Rhodium(II) acetate is the coordination compound with the formula Rh2(AcO)4, where AcO− is the acetate ion (CH 3CO− 2). This dark green powder is slightly...
5 KB (378 words) - 18:56, 5 July 2024
weak bases, moreso than does rhodium(II) acetate. It even forms adducts with hexamethylbenzene and with S8. Rhodium(II) trifluoroacetate catalyzes cyclopropanation...
4 KB (372 words) - 14:54, 29 October 2024
a methanolic solution of hydrated rhodium trichloride with sodium acetate give the blue-green rhodium(II) acetate, Rh2(O2CCH3)4, which features a Rh-Rh...
32 KB (3,845 words) - 11:30, 30 October 2024
the Diels–Alder reaction and cyclopropanation reactions (much like rhodium(II) acetate). NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute...
3 KB (191 words) - 18:29, 25 September 2023
complex. Examples include chromium(II) acetate, molybdenum(II) acetate, and rhodium(II) acetate, copper(II) acetate dihydrate. The name is derived from...
2 KB (169 words) - 16:31, 12 November 2023
acetate is often brushed upon untreated wood to give it an aged appearance.[citation needed] Iron(II) acetate Cobalt(II) acetate Rhodium(II) acetate Manganese(III)...
6 KB (605 words) - 02:11, 22 October 2024
Organorhodium chemistry (section Rhodium(II))
Although not organometallic, rhodium(II) acetate (Rh2(OAc)4) catalyzes cyclopropanations via organometallic intermediates. Rhodium(II) porphyrin complexes react...
10 KB (1,125 words) - 13:44, 11 October 2023
Palladium(II) acetate is a chemical compound of palladium described by the formula [Pd(O2CCH3)2]n, abbreviated [Pd(OAc)2]n. It is more reactive than the...
13 KB (1,182 words) - 00:14, 9 September 2024
both terminal and doubly bridging chloride ligands. In rhodium(II) acetate, the four acetate groups are bridging ligands. In VO(HPO4)·0.5H2O, pairs of...
8 KB (844 words) - 15:08, 6 July 2023
by the Dauben group (Scheme 13). Treatment of diazoimide 64 with rhodium(II) acetate dimer generated a carbenoid that yielded reactive ylide 65 after...
26 KB (2,826 words) - 18:23, 28 May 2024
Transition metal carboxylate complex (redirect from Transition metal acetate)
tetraacetates (M2(OAc)4) including rhodium(II) acetate, copper(II) acetate, molybdenum(II) acetate, and chromium(II) acetate. Platinum diacetate and palladium...
14 KB (1,465 words) - 01:07, 3 October 2024
Hexadecacarbonylhexarhodium (category Rhodium(0) compounds)
rhodium are also effective precursors such as [(CO)2Rh(μ-Cl)]2 and rhodium(II) acetate: 3 Rh2(O2CCH3)4 + 22 CO + 6 H2O → Rh6(CO)16 + 6 CO2 + 12 CH3COOH...
5 KB (399 words) - 18:56, 3 July 2024
(January 1989). "Novel entry to the tropane system by reaction of rhodium (II) acetate stabilized vinylcarbenoids with pyrroles". Tetrahedron Letters. 30...
10 KB (899 words) - 07:32, 27 December 2023
Acetic acid (redirect from Hydrogen acetate)
carbonate) and verdigris, a green mixture of copper salts including copper(II) acetate. Ancient Romans boiled soured wine to produce a highly sweet syrup called...
62 KB (6,574 words) - 15:05, 22 October 2024
Acetic anhydride (redirect from Acetyl acetate)
methyl acetate to methyl iodide and an acetate salt. Carbonylation of the methyl iodide in turn produces acetyl iodide, which reacts with acetate salts...
17 KB (1,392 words) - 20:09, 15 September 2024
Aluminium triacetate (category Acetates)
known. Copper(II) acetate and chromium(II) acetate both have dinuclear dihydrate structures, M2(OAc)4(H2O)2, as does rhodium(II) acetate; each shows significant...
33 KB (3,163 words) - 09:39, 11 April 2024
Platinum(II) acetate is a purple-colored coordination complex. The complex adopts an unusual structure consisting of a square array of Pt atoms. Several...
4 KB (300 words) - 04:05, 19 October 2024
are black, green and blue nickel plating, black chromium plating, black rhodium plating and black ruthenium plating. Anodic oxidation of aluminum, titanium...
16 KB (1,913 words) - 11:42, 9 October 2024
Palladium (section Palladium(II))
goddess Athena, acquired by her when she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as...
59 KB (6,283 words) - 17:25, 19 August 2024
hydrogen in the presence of a catalyst such as cobalt octacarbonyl or a rhodium complex. H2C=CH2 + CO + H2 → CH3CH2CH=O CH3CH2CH=O + H2 → CH3CH2CH2OH A...
9 KB (647 words) - 12:59, 11 October 2024
salt can be either inorganic, such as chloride (Cl−), or organic, such as acetate (CH 3COO− ). Each ion can be either monatomic (termed simple ion), such...
63 KB (6,942 words) - 00:48, 22 October 2024
whereas osmium, iridium, ruthenium and rhodium stay unreacted. The gold is precipitated by the addition of iron(II) chloride and after filtering off the...
66 KB (7,080 words) - 22:48, 12 September 2024
hexafluoride – ReF6 Rhodium hexafluoride – RhF6 Rhodium pentafluoride – Rh4F20 Rhodium(III) chloride – RhCl3 Rhodium(III) hydroxide – Rh(OH)3 Rhodium(III) iodide...
119 KB (8,735 words) - 17:31, 25 October 2024
boronic acid reacts with a N–H or O–H containing compound with Cu(II) such as copper(II) acetate and oxygen and a base such as pyridine forming a new carbon–nitrogen...
26 KB (2,605 words) - 12:51, 11 October 2024
CH3CH=CH2 + CO + H2 → CH3CH2CH2CHO The reaction is catalyzed by cobalt or rhodium complexes. The resulting aldehydes are hydrogenated to the alcohols, which...
8 KB (609 words) - 01:08, 19 October 2024
Otto Dimroth, who in 1902, reported that benzene reacted with mercury(II) acetate (See: organomercury). Many electrophilic metal centers undergo this Friedel-Crafts-like...
36 KB (3,914 words) - 09:58, 15 September 2024
Ytterbium(II) chloride (YbCl2) Ytterbium(III) chloride (YbCl3) Ytterbium(III) nitrate (Yb(NO3)3) Ytterbium(III) acetate (Yb(CH3COO)3) Ytterbium(III) acetate tetrahydrate...
16 KB (1,523 words) - 15:35, 17 April 2024
Chromium (redirect from Chromium (II))
and chromium(II) sulfate CrSO 4. Many chromium(II) carboxylates are known. The red chromium(II) acetate (Cr2(O2CCH3)4) is somewhat famous. It features...
110 KB (11,965 words) - 20:43, 19 October 2024
myrcene, which undergoes asymmetric isomerisation in the presence of a BINAP rhodium complex to give (after hydrolysis) enantiomerically pure R-citronellal...
31 KB (2,946 words) - 03:23, 29 October 2024
silver bromate 7783–89–3 AgCN silver cyanide 506–64–9 AgC2H3O2 silver acetate 563–63–3 AgCl silver chloride 7783–90–6 AgClO3 silver chlorate 7783–92–8...
139 KB (120 words) - 17:07, 15 July 2024