• In a polymer solution, a theta solvent (or θ solvent) is a solvent in which polymer coils act like ideal chains, assuming exactly their random walk coil...
    6 KB (822 words) - 09:18, 28 June 2023
  • Thumbnail for Mark–Houwink equation
    the particular polymer-solvent system. For solvents, a value of a = 0.5 {\displaystyle a=0.5} is indicative of a theta solvent. A value of a = 0.8 {\displaystyle...
    3 KB (462 words) - 11:45, 8 February 2024
  • Thumbnail for Polymer
    the theta solvent, or the state of the polymer solution where the value of the second virial coefficient becomes 0, the intermolecular polymer-solvent repulsion...
    72 KB (7,737 words) - 22:51, 12 June 2024
  • Thumbnail for Coil–globule transition
    transition of a polymer chain from good solvent behavior through ideal or theta solvent behavior to poor solvent behavior. The canonical coil–globule transition...
    5 KB (557 words) - 08:54, 30 December 2023
  • Thumbnail for Polymer physics
    like a fractal object. In bad solvent it behaves like a solid sphere. In the so-called θ {\displaystyle \theta } solvent, ν = 1 / 2 {\displaystyle \nu...
    21 KB (3,218 words) - 18:14, 27 January 2024
  • computational chemistry, a solvent model is a computational method that accounts for the behavior of solvated condensed phases. Solvent models enable simulations...
    32 KB (4,370 words) - 18:27, 17 February 2024
  • 2 ) / λ {\displaystyle \ q=4\pi n_{0}\sin(\theta /2)/\lambda } with n0 the refractive index of the solvent, λ the wavelength of the light source, NA the...
    18 KB (2,529 words) - 21:40, 15 December 2023
  • Thumbnail for Langmuir adsorption model
    {\displaystyle S_{\text{conf}}/k_{\rm {B}}\approx -\theta _{A}\ln(\theta _{A})-(1-\theta _{A})\ln(1-\theta _{A}).} On the other hand, the entropy of a molecule...
    29 KB (4,972 words) - 22:28, 30 June 2024
  • Thumbnail for Spherical cap
    formulas a = r sin ⁡ θ {\displaystyle a=r\sin \theta } , h = r ( 1 − cos ⁡ θ ) {\displaystyle h=r(1-\cos \theta )} , 2 h r = a 2 + h 2 {\displaystyle 2hr=a^{2}+h^{2}}...
    17 KB (2,995 words) - 13:24, 22 May 2024
  • Thumbnail for Angle of repose
    mg\cos \theta } : m g sin ⁡ θ = N μ {\displaystyle mg\sin \theta =N\mu } m g sin ⁡ θ = μ m g cos ⁡ θ {\displaystyle mg\sin \theta =\mu mg\cos \theta } ( sin...
    13 KB (1,715 words) - 10:13, 8 June 2024
  • ellipticity, [ θ ] {\displaystyle [\theta ]} , are readily interconverted by the equation: [ θ ] = 3298.2 Δ ε . {\displaystyle [\theta ]=3298.2\,\Delta \varepsilon...
    29 KB (4,004 words) - 05:32, 12 December 2023
  • the solvent (in which case, the interactions between monomer and monomer, solvent molecule and solvent molecule, and between monomer and solvent are identical...
    22 KB (3,878 words) - 18:56, 11 March 2024
  • Thumbnail for Lower critical solution temperature
    temperatures approaching the liquid-vapor critical point of the solvent. At such temperatures the solvent expands much more rapidly than the polymer, whose segments...
    14 KB (1,790 words) - 18:23, 27 April 2024
  • Thumbnail for Temperature-responsive polymer
    Seiichi (March 8, 2007). "Unperturbed chain dimensions of polyethylene in theta solvents". Journal of Polymer Science Part C: Polymer Symposia. 15 (1): 285–294...
    58 KB (6,032 words) - 03:12, 22 June 2024
  • Thumbnail for Wetting
    _{\alpha \theta }+\gamma _{\theta \beta }\cos \left(\theta \right)+\gamma _{\alpha \beta }\cos \left(\alpha \right)&=0\\\gamma _{\alpha \theta }\cos \left(\theta...
    56 KB (7,539 words) - 22:27, 25 June 2024
  • Thumbnail for Paul Flory
    discovered the understanding of the term 'theta.' In other words, is the constant of hydrodynamic. With the theta point that is the neutral volumes interactions...
    21 KB (2,485 words) - 21:19, 29 April 2024
  • has been used to describe persistence in polymer chains in good and theta solvents, branched polymers, polymers of complex topology such as star polymers...
    21 KB (2,501 words) - 08:38, 12 April 2024
  • changes in the vibrational frequencies of molecules due to variations in the solvent environment. Solvatochromism is a broader term that describes changes in...
    16 KB (2,089 words) - 07:55, 19 June 2024
  • Thumbnail for Adsorption
    {\displaystyle K={\frac {k}{k_{-1}}}={\frac {\theta }{(1-\theta )P}},} or θ = K P 1 + K P , {\displaystyle \theta ={\frac {KP}{1+KP}},} where P {\displaystyle...
    55 KB (7,150 words) - 16:33, 9 June 2024
  • Thumbnail for Surface tension
    different concentration at the surface of a solvent than in its bulk. This difference varies from one solute–solvent combination to another. Gibbs isotherm...
    71 KB (8,782 words) - 10:52, 27 June 2024
  • Thumbnail for Ultrahydrophobicity
    (}{\Big (}{\frac {1-\cos(\theta _{a})}{\sin(\theta _{a})}}{\Big )}{\Big (}3+{\Big (}{\frac {1-\cos(\theta _{a})}{\sin(\theta _{a})}}{\Big )}^{2}{\Big )}{\Big...
    51 KB (5,835 words) - 20:40, 29 May 2024
  • Thumbnail for X-ray diffraction
    {q^{4}}{m^{2}c^{4}}}\right){\frac {1+\cos ^{2}2\theta }{2}}=I_{e}7.94\times 10^{-26}{\frac {1+\cos ^{2}2\theta }{2}}=I_{e}f} Hence the atomic nuclei, which...
    32 KB (4,200 words) - 23:52, 2 June 2024
  • {\displaystyle \delta _{2}} are the cohesive energy densities of the polymer and solvent, respectively, V ¯ {\displaystyle {\bar {V}}} is the molar volume of the...
    17 KB (2,192 words) - 04:21, 1 January 2024
  • 2 {\displaystyle \cos \theta \ \mathrm {obs} =\ f\cos \theta _{1}+(1-f)\cos \theta _{2}} where: θ   o b s {\displaystyle \theta \ \mathrm {obs} } is the...
    23 KB (3,145 words) - 12:36, 8 April 2024
  • Thumbnail for Hydrophobe
    to be nonpolar and, thus, prefer other neutral molecules and nonpolar solvents. Because water molecules are polar, hydrophobes do not dissolve well among...
    29 KB (3,125 words) - 05:18, 24 June 2024
  • Thumbnail for Liquid crystal
    as a function of both temperature and concentration of molecules in a solvent (typically water). Metallotropic LCs are composed of both organic and inorganic...
    93 KB (11,478 words) - 11:30, 7 June 2024
  • Thumbnail for Electric dipole moment
    _{<}=Ar\cos \theta \,,} while outside the sphere: ϕ > = ( B r + C r 2 ) cos ⁡ θ . {\displaystyle \phi _{>}=\left(Br+{\frac {C}{r^{2}}}\right)\cos \theta \,.}...
    55 KB (7,958 words) - 17:56, 30 June 2024
  • Thumbnail for Dynamic light scattering
    n_{0}}{\lambda }}\sin \left({\frac {\theta }{2}}\right)} where λ is the incident laser wavelength, n0 is the solvent refractive index and θ is the angle...
    33 KB (4,231 words) - 23:59, 10 May 2024
  • _{\text{bonds}}k_{r}(R_{II'}-r_{0})^{2}\\&+\sum _{\text{angles}}k_{\theta }(\theta -\theta _{0})^{2}+\sum _{\text{torsions}}\sum _{n}k_{\phi ,n}[\cos(n\phi...
    16 KB (2,321 words) - 23:47, 30 June 2024
  • Thumbnail for Self-assembled monolayer
    of 100 kJ/mol, making them fairly stable in a variety of temperatures, solvents, and potentials. The monolayer packs tightly due to van der Waals interactions...
    44 KB (5,647 words) - 04:38, 19 February 2024