In organic chemistry, the Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol (−OH) is oxidized to...

Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters...

pyridinium chlorochromate) or dimethyl sulfoxide (e.g. Swern oxidation) or Dess–Martin oxidation due to its use of relatively mild and non-toxic reagents...

chemist Choung Un Kim. Although the Corey–Kim oxidation possesses the distinctive advantage over Swern oxidation of allowing an operation above –25 °C, it...

displaced by the Swern oxidation, which also uses DMSO as an oxidant in the presence of an electrophilic activator. Swern oxidations tend to give higher...

Swern is a surname. Notable people with the surname include: Daniel Swern (1916–1982), American chemist Swern oxidation, an organic chemical reaction...

Parikh–Doering oxidation Albright-Goldman oxidation Swern oxidation Corey–Kim oxidation Ley oxidation (TPAP oxidation) TEMPO oxidation Dess, D. B.; Martin, J. C. (1983)...

Although triethylamine is traditionally employed as the hindered base in Swern oxidations, the structurally similar DIPEA can be used instead, as exemplified...

to the corresponding ketone). Selective oxidation of alcohols to aldehydes requires circumventing over-oxidation to the carboxylic acid. One popular approach...

pre-oxidized substrates: various sulfoxides (e.g. the Swern oxidation), or amine oxides (e.g., the Ganem oxidation). Sterically-hindered nitroxyls (i.e., TEMPO)...

synthetic route is shown below: Swern oxidation Pfitzner–Moffatt oxidation Corey–Kim oxidation Tidwell, Thomas T. (1990). "Oxidation of Alcohols to Carbonyl Compounds...

of P4O10 in DMSO, is employed for the oxidation of alcohols. This reaction is reminiscent of the Swern oxidation. The desiccating power of P4O10 is strong...

Daniel Swern (January 21, 1916 – December 5, 1982) was an American chemist who discovered the Swern oxidation. "After deadline". Journal of the American...

sulfonium-based oxidation reactions including the Pfitzner–Moffatt oxidation, Corey–Kim oxidation and the Swern oxidation. The Kornblum oxidation is conceptually...

the corresponding aldehydes and ketones via the process known as the Swern oxidation. Oxalyl chloride is mainly used together with a N,N-dimethylformamide...

ozonolysis of alkenes. It reduces the intermediate trioxolane. The Swern oxidation produces dimethyl sulfide by reduction of dimethylsulfoxide. With chlorinating...

the oxidation of primary alcohols to aldehydes is the Swern oxidation. J. Donald Albright, Leon Goldman (1965), "Indole Alkaloids. III.1 Oxidation of Secondary...

of reaction higher yielding methods using PCC or the Swern oxidation are recommended. Oxidation with chromic acid yields propionic acid. 1-Propanol is...

chloride can also be used as an alternative to oxalyl chloride in the Swern oxidation. Thiazyl chloride trimer – structural analogue with sulfur atoms in-place...

they are very prone to hazardous thermal runaway. For example, in Swern oxidation, the formation of sulfonium chloride must be performed in a cooled...

monosaccharides, the acetylation was not completed. Like Pfitzner–Moffatt oxidation and Swern oxidation, with DMSO, Ms2O can oxidize primary and secondary alcohols...

preparation for a Swern-oxidation of the alcohol at C5, the benzyl ether is cleaved (8). An aldehyde is the product of the Swern-oxidation (9). Reaction with...

stereocontrol because in the next step the alcohol is oxidized in a Swern oxidation to ketone 11. A Staudinger reaction with triphenylphosphine closes...

Pummerer rearrangement. It can be used in place of oxalyl chloride in the Swern oxidation, allowing temperatures up to −30 °C. With sodium iodide, it reduces...

allylic oxidation (Pd(OAc)2 / AcOH / benzoquinone / MnO2) to tetracycle 7. Hydroboration-oxidation (9-BBN / H2O2) gave alcohol 8 and subsequent Swern oxidation...

bicyclo[2.2.1]hept-5-ene-2,3-diol is formed after hydrolysis. The Swern oxidation to the 1,2-ketone bicyclo[2.2.1]hept-5-ene-2,3-dione proceeds (in the...

partial oxidation is effected with TEMPO and hypochlorite, then chlorite is added to complete the oxidation. Only primary alcohol oxidation is observed...

carbonyl groups Suzuki coupling Swain equation Swarts reaction Swern oxidation Tamao oxidation Tafel rearrangement Takai olefination Tebbe olefination ter...

final product, a Mannich base. Swern oxidation Pfitzner–Moffatt oxidation Corey–Kim oxidation Parikh–Doering oxidation Matsuo, J.; Mukaiyama, T. (2001)...

epoxidation Oppenauer oxidation Prilezhaev reaction Rubottom oxidation Schmidt reaction Swern oxidation Wacker-Tsuji oxidation Reduction Birch reduction...