• Thumbnail for Dimethyldioxirane
    Dimethyldioxirane (DMDO) is the organic compound with the formula (CH3)2CO2. It is the dioxirane derived from acetone and can be viewed as the monomer...
    5 KB (482 words) - 16:31, 12 November 2024
  • Thumbnail for Thioanisole
    phenyl sulfoxide, a reaction useful for titration of oxidants such as dimethyldioxirane. Successive oxidation then leads to the sulfone. Nomenclature of Organic...
    3 KB (234 words) - 12:48, 2 September 2024
  • DMD may refer to: Dimethyldioxirane, an organic molecule Disruptive mood dysregulation disorder Doctor of Dental Medicine, an academic degree for the...
    2 KB (253 words) - 04:48, 23 September 2023
  • Thumbnail for Potassium peroxymonosulfate
    for diverse oxidations in organic synthesis. The dominant reagent dimethyldioxirane (DMDO) forms upon treatment of acetone with oxone. Dioxiranes are...
    10 KB (787 words) - 21:47, 4 November 2024
  • Thumbnail for Acetone peroxide
    monomer and cyclic dimer, trimer, and tetramer forms. The monomer is dimethyldioxirane. The dimer is known as diacetone diperoxide (DADP). The trimer is...
    38 KB (3,783 words) - 21:40, 5 December 2024
  • S)-3-Methyloxiranol (S,R)-3-Methyloxiranol (S,S)-3-Methyloxiranol Dimethyldioxirane Oxetan-3-ol Oxetan-2-ol (R)-Oxetan-2-ol (S)-Oxetan-2-ol 3-Methyl-1...
    2 KB (184 words) - 20:38, 20 August 2023
  • Thumbnail for Epoxide
    catalysts. In specialized applications, dioxirane reagents (e.g. dimethyldioxirane) perform similarly, but are more explosive. Typical laboratory operations...
    22 KB (2,324 words) - 21:50, 25 August 2024
  • Thumbnail for Dimesityldioxirane
    oxidizing than other dioxiranes due to its stability. Difluorodioxirane Dimethyldioxirane Shi epoxidation Kirschfeld, Andreas; Muthusamy, Sengodagounder; Sander...
    4 KB (236 words) - 19:15, 2 August 2024
  • peroxyacetic acid, peroxyformic acid, potassium peroxymonosulfate (oxone), dimethyldioxirane, which is generated in situ from acetone and potassium peroxymonosulfate...
    29 KB (3,255 words) - 22:37, 20 December 2024
  • Thumbnail for Cyclooctatetraene
    polyepoxides can be generated by reaction of COT with peroxy acids or with dimethyldioxirane. Various other addition reactions are also known. Furthermore, polyacetylene...
    17 KB (1,518 words) - 05:53, 11 September 2024
  • Thumbnail for Dioxirane
    which is mainly of theoretical interest, more common dioxiranes are dimethyldioxirane (DMD or DMDO) and trifluoromethyl-methyldioxirane (TFD). DMDO and...
    6 KB (567 words) - 14:17, 4 November 2024
  • Thumbnail for Jacobsen epoxidation
    of mixed epoxides when conjugated dienes are used as substrates. Dimethyldioxirane]] can be used as a source of O atomes.DMD of a chiral metal catalyst...
    8 KB (802 words) - 23:18, 1 February 2024
  • Thumbnail for Organic solar cell
    Fast and clean post-polymerization modification by oxidation using dimethyldioxirane (DMDO)". Reactive and Functional Polymers. 86: 16–26. Bibcode:2015RFPol...
    111 KB (13,622 words) - 05:55, 25 November 2024
  • of dimethyldioxirane. Cremera, Dieter; Kraka, Elfi; G Szalay, Peter (1998). "Decomposition modes of dioxirane, methyldioxirane and dimethyldioxirane—a...
    2 KB (150 words) - 13:03, 10 March 2021
  • below. Another example of SKIE is oxidation of benzyl alcohols by dimethyldioxirane, where three transition states for different mechanisms were proposed...
    99 KB (13,885 words) - 23:32, 1 September 2024
  • Thumbnail for Difluorodioxirane
    catalysts for various organic transformations. Dimesityldioxirane Dimethyldioxirane Shi epoxidation "CAS Common Chemistry". CAS Common Chemistry. 2024-04-09...
    7 KB (552 words) - 17:09, 31 May 2024
  • Thumbnail for Dewar benzene
    the alkenes can be epoxidized using mCPBA, peroxybenzoic acid, or dimethyldioxirane (DMDO). Using a peracid (mCPBA or peroxybenzoic acid), the epoxy product...
    21 KB (1,785 words) - 16:41, 21 October 2022
  • itself (CH2O2) is not useful. Instead, the substituted dioxiranes dimethyldioxirane (DMD) and methyl(trifluoromethyl)dioxirane (TFD) are commonly employed...
    13 KB (1,613 words) - 00:28, 5 November 2024
  • Thumbnail for Transition metal sulfoxide complex
    Ruthenium Complexes with Dimethyldioxirane" [Oxyfunctionalization of Allyl Thioether Ruthenium Complexes with Dimethyldioxirane]. Zeitschrift für Naturforschung...
    7 KB (792 words) - 15:37, 31 January 2024
  • results in the active, toxic form of gambierol.Reaction conditions: (a) Dimethyldioxirane, CH2Cl2, -78 to 0 °C; DIBAL, CH2Cl2, 90% (10:1 mixture). (b) TPAP...
    22 KB (2,192 words) - 19:50, 22 December 2024
  • Thumbnail for Coarctate reaction
    coarctate transition state is that of the epoxidation of an olefin by dimethyldioxirane. In this transition state, the oxygen atom transferred to the olefin...
    4 KB (437 words) - 01:41, 14 October 2024
  • Thumbnail for Danishefsky Taxol total synthesis
    trimethylsilyl triflate, and a modified Rubottom oxidation using 3,3-dimethyldioxirane followed by a treatment with camphorsulfonic acid introduced a hydroxyl...
    15 KB (1,399 words) - 13:35, 26 August 2024
  • dichlorides to give arylphosphonic amines. Diisobutylamine reacts with dimethyldioxirane to give diisobutylhydroxylamine, as typical for oxidation of secondary...
    7 KB (560 words) - 20:14, 20 December 2023
  • Thumbnail for Methaneseleninic acid
    can be prepared by oxidation of selenoesters with one equivalent of dimethyldioxirane (DMDO). Use of excess DMDO affords little studied selenonic acids...
    12 KB (1,092 words) - 21:20, 27 January 2024
  • F.; Ricart, S.; Camps, F.; Messeguer, A.; Moretó, J. M. (1992). "Dimethyldioxirane in Organometallic Chemistry. II. An Improved Procedure for the Oxidative...
    4 KB (443 words) - 22:52, 31 August 2023