Chiral resolution, or enantiomeric resolution, is a process in stereochemistry for the separation of racemic mixture into their enantiomers. It is an...
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In chemistry, a molecule or ion is called chiral (/ˈkaɪrəl/) if it cannot be superposed on its mirror image by any combination of rotations, translations...
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reaction with a chiral catalyst or reagent, resulting in an enantioenriched sample of the less reactive enantiomer. As opposed to chiral resolution, kinetic...
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analytical chemistry, a chiral derivatizing agent (CDA), also known as a chiral resolving reagent, is a derivatization reagent that is a chiral auxiliary used...
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Racemic mixture (section Resolution)
racemate into its components, the individual enantiomers, is called a chiral resolution. Various methods exist for this separation, including crystallization...
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A chiral phenomenon is one that is not identical to its mirror image (see the article on mathematical chirality). The spin of a particle may be used to...
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reciprocal of the unit in the last place Resolution (beam engine), an early steam engine at Coalbrookdale Chiral resolution, a process in stereochemistry for...
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Enantioselective synthesis (redirect from Chiral ligand)
reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric...
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Chemical yield: 1.4%. In addition they isolated (−)-narwardine by chiral resolution from a mixture of racemic narwedine and 0.5 equivalents of (+)-galanthamine...
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C6H5CH(NH2)CH3. This primary amine is a colorless liquid is often used in chiral resolutions. Like benzylamine, it is relatively basic and forms stable ammonium...
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enantioselective analysis. Chiral analysis includes all analytical procedures focused on the characterization of the properties of chiral drugs. Chiral analysis is usually...
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Viedma ripening (category Chirality)
technique to separate enantiomers of chiral molecules in the pharmaceutical and fine chemical industries (chiral resolution). The exact interplay of the mechanisms...
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Stereochemistry. Alkane stereochemistry Chiral resolution, which often involves crystallization Chirality (chemistry) (R/S, d/l) Chiral switch Skeletal formula#Stereochemistry...
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knowledge is harnessed in chiral synthesis to separate a mixture of enantiomers. This is the principle behind chiral resolution. After preparing the diastereomers...
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Planar chirality, also known as 2D chirality, is the special case of chirality for two dimensions. Most fundamentally, planar chirality is a mathematical...
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isolated by fractional distillation. The enantiomers are separated by chiral resolution in reaction with methyl benzoate, selective crystallisation followed...
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capacity was 5,000 tons per year. The enantiomers may be separated by chiral resolution of the racemic mixture. S-Malic acid is obtained by fermentation of...
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salt which is fractionally crystallized to yield dextroamphetamine. Chiral resolution remains the most economical method for obtaining optically pure amphetamine...
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provided by Prelog a year earlier to quinotoxine (enantiopure after chiral resolution) that is described. Woodward and Doering argue that Rabe in 1918 already...
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Enantiomer (redirect from Chiral amplification)
absence of an effective enantiomeric environment (precursor, chiral catalyst, or kinetic resolution), separation of a racemic mixture into its enantiomeric...
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otherwise be chiral due to a nitrogen stereocenter, nitrogen inversion provides a low energy pathway for racemization, usually making chiral resolution impossible...
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In stereochemistry, a chiral auxiliary is a stereogenic group or unit that is temporarily incorporated into an organic compound in order to control the...
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(PtCl2(C2H4)(PhCH(NH2)Me) is a chiral derivative of Zeise's salt that is used for the chiral resolution of alkenes. Aldrich datasheet "C&L Inventory"...
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amounts of energy to be supplied to the system. Abnormal grain growth Chiral resolution by crystallization Crystal habit Crystal structure Crystallite Fractional...
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use either a chiral stationary phase or a chiral additive in the mobile phase. The chiral stationary phase can be prepared by mixing chirally pure reagents...
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the allyl alcohol 27. Chiral resolution of this racemic compound with digitonin produced chiral 28 and on Oppenauer oxidation chiral 29. Hydrogenation (Adams'...
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Homochirality (redirect from Chiral transmission)
Homochirality is a uniformity of chirality, or handedness. Objects are chiral when they cannot be superposed on their mirror images. For example, the left...
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reactivity toward chromic acid. Since brucine is a large chiral molecule, it has been used in chiral resolution. Fisher first reported its use as a resolving agent...
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the final product was a racemate that would not suitably undergo chiral resolution. This prevented isolation of the natural levorotary enantiomer of...
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of the ammonium salt with sodium hydroxide. Alternate reagents for chiral resolution include N-p-toluenesulfonylaspartic acid, N-benzenesulfonylaspartic...
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