• Thumbnail for Dess–Martin periodinane
    Dess–Martin periodinane (DMP) is a chemical reagent used in the Dess–Martin oxidation, oxidizing primary alcohols to aldehydes and secondary alcohols...
    12 KB (1,197 words) - 03:33, 24 June 2024
  • Thumbnail for Periodinane
    Periodinanes also known as λ5-iodanes are organoiodine compounds with iodine in the +5 oxidation state. These compounds are described as hypervalent because...
    2 KB (256 words) - 20:03, 25 February 2024
  • Thumbnail for 2-Iodoxybenzoic acid
    2-Iodoxybenzoic acid (category Periodinanes)
    organic compound used in organic synthesis as an oxidizing agent. This periodinane is especially suited to oxidize alcohols to aldehydes. IBX is most often...
    12 KB (1,183 words) - 00:49, 25 June 2024
  • Thumbnail for Dess–Martin oxidation
    Dess–Martin periodinane. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the periodinane reagent in...
    3 KB (269 words) - 22:26, 27 September 2024
  • Thumbnail for 2-Iodobenzoic acid
    common uses is as a precursor for the preparation of IBX and Dess–Martin periodinane, both used as mild oxidants. 2-Iodobenzoic acid can be synthesized by...
    2 KB (89 words) - 15:55, 7 September 2024
  • oxidation Albright-Goldman oxidation Corey–Kim oxidation Dess–Martin periodinane oxidation Ley oxidation (TPAP oxidation) TEMPO oxidation Omura, K.; Swern...
    9 KB (1,019 words) - 17:16, 26 December 2023
  • solution of chromium trioxide in aqueous sulfuric acid. The Dess–Martin periodinane is a mild oxidant for the conversion of alcohols to aldehydes or ketones...
    14 KB (1,578 words) - 10:23, 11 August 2024
  • Thumbnail for Pyridinium chlorochromate
    oxidations, and hypervalent iodine compounds, such as the Dess–Martin periodinane. One disadvantage to the use of PCC is its toxicity, which it shares...
    10 KB (780 words) - 18:59, 14 July 2024
  • Thumbnail for Cyclooctanone
    C. (1991). "A useful 12-I-5 triacetoxyperiodinane (The Dess-Martin periodinane) for the selective oxidation of primary or secondary alcohols and a variety...
    2 KB (149 words) - 00:21, 26 September 2024
  • Thumbnail for Ketone
    or a Cr(VI) compound. Milder conditions make use of the Dess–Martin periodinane or the Moffatt–Swern methods. Many other methods have been developed...
    24 KB (2,895 words) - 17:58, 14 September 2024
  • Thumbnail for Alcohol (chemistry)
    secondary alcohols to ketones. These include Collins reagent and Dess-Martin periodinane. The direct oxidation of primary alcohols to carboxylic acids can be...
    35 KB (3,828 words) - 21:16, 17 September 2024
  • Thumbnail for Aldehyde
    the hypervalent organoiodine compounds (i.e., IBX acid, Dess–Martin periodinane), although these often also oxidize the α position. A Lux-Flood acid...
    29 KB (3,003 words) - 01:22, 16 July 2024
  • Thumbnail for Iodine
    October 2017. Boeckman Jr RK, Shao P, Mullins JJ (2000). "Dess–Martin periodinane: 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one" (PDF). Organic...
    107 KB (11,980 words) - 14:44, 28 September 2024
  • oxidation methods such as pyridinium chlorochromate (PCC) and Dess–Martin periodinane is that secondary alcohols are oxidized much faster than primary alcohols...
    12 KB (1,250 words) - 17:28, 13 May 2022
  • applications ranging from organic synthesis to cloud seeding Dess–Martin periodinane chemical reagent used to oxidize primary alcohols to aldehydes and secondary...
    15 KB (264 words) - 18:51, 14 August 2022
  • and explosive, but acetylation tempers it to the stabler Dess-Martin periodinane. Aliphatic hypoiodites can be synthesized through a variant on the Williamson...
    18 KB (1,940 words) - 17:18, 30 June 2024
  • bidentate ligand and a tridentate analog, co-invented the Dess–Martin periodinane, creator of the Martin sulfurane Emil Wolfgang Menzel Jr. (Ph.D. 1958)...
    312 KB (30,979 words) - 02:06, 11 September 2024
  • memory-dependent prefetcher, part of some CPU architectures Dess–Martin periodinane, a chemical reagent used to oxidise alcohols Dot matrix printer, a type...
    3 KB (364 words) - 03:40, 27 July 2024
  • Thumbnail for Protecting group
    Vicente Samano, Mark D. Johnson: "Nucleic acid-related compounds. 58. Periodinane oxidation, selective primary deprotection, and remarkably stereoselective...
    57 KB (6,755 words) - 23:19, 9 April 2024
  • heteroatom functionality that may coordinate to chromium. Dess-Martin periodinane (DMP) offers the advantages of operational simplicity, a lack of heavy...
    10 KB (1,163 words) - 15:58, 17 November 2023
  • Dess may refer to : Dess–Martin periodinane, a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones Albert...
    831 bytes (141 words) - 20:19, 13 July 2024
  • to be used as the terminal oxidant. Compared to chromium-, DMSO-, or periodinane-mediated oxidations, this proves safe, environmentally-friendly, practical...
    20 KB (2,216 words) - 21:53, 25 July 2024
  • compounds are useful reagents in organic chemistry (e.g. Dess–Martin periodinane) Tetra-, penta- and hexavalent phosphorus, silicon, and sulfur compounds...
    39 KB (4,486 words) - 20:28, 22 July 2024
  • Thumbnail for James Cullen Martin
    his doctoral student Daniel Benjamin Dess, he invented the Dess–Martin periodinane that is used for selective oxidation of alcohols. He is also known for...
    4 KB (321 words) - 12:36, 29 July 2024
  • Thumbnail for Oseltamivir total synthesis
    alcohol 8 which is subsequently oxidized to ketone 9 with Dess-Martin periodinane. Cyanophosphorylation with diethyl phosphorocyanidate (DEPC) modifies...
    20 KB (2,309 words) - 12:58, 25 October 2023
  • Thumbnail for Farinomalein
    the furanone is oxidized to 3-isopropylfuran-2,5-dione by Dess–Martin periodinane, followed by acetic acid reflux with beta-alanine. The white powdered...
    3 KB (212 words) - 13:56, 22 August 2022
  • Organofluorine compounds Organochlorine compounds Organobromine compounds Iodanes Periodinanes Alex G. Fallis, Pierre E. Tessier, "2-Iodoxybenzoic acid (IBX)1" Encyclopedia...
    11 KB (1,317 words) - 10:04, 6 January 2024
  • Thumbnail for Oxoammonium-catalyzed oxidation
    methods for reactions of diols and acetylenic alcohols. Dess-Martin periodinane is a highly selective, mild oxidant of alcohols, whose primary disadvantages...
    13 KB (1,647 words) - 14:54, 28 March 2022
  • sulfonium-based methods are oxidations with hypervalent iodine (e.g., Dess-Martin periodinane, 2-Iodoxybenzoic acid) chromium reagents (e.g., Pyridinium chlorochromate...
    6 KB (729 words) - 16:41, 12 June 2023
  • October 2017. Boeckman Jr RK, Shao P, Mullins JJ (2000). "Dess–Martin periodinane: 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one" (PDF). Organic...
    30 KB (3,558 words) - 02:08, 12 September 2024