Pinacolborane is the borane with the formula (CH3)4C2O2BH. Often pinacolborane is abbreviated HBpin. It features a boron hydride functional group incorporated...

acidic conditions. The B-B bond length is 1.711(6) Å. Dehydrogenation of pinacolborane provides an alternative route: 2 (CH3)4C2O2BH → (CH3)4C2O2B-BO2C2(CH3)4...

boron trichloride to produce useful synthetic intermediates such as pinacolborane, bis(pinacolato)diboron, and pinacolchloroborane. Pinacol coupling reaction...

stoichiometric equivalent rather than a large excess using the cheaper pinacolborane: Unlike in ordinary electrophilic aromatic substitution (EAS) where...

of alkenes. Hydroborations have been studied with catecholborane and pinacolborane. It is also active for the hydrosilylation of alkenes. In the presence...

catalytic hydroboration, pinacolborane and catecholborane are widely used. They also exhibit higher reactivity toward alkynes. Pinacolborane is also widely used...

aryloxy groups that diminish the Lewis acidity of the boron centre. Pinacolborane adopts a similar structure. Catecholborane is less reactive in hydroborations...

Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane". Journal of the American Chemical Society. 135 (30): 10978–10981. doi:10...

compounds, especially those derived from catecholborane and the related pinacolborane, are intermediates in transition metal-catalyzed borylation reactions...

2-migratory insertion (M.I.), a transmetalation can take place with pinacolborane (HBPin) to produce the hydroborated product and regenerate ligated copper...

developed by Mankad (Scheme 5). Bimetallic cleavage of the B-H bond in pinacolborane generates a copper hydride (IPrCu-H) and an iron boryl [(pin)B-Fp],...

organoboronic acids, and addition and coupling reactions of diborons and pinacolborane for the synthesis of organoboronic esters. Working with Akira Suzuki...

upon reaction with N2O. In either case, reduction of the product with pinacolborane (HBpin) returns the bismuth(III) centers to the bismuth(I) state and...