Dimethyldioxirane (DMDO) is the organic compound with the formula (CH3)2CO2. It is the dioxirane derived from acetone and can be viewed as the monomer...
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phenyl sulfoxide, a reaction useful for titration of oxidants such as dimethyldioxirane. Successive oxidation then leads to the sulfone. Nomenclature of Organic...
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DMD may refer to: Dimethyldioxirane, an organic molecule Disruptive mood dysregulation disorder Doctor of Dental Medicine, an academic degree for the...
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for diverse oxidations in organic synthesis. The dominant reagent dimethyldioxirane (DMDO) forms upon treatment of acetone with oxone. Dioxiranes are...
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monomer and cyclic dimer, trimer, and tetramer forms. The monomer is dimethyldioxirane. The dimer is known as diacetone diperoxide (DADP). The trimer is...
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S)-3-Methyloxiranol (S,R)-3-Methyloxiranol (S,S)-3-Methyloxiranol Dimethyldioxirane Oxetan-3-ol Oxetan-2-ol (R)-Oxetan-2-ol (S)-Oxetan-2-ol 3-Methyl-1...
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catalysts. In specialized applications, dioxirane reagents (e.g. dimethyldioxirane) perform similarly, but are more explosive. Typical laboratory operations...
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oxidizing than other dioxiranes due to its stability. Difluorodioxirane Dimethyldioxirane Shi epoxidation Kirschfeld, Andreas; Muthusamy, Sengodagounder; Sander...
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peroxyacetic acid, peroxyformic acid, potassium peroxymonosulfate (oxone), dimethyldioxirane, which is generated in situ from acetone and potassium peroxymonosulfate...
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polyepoxides can be generated by reaction of COT with peroxy acids or with dimethyldioxirane. Various other addition reactions are also known. Furthermore, polyacetylene...
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which is mainly of theoretical interest, more common dioxiranes are dimethyldioxirane (DMD or DMDO) and trifluoromethyl-methyldioxirane (TFD). DMDO and...
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of mixed epoxides when conjugated dienes are used as substrates. Dimethyldioxirane]] can be used as a source of O atomes.DMD of a chiral metal catalyst...
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Fast and clean post-polymerization modification by oxidation using dimethyldioxirane (DMDO)". Reactive and Functional Polymers. 86: 16–26. Bibcode:2015RFPol...
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of dimethyldioxirane. Cremera, Dieter; Kraka, Elfi; G Szalay, Peter (1998). "Decomposition modes of dioxirane, methyldioxirane and dimethyldioxirane—a...
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below. Another example of SKIE is oxidation of benzyl alcohols by dimethyldioxirane, where three transition states for different mechanisms were proposed...
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catalysts for various organic transformations. Dimesityldioxirane Dimethyldioxirane Shi epoxidation "CAS Common Chemistry". CAS Common Chemistry. 2024-04-09...
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the alkenes can be epoxidized using mCPBA, peroxybenzoic acid, or dimethyldioxirane (DMDO). Using a peracid (mCPBA or peroxybenzoic acid), the epoxy product...
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itself (CH2O2) is not useful. Instead, the substituted dioxiranes dimethyldioxirane (DMD) and methyl(trifluoromethyl)dioxirane (TFD) are commonly employed...
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Ruthenium Complexes with Dimethyldioxirane" [Oxyfunctionalization of Allyl Thioether Ruthenium Complexes with Dimethyldioxirane]. Zeitschrift für Naturforschung...
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results in the active, toxic form of gambierol.Reaction conditions: (a) Dimethyldioxirane, CH2Cl2, -78 to 0 °C; DIBAL, CH2Cl2, 90% (10:1 mixture). (b) TPAP...
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coarctate transition state is that of the epoxidation of an olefin by dimethyldioxirane. In this transition state, the oxygen atom transferred to the olefin...
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trimethylsilyl triflate, and a modified Rubottom oxidation using 3,3-dimethyldioxirane followed by a treatment with camphorsulfonic acid introduced a hydroxyl...
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dichlorides to give arylphosphonic amines. Diisobutylamine reacts with dimethyldioxirane to give diisobutylhydroxylamine, as typical for oxidation of secondary...
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can be prepared by oxidation of selenoesters with one equivalent of dimethyldioxirane (DMDO). Use of excess DMDO affords little studied selenonic acids...
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F.; Ricart, S.; Camps, F.; Messeguer, A.; Moretó, J. M. (1992). "Dimethyldioxirane in Organometallic Chemistry. II. An Improved Procedure for the Oxidative...
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