Titanocene dichloride is the organotitanium compound with the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common reagent...

and reduction of aldehydes. Cp2Ti(CO)2 is prepared by the reduction of titanocene dichloride with magnesium as a slurry in THT under an atmosphere of carbon...

Titanocene Y also known as bis[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dichloride or dichloridobis(η5-(p-methoxybenzyl)cyclopentadienyl)titanium...

obtained. Synthesizing Rosenthal's reagent of a titanocene source yields golden-yellow crystals of the titanocene bis(trimethylsilyl)acetylene complex with...

Titanocene pentasulfide is the organotitanium compound with the formula (C5H5)2TiS5, commonly abbreviated as Cp2TiS5. This metallocene exists as a bright...

metathesis reaction of methylmagnesium chloride or methyllithium with titanocene dichloride: Cp2TiCl2 + 2 CH3MgCl → Cp2Ti(CH3)2 + 2 MgCl2 This compound...

chemistry, is an aluminium-containing derivative of titanocene that arises from the reaction of titanocene dichloride with trimethylaluminium. It is used for...

have been intensively studied. The most common organotitanium complex is titanocene dichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and...

alkylated via salt metathesis reactions. Illustrative is the methylation of titanocene dichloride to give the Petasis reagent: (C5H5)2TiCl2 + 2 ClMgCH3 → (C5H5)2Ti(CH3)2...

metallocene catalysts have the composition Cp2MCl2 (M = Ti, Zr, Hf) such as titanocene dichloride. Typically, the organic ligands are derivatives of cyclopentadienyl...

to 1861, the first example was not reported until 1954. In that year titanocene dichloride was described by Wilkinson and Birmingham. Independently, titanium-based...

developed a light-driven "closed cycle of water splitting using ansa-titanocene(III/IV) triflate complexes". An Indium gallium nitride (InxGa1-xN) photocatalyst...

dichloride: H2Sx + SyCl2 → cyclo-Sx+y + 2 HCl A second strategy uses titanocene pentasulfide as a source of the S2−5 unit. This complex is easily made...

for the methylenation of esters and ketones, is prepared from TMA and titanocene dichloride. In combination with 20 to 100 mol % Cp2ZrCl2 (zirconocene...

contiguous (connected to each other), the η-notation is used, as e.g. in titanocene dichloride: dichlorobis(η5-2,4-cyclopentadien-1-yl)titanium. Molecules...

(or the LiBH4) on the corresponding metal halide. One example is the titanocene derivative: 2 (C5H5)2TiCl2 + 4 NaBH4 → 2 (C5H5)2TiBH4 + 4 NaCl + B2H6...

rings engage in degenerate ring flipping. One well-studied example is titanocene pentasulfide, where the inversion barrier is high relative to cyclohexane's...

5187-81-5 C10H10Cl2Nb niobocene dichloride 12793-14-5 C10H10Cl2Ti titanocene dichloride 1271-19-8 C10H10Co cobaltocene 1277-43-6 C10H10F6FeP ferrocenium...

Closely related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride or vanadocene dichloride. Certain metallocenes and their derivatives...

thermal reaction: Pt(η2-C2H4)(PPh3)2 + C60 → Pt(η2-C60)(PPh3)2 + C2H4 Titanocene complexes have also been reported: (η5-Cp)2Ti(η2-(CH3)3SiC≡CSi(CH3)3)...

titanium(II) chloride, cerium(III) halides such as cerium(III) iodide, and titanocene(III) chloride. The crystal structures of the THF complexes of the Reformatsky...

to the lack of d to d transitions. Examples: titanium tetrachloride, titanocene dichloride, Schwartz's reagent. d1 Examples: molybdenum(V) chloride, vanadyl...

include [Au(SH)2]− and (C5H5)2Ti(SH)2, derived from gold(I) chloride and titanocene dichloride, respectively. Bisulfide salts are corrosive, strongly alkaline...

follows with preservation of conformation via elemental zinc or with titanocene dichloride. Protection through a Diels-Alder reaction: the transformation...

have been intensively studied. The most common organotitanium complex is titanocene dichloride ((C5H5)2TiCl2). Related compounds include Tebbe's reagent and...

variants were initially examined with zirconocene bis(amido) complexes. Titanocene amido and sulfonamido complexes catalyze the intra-molecular hydroamination...

some organic solvents. The lighter homologues zirconacene dichloride and titanocene dichloride have received much more attention. While hafnocene is only...

oxidation or hydrolysis Another reagent is generated in situ by treatment of titanocene dichloride with zinc. That blue green Ti(III)-containing solution is highly...

(Ti) and a main group metal (Al). The Tebbe reagent is synthesized from titanocene dichloride and trimethylaluminium in toluene solution. Cp2TiCl2 + 2 Al(CH3)3...

doi:10.1021/op9900176. Selvakumar, Kumaravel; Harrod, John F. (2001). "Titanocene-Catalyzed Coupling of Amides in the Presence of Organosilanes To Form...