols and a variety...
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or a Cr(VI) compound. Milder conditions make use of the Dess–Martin periodinane or the Moffatt–Swern methods. Many other methods have been developed...
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secondary alcohols to ketones. These include Collins reagent and Dess-Martin periodinane. The direct oxidation of primary alcohols to carboxylic acids can be...
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the hypervalent organoiodine compounds (i.e., IBX acid, Dess–Martin periodinane), although these often also oxidize the α position. A Lux-Flood acid...
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October 2017. Boeckman Jr RK, Shao P, Mullins JJ (2000). "Dess–Martin periodinane: 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one" (PDF). Organic...
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oxidation methods such as pyridinium chlorochromate (PCC) and Dess–Martin periodinane is that secondary alcohols are oxidized much faster than primary alcohols...
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applications ranging from organic synthesis to cloud seeding Dess–Martin periodinane chemical reagent used to oxidize primary alcohols to aldehydes and secondary...
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and explosive, but acetylation tempers it to the stabler Dess-Martin periodinane. Aliphatic hypoiodites can be synthesized through a variant on the Williamson...
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bidentate ligand and a tridentate analog, co-invented the Dess–Martin periodinane, creator of the Martin sulfurane Emil Wolfgang Menzel Jr. (Ph.D. 1958)...
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memory-dependent prefetcher, part of some CPU architectures Dess–Martin periodinane, a chemical reagent used to oxidise alcohols Dot matrix printer, a type...
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Vicente Samano, Mark D. Johnson: "Nucleic acid-related compounds. 58. Periodinane oxidation, selective primary deprotection, and remarkably stereoselective...
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heteroatom functionality that may coordinate to chromium. Dess-Martin periodinane (DMP) offers the advantages of operational simplicity, a lack of heavy...
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Dess may refer to : Dess–Martin periodinane, a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones Albert...
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to be used as the terminal oxidant. Compared to chromium-, DMSO-, or periodinane-mediated oxidations, this proves safe, environmentally-friendly, practical...
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compounds are useful reagents in organic chemistry (e.g. Dess–Martin periodinane) Tetra-, penta- and hexavalent phosphorus, silicon, and sulfur compounds...
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his doctoral student Daniel Benjamin Dess, he invented the Dess–Martin periodinane that is used for selective oxidation of alcohols. He is also known for...
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alcohol 8 which is subsequently oxidized to ketone 9 with Dess-Martin periodinane. Cyanophosphorylation with diethyl phosphorocyanidate (DEPC) modifies...
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the furanone is oxidized to 3-isopropylfuran-2,5-dione by Dess–Martin periodinane, followed by acetic acid reflux with beta-alanine. The white powdered...
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Organofluorine compounds Organochlorine compounds Organobromine compounds Iodanes Periodinanes Alex G. Fallis, Pierre E. Tessier, "2-Iodoxybenzoic acid (IBX)1" Encyclopedia...
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methods for reactions of diols and acetylenic alcohols. Dess-Martin periodinane is a highly selective, mild oxidant of alcohols, whose primary disadvantages...
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sulfonium-based methods are oxidations with hypervalent iodine (e.g., Dess-Martin periodinane, 2-Iodoxybenzoic acid) chromium reagents (e.g., Pyridinium chlorochromate...
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October 2017. Boeckman Jr RK, Shao P, Mullins JJ (2000). "Dess–Martin periodinane: 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one" (PDF). Organic...
30 KB (3,558 words) - 02:08, 12 September 2024