Trimethylphosphine is an organophosphorus compound with the formula P(CH3)3, commonly abbreviated as PMe3. This colorless liquid has a strongly unpleasant...

Hexakis(trimethylphosphine)tungsten is a tungsten(0) organometallic compound with the formula W(P(CH3)3)6. It is a yellow crystalline solid soluble in...

Tetrakis(trimethylphosphine)tungsten(II) trimethylphospinate hydride (W(PMe3)4(η2-CH2PMe2)H) is an air-sensitive organotungsten complex with tungsten in...

synthesis of organic compounds containing phosphorus, which he named "trimethylphosphine" and "triethylphosphine", in analogy with "amine" (organo-nitrogen...

3 HOC6H5 → P(OC6H5)3 + 3 HCl Triphenylphosphite is a precursor to trimethylphosphine, it serves as a source of P3+ that is less electrophilic than phosphorus...

triethylphosphine gained acceptance earlier than did the simpler trimethylphosphine, as illustrated by the preparation of the hydride complex trans-PtHCl(PEt3)2...

tetramethylphosphonium and the bromide anion. It is prepared by treating trimethylphosphine with methyl bromide. Deprotonation gives methylenetrimethylphosphine...

present. SnBr4 forms 1:1 and 1:2 complexes with ligands, e.g. with trimethylphosphine the following can be produced, SnBr4.P(CH3)3 and SnBr4.2P(CH3)3. Greenwood...

Pyridine N 128 Acetonitrile N 60 DMA O 112 DMSO O 105 THF O 90.4 Et2O O 78.8 Acetone O 76.0 EtOAc O 75.5 Trimethylphosphine P 97.3 Tetrahydrothiophene S 51.6...

organolithium compounds: 3 RMgX + PCl3 → PR3 + 3 MgX2 In the case of trimethylphosphine, triphenyl phosphite is used in place of the highly electrophilic...

in low oxidation states. It is cheaper and less air-sensitive than trimethylphosphine and other trialkylphosphines. Although its complexes are generally...

dichlorotrimethyltantalum has also been reported with trimethylphosphine by Sattler. Trimethylphosphine was introduced by vapour transfer to dichlorotrimethyltantalum...

2]pentane 39 °C Ruthenium(VIII) oxide 40 °C Nickel carbonyl 42.1 °C Trimethylphosphine 43 °C Gallane liquid decomposes at 0 °C. Nitroxyl and diazene are...

produced by anaerobic bacteria in antimony-rich soils. In contrast to trimethylphosphine, trimethylstibine is a weaker Lewis base. It is used in the production...

preparation of zirconocene complex by reaction diphenylzirconocene with trimethylphosphine. Cp2ZrPh2 + PMe3 → Cp2Zr(C6H4)(PMe3) + PhH The preparation of Ta(η5-C5Me5)(C6H4)Me2...

monodentate Triethylenetetramine (trien) C6H18N4 neutral tetradentate Trimethylphosphine P(CH3)3 neutral monodentate Tris(o-tolyl)phosphine P(o-tolyl)3 neutral...

(SDS) Fisher Scientific Related compounds Related tertiary phosphines Trimethylphosphine Phosphine Related compounds Triphenylamine Triphenylarsine Triphenylstibine...

It is Lewis acidic, forming double adducts with two equivalents of trimethylphosphine. Pentaborane is used for the synthesis of other boron hydride clusters...

Trimethyl phosphite 923 Dimethylamine 923 Pyridine 924 Trimethylamine 942 Trimethylphosphine 950 Triethylphosphine 969 Triethylamine 972 Lithium hydroxide 1008...

acids, with concomitant opening of the cluster. An example involving trimethylphosphine: B5H9 + 2 P(CH3)3 → B5H9·2P(CH3)3 Some higher boranes, especially...

Masaki; Dahl, Lawrence F. (2001). "High-nuclearity palladium carbonyl trimethylphosphine clusters containing unprecedented face-condensed icosahedral-based...

converted into aziridines with the use of trialkyl phosphines such as trimethylphosphine or tributylphosphine. Aziridines are reactive substrates in ring-opening...

has a smaller cone angle and better acceptor properties relative to trimethylphosphine. A representative derivative is the colorless tetrahedral complex...

"Bis(η5-2,4-cyclopentadienyl)bis(trimethylphosphine)titanium". Bis(5-2,4-cyclopentadienyl)bis(trimethylphosphine)titanium. Encyclopedia of Reagents...

dimethyldiborane: (CH3)BH2.BH3 and (CH3)2BH.BH3. It reacts as a gas with trimethylphosphine to form a solid Lewis salt with a heat of formation of −41 kcal per...

trihydrazide 10105-42-7 C3H9OP trimethylphosphine oxide 676-96-0 C3H9PS dimethyl methylthiophosphine 35449-60-6 C3H9PS trimethylphosphine sulfide 2404-55-9 C3H9PSe...

Related compounds Cacodylic acid Triphenylarsine Pentamethylarsenic Trimethylphosphine Trimethylamine Supplementary data page Trimethylarsine (data page)...

atoms linked to the metal atom. This was first shown in 2003. The bis(trimethylphosphine) thiirane S-oxide complex of platinum, when heated in toluene at 110 °C...

diethyl ether, tri(n‐butyl)phosphate, butylamine, dimethylamine, and trimethylphosphine oxide. New Jersey Department of Health. Thorium Nitrate. Hazardous...

hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium." Organometallics, 3.2 (1984): 274–278. Tilley Group Website...