In chemistry, bond cleavage, or bond fission, is the splitting of chemical bonds. This can be generally referred to as dissociation when a molecule is...

of bond cleavage patterns are simple bond cleavage reactions and rearrangement reactions. Majority of organic compounds undergo simple bond cleavage reactions...

weaker van der Waals bond. This gives graphite a single direction of cleavage, parallel to the basal pinacoid. So weak is this bond that it is broken with...

breaking of a chemical bond. These processes are known as homolytic cleavage and heterolytic cleavage. Homolytic bond cleavage is a process where the...

controlled break in an optical fiber Bond cleavage, in chemistry and biochemistry, the splitting of chemical bonds Cleavage factor, a protein complex that helps...

covalent bond where one previously bonded species takes both original bonding electrons from the other species. During heterolytic bond cleavage of a neutral...

the two electrons involved in the original bond are distributed between the two fragment species. Bond cleavage is also possible by a process called heterolysis...

corresponding alcohols or alkanes. There are two common cleavage modes. α-cleavage and C-O bond cleavage. Aromatic ethers can generate the C6H5O+ ion by loss...

other homolytic cleavages which can in turn lead to more damage. Polymers have also been observed to undergo heterolytic bond cleavage through isotope...

is called homolytic bond cleavage (homolytic cleavage; homolysis) and results in the formation of radicals. The strength of a bond can be estimated by...

more energy must be supplied to break the bond, resulting in a higher activation energy for bond cleavage, which in turn lowers the measured rate (see...

Water is required for normal peptide bond cleavage of the iminolactone intermediate. In formic acid, cleavage of Met-Ser and Met-Thr bonds is enhanced...

which a C–H bond, one that is typically considered to be "unreactive", interacts with a transition metal center M, resulting in its cleavage and the generation...

ε0 holds. The bond dissociation energy is an enthalpy change of a particular chemical process, namely homolytic bond cleavage, and "bond strength" as measured...

facilitates the attack of CO2 at the C2 carbon of RuBP and subsequent bond cleavage between the C3 and C2 carbon, 2 molecules of glycerate-3-phosphate are...

result, the cleavage of unstrained compounds that have been achieved is mainly focused on ketone substrates. This is because the C–C bond adjacent to...

to a fragment that departs with a pair of electrons in heterolytic bond cleavage. In this usage, a leaving group is a less formal but more commonly used...

is employed to protect ketones. With sodium amide resulting in C–C bond cleavage with formation of the amide RCONH2 and the alkane or arene R'H, a reaction...

through the interaction with electromagnetic radiation. Heterolytic bond cleavage and heterolytic substitution reactions can result in the formation of...

site, transferring the positive charge to this atom as a result of the bond cleavage. Todd, J. F. J. (1991). "Recommendations for nomenclature and symbolism...

with the molecular motions of Mn2(CO)10, as well as the Mn-Mn and Mn-C bond cleavage events. Mn2(CO)10 is air stable as a crystalline solid, but solutions...

Alpha-cleavage (α-cleavage) in organic chemistry refers to the act of breaking the carbon-carbon bond adjacent to the carbon bearing a specified functional...

information by activation of higher charged proteins. Moreover, disulfide bond cleavage takes place by ECD of multiply charge proteins or peptides produced...

the breaking of a peptide bond. The existence of this seventh catalytic type of proteases, in which the peptide bond cleavage occurs by self-processing...

Cleavage is the narrow depression or hollow between the breasts of a woman. The superior portion of cleavage may be accentuated by clothing such as a low-cut...

LCCN 64-25218. Nogi, Keisuke; Yorimitsu, Hideki (2021). "Carbon–Carbon Bond Cleavage at Allylic Positions: Retro-allylation and Deallylation". Chemical Reviews...

R−S−S−R′ functional group or the S2− 2 anion. The linkage is also called an SS-bond or sometimes a disulfide bridge and usually derived from two thiol groups...

self-processing domain, cleavage of the Asn-Pro bond in Salmonella FlhB protein, Yersinia YscU protein, as well as cleavage of the Gly-Ser bond in a subset of...

intramolecular ligand bond cleavage of the ligand (probably by donation of electron pair into the sigma* orbital of the inter ligand bond) to form the oxidized...

protonate N-3 of adenine and break the bond between N-9 of the adenine ring and C-1' of the ribose. Bond cleavage results in an oxycarbonium ion on the...