In chemistry, a Zintl phase is a product of a reaction between a group 1 (alkali metal) or group 2 (alkaline earth metal) and main group metal or metalloid...

case of aluminium, tin, and bismuth, respectively). They can also form Zintl phases (half-metallic compounds formed between highly electropositive metals...

that contains lead, or a Zintl phase compound with lead as the anion. Plumbides can be formed when lead forms a Zintl phase compound with a more metallic...

electropositive elements) affords polyarsenic compounds, which are members of the Zintl phases. See Category:Arsenides for a list. Greenwood, Norman N.; Earnshaw, Alan...

(2007). "Sr14[Al4]2[Ge]3: Eine Zintl-Phase mit isolierten [Ge]4–- und [Al4]8–-Anionen / Sr14[Al4]2[Ge]3: A Zintl Phase with Isolated [Ge]4–- and [Al4]8–...

(2007). "Sr14[Al4]2[Ge]3: Eine Zintl-Phase mit isolierten [Ge]4–- und [Al4]8–-Anionen / Sr14[Al4]2[Ge]3: A Zintl Phase with Isolated [Ge]4–- and [Al4]8–...

Quite recently, the aromaticity of planar Si56- rings occurring in the Zintl phase Li12Si7 was experimentally evidenced by Li solid state NMR. Metal aromaticity...

alkaline earth metal acetylides of the general formula MC≡CM are salt-like Zintl phase compounds, containing C2− 2 ions. Evidence for this ionic character can...

him to the discovery of the Zintl phases. The structure of Zintl phases were ionic, and the structure of the anion (aka Zintl ion) could result an electronic...

with Increased Electron Count and Their Comparison with the Nominal Zintl Phase La3In5". Inorg. Chem. 40 (27): 7020–7026. doi:10.1021/ic010804v. PMID 11754285...

Peter; Schnelle, Walter; Zhao, Jing-Tai; Grin, Yuri (5 October 2015). "Zintl-Phase Sr3LiAs2H: Crystal Structure and Chemical Bonding Analysis by the Electron...

1998). "Ba3AlO4H: Synthesis and Structure of a New Hydrogen-Stabilized Phase". Journal of Solid State Chemistry. 141 (2): 570–575. Bibcode:1998JSSCh...

Hume-Rothery) compounds Size packing phases. e.g. Laves phases, Frank–Kasper phases and Nowotny phases Zintl phases The definition of a metal is taken to...

synthesis and characterization of two broad classes of materials, notably Zintl phases and condensed transition metal halide clusters. Both classes of materials...

These can be classed as interstitial hydrides, Hydrogenated zintl phases, or Zintl phase hydrides. In the related silanides, SiH3− anions or groups occur...

obtained with reagent prepared from lithium and acetylene. Li2C2 is a Zintl phase compound and exists as a salt, with the formula [Li+]2[−C≡C−]. Its reactivity...

typeface designer (Palatino, Optima, Zapfino) Eduard Zintl, chemist and discoverer of the Zintl phase University and State Library Darmstadt "Welcome". Technische...

universe. In retrospect, the first nanoclustered ions discovered were the Zintl phases, intermetallics studied in the 1930s.[citation needed] The first set...

give a layered solid with the empirical formula GeH. The Ca sites in Zintl-phase CaGe2 interchange with the hydrogen atoms in the HCl solution, producing...

semimetal line, or the staircase. While it has also been called the Zintl border or the Zintl line these terms instead refer to a vertical line sometimes drawn...

November 2016. Röhr, C. (2017). "Binare Zintl-Phasen" [Binary Zintl Phases]. Intermetallische Phasen [Intermettallic Phases] (in German). Universitat Freiburg...

Potential uses include electrodes in lithium batteries. Li12Si7 has a Zintl phase with planar Si56− rings. Li NMR spectroscopy suggests these rings are...

complex metallic alloy has to be, but the broadest definition includes Zintl phases, skutterudites, and Heusler compounds on the most simple end, and quasicrystals...

tetrelarsenides, pnictidosilicates, or tetrelpnictides. They can be classed as Zintl phases or intermetallics. They are analogous to the nitridosilicates, phosphidosilicates...

Asbrand, Matthias; Eisenmann, Brigitte (1993). "Na2[SnAs2], the first Zintl phase with a [SnAs2] framework based on adamantane analogous [Sn4As10] units"...

intermetallic compounds. Bismanol, a magnetic alloy of bismuth and manganese Zintl phase E. Dönges (1963). "Phosphides, Arsenides, Antimonides and Bismuthides"...

under 414K results in the release of hydrogen and the formation of a Zintl-phase MSi. If an alkali silande is rapidly heated to 500K another irreversible...

Nikolaus; Gärtner, Stefanie (2019-04-25). "Synthesis of the Tetragonal Phase of Zintl's NaTl and Its Structure Determination from Powder Diffraction Data"...

for example in Laves phase and Hume-Rothery phases. Ligand-free intermetalloid clusters include also endohedrally filled Zintl clusters. A synonym for...

been used in the crystallization of Zintl ions such as Sn4− 9. Although rarely practical, cryptands can serve as phase transfer catalysts since their cationic...