In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such...
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production Frustrated Lewis pair Jemmis mno rules Lewis acids and bases Nucleophile Polyhedral skeletal electron pair theory Lewis, Gilbert N. (1916). "The...
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rule for the π-electrons of aromatic compounds, Polyhedral skeletal electron pair theory for polyhedral cluster compounds, including transition metals...
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Polyhedral skeletal electron pair theory — Baeyer strain theory — Quantum theory of atoms in molecules — Collision theory — Ligand field theory (successor...
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can be used in the applications of chemistry as in the polyhedral skeletal electron pair theory and chemical compounds. Omitting the convex property leaves...
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Molecular geometry (redirect from Electron Geometry)
Molecular modelling Molecular symmetry Molecule editor Polyhedral skeletal electron pair theory Quantum chemistry Ribbon diagram Styx rule (for boranes)...
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Jemmis mno rules (section Electron-counting rules)
rules and polyhedral skeletal electron pair theory. The Jemmis mno rule provides the relationship between polyhedral boranes, condensed polyhedral boranes...
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features heavily in cluster compounds described by the polyhedral skeletal electron pair theory, such as boranes and carboranes. These molecules derive...
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complexes. Their structures can often be rationalized by polyhedral skeletal electron pair theory. The inventory of these compounds is large, and their structures...
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powder. As the lightest element of the boron group it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric...
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in the context of polyhedral skeletal electron pair theory. This theory predicts that tetrametallic clusters with 60 valence electrons will adopt tetrahedral...
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Polyhedron (redirect from Polyhedral surface)
model Polyhedral combinatorics Polyhedral group Polyhedral number Polyhedral skeletal electron pair theory Polyhedral space Polyhedral symbol Polyhedral terrain...
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These compounds are Lewis acids in that they readily form adducts with electron-pair donors, which are called Lewis bases. For example, fluoride (F−) and...
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of BH centers. The bonding of the clusters ushered in Polyhedral skeletal electron pair theory and Wade's rules, which can be used to predict the structures...
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2-centre 2-electron bonds (2c-2e), others are "electron deficient" and bonding sometimes can be described using polyhedral skeletal electron pair theory (Wade's...
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polycations. The term is usually used in the context of polyhedral skeletal electron pair theory or systematic nomenclature in inorganic chemistry. From...
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consistent with the classification of this cage as "closo" in polyhedral skeletal electron pair theory. Crystals of Cs2B12H12 feature Cs+ ions in contact with...
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on pi ligands. Mingos' 1984 paper on the polyhedral skeletal electron pair theory develops Wade's electron counting rules for predicting the molecular...
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elaborate rules are invoked including Jemmis mno rules and polyhedral skeletal electron pair theory. Although clusters are often written with discrete M-M...
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of Chemistry. Wade's Rules, also known as Polyhedral skeletal electron pair theory, are a set of electron counting rules to predict the shapes of borane...
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tissue is present. Cells of this type of tissue are roughly spherical or polyhedral to rectangular in shape, with thin cell walls. New cells produced by meristem...
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hydrocarbons are typically chains or rings. Like for other electron-delocalized polyhedral clusters, the electronic structure of these cluster compounds...
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Zintl phase (section Electronic theory)
4 skeletal-electrons corresponding to a nido-form of a trigonal-bipyramid) and 1x Si4− 9 (according to Wade's rules, 22 = 2n + 4 skeletal-electrons corresponding...
36 KB (3,708 words) - 15:47, 9 August 2024