Nitro compound (redirect from Nitroalkane)
proposed in which in the first slow step a proton is abstracted from nitroalkane 1 to a carbanion 2 followed by protonation to an aci-nitro 3 and finally...
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In enzymology, a nitroalkane oxidase (EC 1.7.3.1) is an enzyme that catalyzes the chemical reaction a nitroalkane + H2O + O2 ⇌ {\displaystyle \rightleftharpoons...
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reaction describing the acid hydrolysis of a salt of a primary or secondary nitroalkane (R−NO2) to an aldehyde (R−CH=O) or a ketone (R2C=O) and nitrous oxide...
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Belgian chemist Louis Henry (1834–1913), it is the combination of a nitroalkane and an aldehyde or ketone in the presence of a base to form β-nitro alcohols...
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Tetrachlorodinitroethane is a chlorinated nitroalkane produced by nitration of tetrachloroethylene with dinitrogen tetroxide or fuming nitric acid. It's...
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the iodoalkane which is again treated with AgNO2 to get the nitroalkane. The nitroalkane is then treated with nitrous acid which is obtained by NaNO2...
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reaction. The Knoevenagel condensation reaction of benzaldehydes with nitroalkanes is a classic general method for the preparation of nitroalkenes, which...
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solvent-dependent. Quinones are produced from catechols and hydroquinones and even nitroalkanes are oxidized. CAN provides an alternative to the Nef reaction; for example...
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Nitroethane (category Nitroalkanes)
350–450 °C. This exothermic reaction produces four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction...
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nitro-Mannich reaction (or aza-Henry reaction) is the nucleophilic addition of a nitroalkane (or the corresponding nitronate anion) to an imine, resulting in the...
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Trinitromethane (category Nitroalkanes)
Trinitromethane, also referred to as nitroform, is a nitroalkane and oxidizer with chemical formula HC(NO2)3. It was first obtained in 1857 as the ammonium...
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Nitromethane (category Nitroalkanes)
This exothermic reaction produces the four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction...
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Vijayarajan; Watson, Donald A. (2017). "Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides". Journal of the American Chemical Society...
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Minor impurities include oxygen-containing substances such as amides and nitroalkanes. Oleylamine reacts with carboxylic acid to form its carboxylate salt...
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the functional group RC(NO2)=NOH. They are prepared by the reaction of nitroalkanes with base and nitrite sources: RCH2NO2 + HNO2 → RC(NO2)=NOH + H2O The...
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two proposed pathways for the reaction of d-amino acid oxidase with nitroalkane anions. Path A involved a nucleophilic attack on the coenzyme flavin...
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1021/ie50459a035. A. S. Kende & J. S. Mendoza (1991). "Controlled reduction of nitroalkanes to alkyl hydroxylamines or amines by samarium diiodide". Tetrahedron...
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of aromatic carboxylic acids from sulfonic acid and formates (1869). Nitroalkanes from alkyl iodides and silver nitrite (1872), used to distinguish 1°...
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aldehyde 20 to nitroalkene 21 occurs through enamine catalysis, yielding nitroalkane 25. Condensation of α,β-unsaturated aldehyde 22 with the organocatalyst...
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in which alkyl halides react with metallic nitrites to a mixture to nitroalkanes and nitrites. Nitrite salts can react with secondary amines to produce...
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2-Nitropropane (category Nitroalkanes)
2-Nitropropane (2-NP) is an organic compound with the formula (CH3)2CH(NO2). It is used as a solvent. It is a colorless liquid and is classified as a nitro...
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can be synthesised by dehydrogenation of oximes or by dehydration of nitroalkanes.: 934–936 They can be used to synthesise isoxazoles.: 1201–1202 Nitriles...
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are highly explosive and very shock-sensitive, and may be dissolved in nitroalkanes to reduce their shock-sensitivity. Trinitroethanol reacts with carbon...
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doi:10.1021/jo00357a040. Kende, A (1991). "Controlled reduction of nitroalkanes to alkyl hydroxylamines or amines by samarium diiodide". Tetrahedron...
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1-Nitropropane (category Nitroalkanes)
by the reaction of propane and nitric acid. This reaction forms four nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. 1-nitropropane...
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Tetranitromethane (category Nitroalkanes)
Tetranitromethane or TNM is an organic oxidizer with chemical formula C(NO2)4. Its chemical structure consists of four nitro groups attached to one carbon...
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Heptanitrocubane (category Nitroalkanes)
Heptanitrocubane /ˌhɛptəˌnaɪtroʊˈkjuːbeɪn/ is an experimental high explosive based on the cubic eight-carbon cubane molecule and closely related to octanitrocubane...
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Astronautics. doi:10.2514/6.1980-1293. Reich, Hans. "Bordwell pKa table: "Nitroalkanes"". University of Wisconsin Chemistry Department. Archived from the original...
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increasing a diesel fuel's cetane number. A few examples are nitrates, nitroalkanes, nitrocarbonates and peroxides. One of the main cetane improver additives...
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pendant chiral backbones have shown to activate systems with tethered nitroalkane and ester motifs to induce asymmetric IMA. The utility of this transformation...
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