Borane dimethylsulfide (BMS) is a chemical compound with the chemical formula BH3·S(CH3)2. It is an adduct between borane molecule (BH3) and dimethyl...
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but may be easily oxidised in air. Solutions containing borane dimethylsulfide and borane–tetrahydrofuran are commercially available; in tetrahydrofuran...
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instantly to form diborane, B2H6. Its adduct borane–tetrahydrofuran and borane–dimethylsulfide are useful in hydroboration reactions. Greenwood, Norman N.; Earnshaw...
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secondary boranes are less common. Tert-butylamine borane (tBuNH2→BH3) Phosphine-borane (R3P→BH3) Borane dimethylsulfide ((CH3)2S→BH3) Borane–tetrahydrofuran...
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synthesis of organic compounds. The use of borane–tetrahydrofuran has been displaced by borane–dimethylsulfide, which has a longer shelf life and effects...
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Hydroboration (section Borane adducts)
hydroboration employed diborane as a source of BH3. Usually however, borane dimethylsulfide complex BH3S(CH3)2 (BMS) is used instead. It can be obtained in...
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Diborane (category Boranes)
work on hydroboration relied on diborane, it has been replaced by borane dimethylsulfide, which is more safely handled. Pyrolysis of diborane gives hydrogen...
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Catecholborane (category Boranes)
Catecholborane is less reactive in hydroborations than borane-THF or borane-dimethylsulfide. When catecholborane is treated with a terminal alkyne, a...
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catalyst is used along with borane-tetrahydrofuran (THF), borane-dimethylsulfide, borane-N,N-diethylaniline, or diborane as the borane source. Enantioselective...
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been extensively examined. With borane-dimethylsulfide, two equivalents of α-pinene react to give (diisopinocampheyl)borane. Reaction with 9-BBN gives the...
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management system Bridge management system Building management system Borane dimethylsulfide, a chemical Bone marrow suppression Burning mouth syndrome, also...
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co-workers was achieved via an enantioselective CBS reduction using a borane-dimethylsulfide complex. Corey-Fuchs alkyne synthesis is the synthesis of terminal...
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Carborane (redirect from Carbo-borane)
produced from decaborane and formaldehyde, followed by addition of borane dimethylsulfide. Monocarboranes are precursors to weakly coordinating anions. Dicarbaboranes...
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Fontaine, Frédéric-Georges (2014-08-28). "Lewis base activation of borane–dimethylsulfide into strongly reducing ion pairs for the transformation of carbon...
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it is produced by the reduction of the amino acid tyrosine with borane dimethylsulfide. The compound, which is chiral, is an example of a 1,2-ethanolamine...
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prepared by reaction of trifluoroethanol with boron trichloride, borane dimethylsulfide, boron tribromide, or boric anhydride. The latter is more convenient...
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Dimethyl sulfide (redirect from Dimethylsulfide)
thioether produced industrially. One major use is for the production of borane dimethyl sulfide from diborane: B2H6 + 2 (CH3)2S → 2 BH3·S(CH3)2 Oxidation...
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in the 1940s by Standard Oil of Indiana, was based on oxidation of dimethylsulfide by O 2 from air. Although inexpensive, this process suffered from a...
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[Pd(Me-DuPhos(MeCN)2)](BF4)2 Mono oxidation of (R,R)-Me-Duphos using borane dimethylsulfide as protective group and hydrogen peroxide as oxidizing agent gives...
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acetate, CID:70104936 (4). Reduction of the imide with Borane dimethylsulfide afforded [182621-51-8] (5). The reaction of this intermediate with...
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ozonolysis. Often the reaction procedure includes a mild reductant, such as dimethylsulfide (SMe2): RCH=CHR' + O3 + SMe2 → RCHO + R'CHO + O=SMe2 R2C=CHR' + O3...
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solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts". Chemical Communications. 53 (59): 8265–8267. doi:10.1039/c7cc03148c...
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