Chemoselectivity is the preferential reaction of a chemical reagent with one of two or more different functional groups. In a chemoselective system, a...

sacrificial alcohol. The advantages of the MPV reduction lie in its high chemoselectivity and its use of a cheap environmentally friendly metal catalyst. MPV...

pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life. However...

tolerated. In this sense, chemoselectivity is sometimes referred to as functional group tolerance. Furthermore, high chemoselectivity avoids often undesired...

in biology Reactivity–selectivity principle, in general chemistry Chemoselectivity, a term used in organic chemistry to describe reactivity of one functional...

couple with chlorinated arenes. This low reactivity is the basis for chemoselectivity for nickel insertion into the C–Br bond of bromochlorobenzene using...

variations of the Grignard reagent have been discovered to improve the chemoselectivity of the Grignard reaction, which include but are not limited to: Turbo-Grignards...

aromatic ring to give acetyl aromatic esters instead of methyl benzoates. Chemoselectivity Cryptoregiochemistry Enantioselectivity Keto–enol tautomerism Stereoselectivity...

considerations to be made when designing a reductive amination reaction. Chemoselectivity issues may arise since the carbonyl group is also reducible. The reaction...

Nitrosation. Cambridge, UK: Cambridge University. p. 16. ISBN 0-521-26796-X. Chemoselective Nitration of Phenols with tert-Butyl Nitrite in Solution and on Solid...

powerful single-electron reducing agent, it does display remarkable chemoselectivity among functional groups. For example, sulfones and sulfoxides can be...

therefore distinguish between very similar substrate molecules to be chemoselective, regioselective and stereospecific. Some of the enzymes showing the...

(−)-pinoresinol. Dynamic stereochemistry Torquoselectivity Regioselectivity Chemoselectivity (a)"Overlap Control of Carbanionoid Reactions. I. Stereoselectivity...

Since sodium cyanoborohydride is a mild reducing agent, it gives good chemoselectivity for reaction with certain functional groups in the presence of others...

cycle; see the Milas hydroxylation. Drawbacks of peroxides include chemoselectivity issues. Trialkylammonium N-oxides, such as NMO—as in the Upjohn Reaction—and...

pub2. ISBN 978-3527306732. McGrath, N. A.; Raines, R. T. (2011). "Chemoselectivity in chemical biology: Acyl transfer reactions with sulfur and selenium"...

stoichiometric amount of sodium chlorite. TEMPO oxidations also exhibit chemoselectivity, being inert towards secondary alcohols, but the reagent will convert...

acyl shift) amide-forming step under the reaction conditions used. Chemoselectivity of NCL : No side-products are formed from reaction with the other functional...

chemistry. As isocyanides exhibit high functional group tolerance, chemoselectivity, regioselectivity, and stereoselectivity, the Passerini reaction has...

molecule by chemical modification of a functional group to obtain chemoselectivity in a subsequent chemical reaction. It plays an important role in multistep...

Akula, Venugopal (2021-09-05). "Influence of Brønsted acid sites on chemoselective synthesis of pyrrolidones over H-ZSM-5 supported copper catalyst". Applied...

wide range of different types of ketones in both a stereoselective and chemoselective manner. Substrates include a large variety of aryl-aliphatic, di-aliphatic...

acid–base theory Acid dissociation constants Lewis acids and bases Chemoselectivity Molecular structure Aromaticity Chemical bonding Covalent bonding Lewis...

J. S. Dileep; Ho, ManKit M.; Toyokuni, Tatsushi (2001). "Simple and chemoselective reduction of aromatic nitro compounds to aromatic amines: reduction...

N-Dimethyl(chloromethylene)ammonium chloride; [ClHC=N+(CH3)2]Cl−) is a highly chemoselective agent for carboxylic acid reduction. It selectively activates the carboxylic...

molecule by chemical modification of a functional group to obtain chemoselectivity in a subsequent chemical reaction, facilitating multistep organic synthesis...

catalytic properties. Lanthanide-containing polyoxometalates show chemoselectivity and are also able to form inorganic–organic adducts, which can be exploited...

Pierre; Islam, Saidul; Powner, Matthew W. (2019). "Peptide ligation by chemoselective aminonitrile coupling in water". Nature. 571 (7766): 546–549. doi:10...

1002/(issn)1521-3773a. "Zirconium Tetrachloride (ZrCl4) Catalyzed Highly Chemoselective and Efficient Acetalization of Carbonyl Compounds". www.organic-chemistry...

(1996). "Organotin-Mediated Monoacylation of Diols with Reversed Chemoselectivity". Journal of Organic Chemistry. 61 (16): 5257–5263. doi:10.1021/jo960453f...