Titanocene dichloride is the organotitanium compound with the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common...

metallocenes are the metallocene derivatives, e.g. titanocene dichloride or vanadocene dichloride. Certain metallocenes and their derivatives exhibit...

Titanocene Y also known as bis[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dichloride or dichloridobis(η5-(p-methoxybenzyl)cyclopentadienyl)titanium...

Vanadocene dichloride is an organometallic complex with formula (η5-C5H5)2VCl2 (commonly abbreviated as Cp2VCl2). It is a structural analogue of titanocene dichloride...

ExCl2, to afford titanocene dichloride and various S5+x and S5Sex rings. Illustrative is the synthesis of S7 from disulfur dichloride: (C5H5)2TiS5 + S2Cl2...

reduction of aldehydes. Cp2Ti(CO)2 is prepared by the reduction of titanocene dichloride with magnesium as a slurry in THT under an atmosphere of carbon...

Zirconocene dichloride is an organozirconium compound composed of a zirconium central atom, with two cyclopentadienyl and two chloro ligands. It is a colourless...

is an aluminium-containing derivative of titanocene that arises from the reaction of titanocene dichloride with trimethylaluminium. It is used for the...

1861, the first example was not reported until 1954. In that year titanocene dichloride was described by Wilkinson and Birmingham. Independently, titanium-based...

intensively studied. The most common organotitanium complex is titanocene dichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and Petasis...

contiguous (connected to each other), the η-notation is used, as e.g. in titanocene dichloride: dichlorobis(η5-2,4-cyclopentadien-1-yl)titanium. Molecules with...

via salt metathesis reactions. Illustrative is the methylation of titanocene dichloride to give the Petasis reagent: (C5H5)2TiCl2 + 2 ClMgCH3 → (C5H5)2Ti(CH3)2...

catalysts have the composition Cp2MCl2 (M = Ti, Zr, Hf) such as titanocene dichloride. Typically, the organic ligands are derivatives of cyclopentadienyl...

ketones, is prepared from TMA and titanocene dichloride. In combination with 20 to 100 mol % Cp2ZrCl2 (zirconocene dichloride), the (CH3)2Al-CH3 adds "across"...

angle defined by the two Cp rings. In titanocene dichloride, this angle is 58.5° whereas in the ansa-titanocene Me2Si(C5H4)2TiCl2 the angle is 51.2°....

Molybdocene dichloride is the organomolybdenum compound with the formula (η5-C5H5)2MoCl2 and IUPAC name dichlorobis(η5-cyclopentadienyl)molybdenum(IV)...

metathesis reaction of methylmagnesium chloride or methyllithium with titanocene dichloride: Cp2TiCl2 + 2 CH3MgCl → Cp2Ti(CH3)2 + 2 MgCl2 This compound is used...

some organic solvents. The lighter homologues zirconacene dichloride and titanocene dichloride have received much more attention. While hafnocene is only...

[Au(SH)2]− and (C5H5)2Ti(SH)2, derived from gold(I) chloride and titanocene dichloride, respectively. Bisulfide salts are corrosive, strongly alkaline...

follows with preservation of conformation via elemental zinc or with titanocene dichloride. Protection through a Diels-Alder reaction: the transformation of...

HOMO in this class of complex. Unlike the related zirconacene and titanocene dichlorides, no applications have been found for this compound, although it...

precursor to many organotitanium complexes. The complex is related to titanocene dichloride, which lacks the methyl groups. The complex is prepared by the reaction...

tetrachloride, titanocene dichloride, Schwartz's reagent. d1 Examples: molybdenum(V) chloride, vanadyl acetylacetonate, vanadocene dichloride, vanadium tetrachloride...

a main group metal (Al). The Tebbe reagent is synthesized from titanocene dichloride and trimethylaluminium in toluene solution. Cp2TiCl2 + 2 Al(CH3)3...

photocatalytic approach was also developed: the use of catalytic titanocene dichloride in the presence of a red-absorbing organic dye as the photosensitizer...

(N-bromosuccinimide, tBuOH/H2O then triethylamine) to 3, radical cyclisation (titanocene dichloride, manganese, triethylborane, 2,6-lutidine) to 4, alcohol protection...

1955 by Geoffrey Wilkinson It is commonly prepared by reducing titanocene dichloride with zinc, manganese, or magnesium. For use in organic synthesis...

titanocene or zirconocene dichloride with magnesium in the presence of bis(trimethylsilyl)acetylene in THF. The illustrated product for a titanocene complex...

range near 2.35 Å. The complex can be prepared by the reaction of titanocene dichloride, butyllithium, and cycloheptatriene. (Cycloheptatrienyl)(cyclopentadienyl)vanadium...

hydrolysis Another reagent is generated in situ by treatment of titanocene dichloride with zinc. That blue green Ti(III)-containing solution is highly...