Borane dimethylsulfide (BMS) is a chemical compound with the chemical formula BH3·S(CH3)2. It is an adduct between borane molecule (BH3) and dimethyl...

but may be easily oxidised in air. Solutions containing borane dimethylsulfide and borane–tetrahydrofuran are commercially available; in tetrahydrofuran...

instantly to form diborane, B2H6. Its adduct borane–tetrahydrofuran and borane–dimethylsulfide are useful in hydroboration reactions. Greenwood, Norman N.; Earnshaw...

secondary boranes are less common. Tert-butylamine borane (tBuNH2→BH3) Phosphine-borane (R3P→BH3) Borane dimethylsulfide ((CH3)2S→BH3) Borane–tetrahydrofuran...

synthesis of organic compounds. The use of borane–tetrahydrofuran has been displaced by borane–dimethylsulfide, which has a longer shelf life and effects...

hydroboration employed diborane as a source of BH3. Usually however, borane dimethylsulfide complex BH3S(CH3)2 (BMS) is used instead. It can be obtained in...

work on hydroboration relied on diborane, it has been replaced by borane dimethylsulfide, which is more safely handled. Pyrolysis of diborane gives hydrogen...

Catecholborane is less reactive in hydroborations than borane-THF or borane-dimethylsulfide. When catecholborane is treated with a terminal alkyne, a...

catalyst is used along with borane-tetrahydrofuran (THF), borane-dimethylsulfide, borane-N,N-diethylaniline, or diborane as the borane source. Enantioselective...

been extensively examined. With borane-dimethylsulfide, two equivalents of α-pinene react to give (diisopinocampheyl)borane. Reaction with 9-BBN gives the...

management system Bridge management system Building management system Borane dimethylsulfide, a chemical Bone marrow suppression Burning mouth syndrome, also...

co-workers was achieved via an enantioselective CBS reduction using a borane-dimethylsulfide complex. Corey-Fuchs alkyne synthesis is the synthesis of terminal...

produced from decaborane and formaldehyde, followed by addition of borane dimethylsulfide. Monocarboranes are precursors to weakly coordinating anions. Dicarbaboranes...

Fontaine, Frédéric-Georges (2014-08-28). "Lewis base activation of borane–dimethylsulfide into strongly reducing ion pairs for the transformation of carbon...

it is produced by the reduction of the amino acid tyrosine with borane dimethylsulfide. The compound, which is chiral, is an example of a 1,2-ethanolamine...

prepared by reaction of trifluoroethanol with boron trichloride, borane dimethylsulfide, boron tribromide, or boric anhydride. The latter is more convenient...

thioether produced industrially. One major use is for the production of borane dimethyl sulfide from diborane: B2H6 + 2 (CH3)2S → 2 BH3·S(CH3)2 Oxidation...

in the 1940s by Standard Oil of Indiana, was based on oxidation of dimethylsulfide by O 2 from air. Although inexpensive, this process suffered from a...

[Pd(Me-DuPhos(MeCN)2)](BF4)2 Mono oxidation of (R,R)-Me-Duphos using borane dimethylsulfide as protective group and hydrogen peroxide as oxidizing agent gives...

acetate, CID:70104936 (4). Reduction of the imide with Borane dimethylsulfide afforded [182621-51-8] (5). The reaction of this intermediate with...

ozonolysis. Often the reaction procedure includes a mild reductant, such as dimethylsulfide (SMe2): RCH=CHR' + O3 + SMe2 → RCHO + R'CHO + O=SMe2 R2C=CHR' + O3...

solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts". Chemical Communications. 53 (59): 8265–8267. doi:10.1039/c7cc03148c...