A transition metal fullerene complex is a coordination complex wherein fullerene serves as a ligand. Fullerenes are typically spheroidal carbon compounds...

elongated by 0.2 Å. In the fullerene complex Ru3(CO)9(C60), the fullerene binds to the triangular face of the cluster. In some complexes, the arene binds through...

A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially...

Buckminsterfullerene is a type of fullerene with the formula C60. It has a cage-like fused-ring structure (truncated icosahedron) made of twenty hexagons...

inside a shell. Two types of endohedral complexes exist: endohedral metallofullerenes and non-metal doped fullerenes. In a traditional chemical formula notation...

Transition-metal dichalcogenide (TMD or TMDC) monolayers are atomically thin semiconductors of the type MX2, with M a transition-metal atom (Mo, W, etc...

square planar for some nickel complexes to octahedral for coordination complexes of cobalt. A range of transition metals can be found in biologically important...

xenon gas. XeF 2 also forms coordination complexes with transition metal ions. More than 30 such complexes have been synthesized and characterized. Whereas...

(R5C5)M(R′2)C2B4H4) where M is a transition metal and R and R′ are methyl or ethyl. Closely related are the metal complexes containing H3C3B2R2 (diborolyl)...

of the late transition metals, where metal-halide bonding is replete. Transition metal halide clusters are prevalent for the heavier metals: Zr, Hf, Nb...

it is for simple metals) n = 3 implies that the resistance is due to s-d electron scattering (as is the case for transition metals) n = 2 implies that...

MOFs increased their functionality by reacting organic units and metal-organic complexes with linkers. (4) Multifunctional MOFs incorporated multiple functionalities...

compounds is +4, while +2 is found in carbon monoxide and transition metal carbonyl complexes. The largest sources of inorganic carbon are limestones,...

encountered in octahedral complexes of the transition metals. The phenomenon is very common in six-coordinate copper(II) complexes. The d9 electronic configuration...

copper(II) complexes oxidized H2. The 1960s witnessed the development of well defined homogeneous catalysts using transition metal complexes, e.g., Wilkinson's...

carbide coatings on a metal piece. The carbides of the group 4, 5 and 6 transition metals (with the exception of chromium) are often described as interstitial...

complexes between transition metals and carbonyl ligands. Metal carbonyls are complexes that are formed with the neutral ligand CO. These complexes are...

(such as C25, a 25-carbon fullerene spheroid). The term is sometimes also used in reference to reactivity – for example, a complex that quickly reaches equilibrium...

5, hydrated 18-crown-6 ether alkali metal ions, hydrated alkali metal ions, transition metal acetylene complexes, protonated ethylene, and IrO4+. Argon...

interactions between these molecules or sheets. Metal dichalcogenides have the formula ME2, where M = a transition metal and E = S, Se, Te. In terms of their electronic...

example, diamond, graphite, and fullerenes are different allotropes of carbon. When a substance undergoes a phase transition (changes from one state of matter...

Different forms (allotropes) of pure carbon, such as diamond, graphite, fullerenes and carbon nanotubes are also excluded because they are simple substances...

one each for the eight C−H bonds. Transition metal complexes that feature multiple bonds, such as the dihydrogen complex, have sigma bonds between the multiple...

charge-transfer complex, λ-BETS2X compounds, graphite intercalation compounds and three-dimensional materials such as the alkali-doped fullerenes. Organic superconductors...

dendrimer molecules can be functionalized with porphyrins, fullerenes and metal complexes. Some reported dendrimer systems can achieve up to 99% energy...

chemistry with transition metals. Coupling of sodium pentacyanocyclopentadiene (NaC5(CN)5) with transition metal halide salts generates metal complexes containing...

heating and cooking. For instance, the class of nanomaterials called fullerenes are generated by burning gas, biomass, and candle. It can also be a byproduct...

are stronger for endohedral metallo-fullerenes, in which a positively charged metal ion is trapped inside a fullerene cage and makes it more electronegative...

nanomaterials, such as fullerenes, and inorganic nanomaterials based on other elements, such as silicon. Examples of nanomaterials include fullerenes, carbon nanotubes...

building blocks such as fullerenes, nanoparticles, and dendrimers becoming involved in synthetic systems. Supramolecular complexes are formed by non-covalent...