In chemistry, decarbonylation is a type of organic reaction that involves the loss of carbon monoxide (CO). It is often an undesirable reaction, since...

The Tsuji–Wilkinson decarbonylation reaction is a method for the decarbonylation of aldehydes and some acyl chlorides. The reaction name recognizes Jirō...

Nickel carbonyl (IUPAC name: tetracarbonylnickel) is a nickel(0) organometallic compound with the formula Ni(CO)4. This colorless liquid is the principal...

from alkenes to oxygenates. Few organic carbonyls undergo spontaneous decarbonylation, but many can be induced to do so with appropriate catalysts. A common...

fuels produced by converting biomass, by either decarboxylation or decarbonylation, into liquid transportation fuels, such as ethanol and biodiesel. Conversion...

A Fischer carbene is a type of transition metal carbene complex, which is an organometallic compound containing a divalent organic ligand. In a Fischer...

chemistry reaction of nucleophilic abstraction, Me3NO is employed as a decarbonylation agent according to the following stoichiometry: M(CO)n + Me3NO + L...

reactions, including condensations with diamines to give quinoxalines and decarbonylation to give a diazafluorenone. The compound is prepared by oxidation of...

of unsaturated products, or isomerization to a vinylidene ketene. Decarbonylation has been observed but is thermodynamically difficult to achieve with...

Iron pentacarbonyl, also known as iron carbonyl, is the compound with formula Fe(CO)5. Under standard conditions Fe(CO)5 is a free-flowing, straw-colored...

Comproportionation C–C coupling C–H activation Cyanation Cyclometalation Decarbonylation Decarboxylation Dehydration Dehalogenation Dehydrogenation Dehydrohalogenation...

structure. In another application as a feedstock, palladium-catalyzed decarbonylation on furfural manufactures industrially furan. Another important solvent...

to be converted to THF via acid-catalyzed digestion to furfural and decarbonylation to furan, although this method is not widely practiced. THF is thus...

Hydroacylation Ketone In hydroacylation an aldehyde is added over an unsaturated bond to form a ketone. Decarbonylation Alkane Catalysed by transition metals...

reactions, including the Tsuji-Trost reaction, the Tsuji-Wilkinson decarbonylation, and the Tsuji-Wacker reaction. Tsuji was born in Japan in 1927. After...

aldehydes by hydrogen-atom abstraction. However, they undergo rapid decarbonylation to afford the alkyl radical: RC(H)=O → RC•=O → R• + C≡O Acyl anions...

chloride, trans-RhCl(CO)(PPh3)2. The same complex arises from the decarbonylation of aldehydes: RhCl(PPh3)3 + RCHO → RhCl(CO)(PPh3)2 + RH + PPh3 Upon...

cleavage. α-Hydroxy acids are particularly prone to acid-catalyzed decarbonylation, yielding carbon monoxide, a ketone or aldehyde, and water as by-products...

through either two identified pathways, an acyl reduction pathway or a decarbonylation pathway. In the acyl reduction pathway, a reductase converts VLCFAs...

additional species. Atomic carbon can be produced by carbon suboxide decarbonylation. In this process, carbon suboxide decomposes to produce atomic carbon...

to the higher trans-influence of the more electronegative nitrogen. Decarbonylation of aldehydes, the reverse of CO insertion, is a well-recognized reaction:...

biofuels Algae fuel Renewable hydrocarbon fuels via decarboxylation/decarbonylation Sustainable oils Vegetable oil fuel Zeman, Petr; Hönig, Vladimír; Kotek...

the reduced product. As with the parent Wolff–Kishner reduction, the decarbonylation reaction can often fail due to unsuccessful formation of the corresponding...

to their parent carbonyl compounds. The Hofmann rearrangement is a decarbonylation reaction whereby an amide is converted to an amine by way of an isocyanate...

C6H5OH). Industrially, furan is manufactured by the palladium-catalyzed decarbonylation of furfural, or by the copper-catalyzed oxidation of 1,3-butadiene:...

hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes". Chem. Commun. (11): 931–932....

oxidative decarboxylation to 3-cyanopropanoic acid, followed by a decarbonylation-elimination to acrylonitrile. Of these, the glycerol route is broadly...

hydroxide, DMF converts to formate and dimethylamine. DMF undergoes decarbonylation near its boiling point to give dimethylamine. Distillation is therefore...

additional hydrocarbons and evidence for alkane biosynthesis by a decarbonylation mechanism". Insect Biochemistry and Molecular Biology. 22 (3): 237–243...

complexes are often highly toxic. Some metal–CO complexes are prepared by decarbonylation of organic solvents, not from CO. For instance, iridium trichloride...