Alkylation is a chemical reaction that entails transfer of an alkyl group. The alkyl group may be transferred as an alkyl carbocation, a free radical,...

An alkylation unit (alky) is one of the conversion processes used in petroleum refineries. It is used to convert isobutane and low-molecular-weight alkenes...

to an aromatic ring. Friedel–Crafts reactions are of two main types: alkylation reactions and acylation reactions. Both proceed by electrophilic aromatic...

Amine alkylation (amino-dehalogenation) is a type of organic reaction between an alkyl halide and ammonia or an amine. The reaction is called nucleophilic...

The Enders SAMP/RAMP hydrazone alkylation reaction is an asymmetric carbon-carbon bond formation reaction facilitated by pyrrolidine chiral auxiliaries...

selectively furnishes the (Z)-enolate, which can undergo stereoselective alkylation. Alkylation of an oxazolidinone imide with benzyl bromide Activated electrophiles...

In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom bonded to two organyl groups (e.g., alkyl or aryl). They...

The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate...

The Stork enamine alkylation involves the addition of an enamine to a Michael acceptor (e.g., an α,β -unsaturated carbonyl compound) or another electrophilic...

salts are necessary to colocate the reactants via complexation. In Birch alkylation the anion formed in the Birch reduction is trapped by a suitable electrophile...

effects. Industrially significant alkyl amines are prepared from ammonia by alkylation with alcohols: ROH + NH 3 ⟶ RNH 2 + H 2 O {\displaystyle {\ce {ROH + NH3...

the Fráter–Seebach alkylation (also known as Seebach–Fráter alkylation or Fráter–Seebach reaction) is a diastereoselective alkylation of chiral beta-hydroxy...

Lewis acids. A classic preparation of sulfonates is the Strecker sulfite alkylation, in which an alkali sulfite salt displaces a halide, typically in the...

counterparts, they can still react selectively, rendering them useful for alkylation reactions. The enamine nucleophile can attack haloalkanes to form the...

Pennsylvania. A release of hydrocarbons and hydrofluoric acid in the refinery's alkylation unit caused a ground-hugging vapor cloud which rapidly ignited, leading...

well as the phenol. Cumene is formed in the gas-phase Friedel–Crafts alkylation of benzene by propene. Benzene and propene are compressed together to...

"Haloalkanes and ammonia". www.chemguide.co.uk. Ashenhurst, James (2017-05-26). "Alkylation of Amines". Master Organic Chemistry. Werner, Emil Alphonse (1918-01-01)...

In chemistry, cyanide (from Greek kyanos 'dark blue') is a chemical compound that contains a C≡N functional group. This group, known as the cyano group...

cumene is by Friedel–Crafts alkylation of benzene with propylene. The original route for manufacturing of cumene was by alkylation of benzene in the liquid...

effects. This diagram shows an o-alkylation between phenol and methanol. Unlike the c-alkylation, the o-alkylation replaces the hydrogen atom on the...

1951 and came into medical use in 1960. Carbocisteine is produced by alkylation of cysteine with chloroacetic acid. Carbocisteine. drugbank.ca Zheng JP...

DIPEA is commercially available. It is traditionally prepared by the alkylation of diisopropylamine with diethyl sulfate. Pure DIPEA exists as a colorless...

scale in the petroleum industry by alkylation of isobutene with isobutane. This process is conducted in alkylation units in the presence of acid catalysts...

plant is not stored but piped directly to the Alkylation plant where it is consumed. If the Alkylation plant cannot accept the ethylene, the gas is sent...

Friedel-Crafts alkylation and related reactions. AlCl3 is a common Lewis-acid catalyst for Friedel-Crafts reactions, both acylations and alkylations. Important...

elaboration of phenol or cresols. They are typically produced by the alkylation of benzene/toluene with propylene to form cumene then O 2 is added with...

halides. The primary difficulty for alkylation reactions employing nitrile anions is over-alkylation. In the alkylation of acetonitrile, for instance, yields...

are aromatic nitration, aromatic halogenation, aromatic sulfonation, alkylation Friedel–Crafts reaction and acylation Friedel–Crafts reaction. The most...

polymerization, 2) oxidation, 3) halogenation and hydrohalogenation, 4) alkylation, 5) hydration, 6) oligomerization, and 7) hydroformylation. In the United...

chlorphenamine. A second method boom starts from pyridine, which undergoes alkylation by 4-chlorophenylacetonitrile, giving 2-(4-chlorobenzyl)pyridine. Alkylating...