Samarium(II) iodide is an inorganic compound with the formula SmI2. When employed as a solution for organic synthesis, it is known as Kagan's reagent...
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with samarium(II) iodide involve the conversion of various classes of organic compounds into reduced products through the action of samarium(II) iodide, a...
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Samarium(III) iodide is an inorganic compound, a salt of samarium and hydroiodic acid with the chemical formula SmI 3. Samarium(III) iodide is prepared...
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SmSe and SmTe, as well as samarium(II) iodide. Discovered in 1879 by French chemist Paul-Émile Lecoq de Boisbaudran, samarium was named after the mineral...
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Samarium iodide may refer to: samarium(II) iodide (samarium diiodide), SmI2 samarium(III) iodide (samarium triiodide), SmI3 This set index article lists...
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1,2-Diiodoethane (redirect from Ethylene iodide)
commonly used in organic synthesis in the preparation of samarium(II) iodide or ytterbium(II) iodide in an inert solvent such as THF. Sm + ICH2CH2I → SmI2...
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carbon-carbon bond formation in a large monocyclic ring. An example is the samarium(II) iodide induced ketone - alkene cyclization of 5-methylenecyclooctanone which...
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of metals, notably samarium(II) iodide, chromium(II) chloride, titanium(II) chloride, cerium(III) halides such as cerium(III) iodide, and titanocene(III)...
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(chloride, bromide, iodide), a carbonyl group and a metal. The reaction can be performed using magnesium, aluminium, zinc, indium, tin, samarium, barium or their...
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especially in conjunction with samarium(II) iodide. Like many nickel complexes, those derived from hydrated nickel iodide have been used in cross coupling...
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Lanthanide (section Ln(II) and Ln(IV) compounds)
Many of the iodides form soluble complexes with ethers, e.g. TmI2(dimethoxyethane)3. Samarium(II) iodide is a useful reducing agent. Ln(II) complexes can...
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active metals or salts (sodium amalgam, aluminium amalgam, magnesium, samarium(II) iodide), tin hydrides (tributyltin hydride), or transition metal complexes...
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oxide – RuO2 Samarium(II) iodide – SmI2 Samarium(III) chloride – SmCl3 Samarium(III) oxide – Sm2O3 Samarium(III) bromide – SmBr3 Samarium(III) carbonate...
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Samarium(III) oxyiodide is an inorganic compound with the chemical formula SmOI. It can be obtained by reacting samarium(II) iodide with dry oxygen. It...
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Samarium(III) chloride, also known as samarium trichloride, is an inorganic compound of samarium and chloride. It is a pale yellow salt that rapidly absorbs...
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of samarium(III) chloride with samarium metal in a vacuum at a temperature of 800 °C to 900 °C, or with hydrogen gas at 350 °C yields samarium(II) chloride:...
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Ytterbium (section Yb(II) vs. Yb(III))
the Aldol and Diels–Alder reactions. Ytterbium(II) iodide (YbI2) may be used, like samarium(II) iodide, as a reducing agent for coupling reactions. Ytterbium(III)...
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Neodymium(II) iodide or neodymium diiodide is an inorganic salt of iodine and neodymium the formula NdI2. Neodymium uses the +2 oxidation state in the...
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can therefore only be determined imprecisely. Like samarium(II) iodide (SmI2), ytterbium(II) iodide is a reagent used in organic chemical reactions. G...
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to heterocycles using a sulfur linker cleaved by reduction with samarium (II) iodide at University of Glasgow and successfully gained her PhD in 2006...
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derivatives can be obtained with high diastereoselectivity in a system of samarium(II) iodide and HMPA. A titanium-catalyzed photocatalytic approach was also developed:...
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10361–82–7 SmF2 samarium(II) fluoride 15192–17–3 SmF3 samarium(III) fluoride 13765–24–7 SmI2 samarium(II) iodide 32248–43–4 SmI3 samarium(III) iodide 13813–25–7...
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tetraacetate gave ketone 46. The epoxide protecting group was removed with samarium (II) iodide to give α-ß-unsaturated ketone 47. The enolate was formed by the...
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desulfurization Sakaguchi's Reagent Detects the presence of arginine Samarium(II) iodide (Kagan Reagent) a powerful reducing agent Silver oxide used to prepare...
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Samarium(II) fluoride is one of fluorides of samarium with a chemical formula SmF2. The compound crystalizes in the fluorite structure, and is significantly...
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Samarium(II) bromide is an inorganic compound with the chemical formula SmBr 2. It is a brown solid that is insoluble in most solvents but degrades readily...
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16 in 90% yield. The hydroxyl group was reductively removed using samarium(II) iodide to give an enol, and chromatography of this enol on silica gel gave...
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reduce alkali cations) compounds. Of these divalent lanthanides, Samarium(II) iodide, SmI2, is a common reducing agent that is used in a variety of synthetic...
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compounds Samarium(II) chloride (SmCl2) Samarium(II) iodide (SmI2) Samarium(III) chloride hexahydrate (SmCl3·6H2O) Samarium(III) nitrate (Sm(NO3)3) Samarium(III)...
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possible in the presence of a one-electron reducing agent such as samarium(II) iodide. (9) Benzylic cations of chromium arene complexes are conformationally...
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