• Thumbnail for Protecting group
    A protecting group or protective group is introduced into a molecule by chemical modification of a functional group to obtain chemoselectivity in a subsequent...
    57 KB (6,755 words) - 23:19, 9 April 2024
  • Thumbnail for Fluorenylmethyloxycarbonyl protecting group
    protecting group (Fmoc) is a base-labile protecting group used in organic synthesis. Fmoc carbamate is frequently used as a protecting group for amines...
    6 KB (682 words) - 13:54, 31 July 2024
  • Thumbnail for Tert-Butyloxycarbonyl protecting group
    tert-butyloxycarbonyl protecting group or tert-butoxycarbonyl protecting group (BOC group) is an acid-labile protecting group used in organic synthesis. The BOC group can...
    10 KB (1,045 words) - 17:06, 19 July 2024
  • A protected group, protected class (US), or prohibited ground (Canada) is a category by which people are qualified for special protection by a law, policy...
    6 KB (648 words) - 20:48, 21 August 2024
  • A photolabile protecting group (PPG; also known as: photoremovable, photosensitive, or photocleavable protecting group) is a chemical modification to a...
    40 KB (4,529 words) - 08:06, 18 June 2024
  • Thumbnail for Benzyl group
    deprotection of benzyl group are applicable for cleavage of the PMB protecting group The benzyl group is occasionally used as a protecting group for amines in...
    15 KB (1,604 words) - 15:45, 3 December 2023
  • group of one alpha-amino acid with the alpha-amino group of a second amino acid. Reversible protecting groups are used to block the alpha-amino group...
    54 KB (6,166 words) - 10:11, 1 October 2024
  • (tBu) ether is an acid-labile protecting group for alcohols. A traditional way to introduce the tBu group to a hydroxyl group is by treating the compound...
    8 KB (874 words) - 22:07, 1 March 2024
  • Thumbnail for Triphenylmethane
    called trityl, is widely used in organic chemistry. Trityl serves as a protecting group for alcohols. protection (requires proton acceptor): Ph3CCl + ROH →...
    8 KB (614 words) - 19:41, 17 September 2024
  • Thumbnail for Tosyl group
    nucleophile. A tosyl group can function as a protecting group in organic synthesis. Alcohols can be converted to tosylate groups so that they do not react...
    7 KB (781 words) - 19:17, 13 April 2024
  • deprotection of the protected sensitive part of a molecule. The deprotection mechanism has been proven only for several Thermolabile Protecting Groups (TPGs). Most...
    3 KB (368 words) - 00:29, 24 November 2022
  • Thumbnail for Danishefsky Taxol total synthesis
    points for fusion with the A ring. Alcohol 12 was protected by a benzyl group. The acetonide protecting group was removed from the ketone. Ketone 14 was converted...
    15 KB (1,399 words) - 13:35, 26 August 2024
  • Thumbnail for Fluorenylmethyloxycarbonyl chloride
    chloroformate ester. It is used to introduce the fluorenylmethyloxycarbonyl protecting group as the Fmoc carbamate. This compound may be prepared by reacting 9-fluorenylmethanol...
    2 KB (61 words) - 15:44, 18 September 2024
  • Thumbnail for Benzyl chloroformate
    Benzyl chloroformate (redirect from Z group)
    early 1930s who used it for the introduction of the benzyloxycarbonyl protecting group, which became the basis of the Bergmann-Zervas carboxybenzyl method...
    10 KB (920 words) - 21:29, 12 November 2023
  • BOC Group may refer to: Bank of China Group (BOCG), simplified Chinese: 中银集团; traditional Chinese: 中銀集團 Boc group, a protecting group used in organic...
    284 bytes (68 words) - 01:19, 11 November 2023
  • Thumbnail for Di-tert-butyl dicarbonate
    allowing for the use of the fluorenylmethyloxycarbonyl group (Fmoc) as an orthogonal protecting group. Di-tert-butyl dicarbonate is inexpensive, so it is...
    13 KB (1,222 words) - 20:59, 16 December 2023
  • Thumbnail for Acetonide
    Kocieński, Philip j. (1994). "3.2.2: Diol Protecting Groups—Acetals—Isopropylidene Acetals". Protecting Groups. Foundations of Organic Chemistry Series...
    3 KB (331 words) - 13:50, 24 March 2024
  • non-participating group, a group usually without a carboxyl group, will often result in an α-glycoside. Below it can be seen that having an acetyl protecting group at...
    16 KB (1,841 words) - 13:01, 31 July 2024
  • Thumbnail for Skeletal formula
    the tosylate group A protecting group or protective group is introduced into a molecule by chemical modification of a functional group to obtain chemoselectivity...
    28 KB (3,597 words) - 01:30, 6 July 2024
  • Thumbnail for Trimethylsilyl group
    attached to certain functional groups in a reactant molecule, trimethylsilyl groups may also be used as temporary protecting groups during chemical synthesis...
    9 KB (1,016 words) - 00:04, 19 July 2024
  • with 2-cyanoethyl groups; The exocyclic amino groups in all nucleic bases except for T and U are protected with acyl protecting groups. To furnish a functional...
    79 KB (9,460 words) - 05:24, 25 September 2024
  • Diol (category Functional groups)
    many subcategories have been identified. They are used as protecting groups of carbonyl groups, making them essential in synthesis of organic chemistry...
    12 KB (1,284 words) - 19:59, 27 July 2024
  • Thumbnail for Triphenylmethyl chloride
    C19H15Cl. It is an alkyl halide, sometimes used to introduce the trityl protecting group. Triphenylmethyl chloride is commercially available. It may be prepared...
    4 KB (226 words) - 09:28, 31 October 2022
  • Thumbnail for Tert-Butyldiphenylsilyl
    Tert-Butyldiphenylsilyl (category Protecting groups)
    TBDPS, is a protecting group for alcohols. Its formula is C16H19Si-. The tert-butyldiphenylsilyl group was first suggested as a protecting group by Hanessian...
    5 KB (582 words) - 23:47, 28 November 2023
  • synthesised step-by-step in a single reaction vessel utilising selective protecting group chemistry. Benefits compared with normal synthesis in a liquid state...
    12 KB (1,632 words) - 11:02, 14 August 2024
  • sprinklers; see Glossary of firefighting equipment#P Pivaloyl protecting group (Piv), a protecting group in chemistry P = IV, the formula describing power in terms...
    1 KB (181 words) - 05:37, 25 September 2024
  • Thumbnail for Sacubitril
    succinimide protecting group, hydrolysis of the alkyl chloride using sodium hydroxide and protection of the free amine with a tert-butoxycarbonyl (Boc) group. The...
    7 KB (526 words) - 15:48, 25 March 2024
  • psychology Enantiomeric excess, in chemistry Ethoxyethyl ethers, a protecting group in chemistry Easy Editor, a text editor for the BSD computer operating...
    3 KB (464 words) - 10:17, 4 August 2024
  • a methylene separating the double bond and oxygen. DHP is used for protecting group for alcohols. It is a colorless liquid. Dihydropyran is prepared by...
    3 KB (230 words) - 11:13, 13 January 2024
  • Silyl ether (category Protecting groups)
    is R1R2R3Si−O−R4 where R4 is an alkyl group or an aryl group. Silyl ethers are usually used as protecting groups for alcohols in organic synthesis. Since...
    10 KB (1,269 words) - 22:55, 13 August 2024