• Thumbnail for Diels–Alder reaction
    In organic chemistry, the DielsAlder reaction is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile...
    62 KB (7,088 words) - 00:41, 15 November 2024
  • The retro-DielsAlder reaction (rDA reaction) is the reverse of the DielsAlder (DA) reaction, a [4+2] cycloelimination. It involves the formation of...
    13 KB (1,538 words) - 22:24, 27 September 2024
  • Thumbnail for Aza-Diels–Alder reaction
    The Aza-DielsAlder reaction is a modification of the DielsAlder reaction wherein a nitrogen replaces sp2 carbon. The nitrogen atom can be part of the...
    9 KB (968 words) - 17:26, 16 November 2024
  • six-membered ring are formed. It is related to the DielsAlder reaction, but unlike the DielsAlder (or DA) reaction, the DAINV is a cycloaddition between an electron-rich...
    26 KB (2,637 words) - 20:27, 12 July 2024
  • In organic chemistry, the hexadehydro-DielsAlder (HDDA) reaction is an organic chemical reaction between a diyne (2 alkyne functional groups arranged...
    19 KB (2,205 words) - 22:23, 27 September 2024
  • An oxo-DielsAlder reaction (also called an oxa-DielsAlder reaction) is an organic reaction and a variation of the DielsAlder reaction in which a suitable...
    2 KB (148 words) - 13:44, 13 November 2024
  • Thumbnail for Otto Diels
    German chemist. His most notable work was done with Kurt Alder on the DielsAlder reaction, a method for cyclohexene synthesis. The pair was awarded the Nobel...
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  • Thumbnail for Kurt Alder
    known as the DielsAlder reaction. The lunar crater Alder is named in his honour. The insecticide aldrin, created through a DielsAlder reaction, is also...
    6 KB (531 words) - 16:59, 23 October 2024
  • the retro-DielsAlder reaction. Reactions involving heteroatoms are known, including the aza-DielsAlder reaction and oxo-DielsAlder reaction. The Huisgen...
    12 KB (1,313 words) - 01:23, 15 November 2024
  • Thumbnail for Thermodynamic versus kinetic reaction control
    principle.) The DielsAlder reaction of cyclopentadiene with furan can produce two isomeric products. At room temperature, kinetic reaction control prevails...
    21 KB (2,751 words) - 18:12, 1 November 2024
  • his work on the DielsAlder reaction Ludwig Diels (1874–1945), German botanist whose standard author abbreviation is Diels Hermann Diels (1848–1922), German...
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  • dimerizes over the course of hours to give dicyclopentadiene via a DielsAlder reaction. This dimer can be restored by heating to give the monomer. The compound...
    13 KB (1,040 words) - 05:40, 13 August 2024
  • Lewis acid catalysis (category Chemical reactions)
    lowers the Diels-Alder reaction barrier. In addition, the Lewis acid catalyst also increases the asynchronicity of the Diels-Alder reaction, making the...
    45 KB (5,026 words) - 04:16, 15 October 2024
  • common in drug synthesis. Common reaction types include DielsAlder reactions, the ene reaction, [2+2] cycloaddition reactions, hydrocyanation of aldehydes...
    11 KB (1,242 words) - 23:24, 12 November 2023
  • referred to simply as Click reactions Thiol-ene reaction Diels-Alder reaction and inverse electron demand Diels-Alder reaction [4+1] cycloadditions between...
    48 KB (5,450 words) - 01:17, 21 November 2024
  • aromatic compounds into cycloalkenes, specifically cyclohexadiene. The Diels-Alder reaction, also known as cycloaddition, combines a conjugated diene and an...
    12 KB (1,178 words) - 19:35, 16 November 2024
  • Thumbnail for Cheletropic reaction
    reaction. The activation enthalpy for the hetero-DielsAlder reaction is about 8 kJ/mol smaller than that for the corresponding cheletropic reaction....
    14 KB (1,611 words) - 13:49, 6 May 2024
  • 3-dipolar cycloaddition of alkynes and nitrones in the Kinugasa reaction Diels-Alder reaction between cyclopentadiene and chlorosulfonyl isocyanate (CSI)...
    6 KB (470 words) - 12:52, 23 November 2024
  • Thumbnail for 1,3-Diphenylisobenzofuran
    diene that can scavenge unstable and short-lived dienophiles in a Diels-Alder reaction. It is furthermore used as a standard reagent for the determination...
    20 KB (1,956 words) - 11:06, 23 October 2024
  • Thumbnail for Ene reaction
    organic chemistry, the ene reaction (also known as the Alder-ene reaction by its discoverer Kurt Alder in 1943) is a chemical reaction between an alkene with...
    27 KB (3,345 words) - 05:39, 27 October 2024
  • importance as a reagent in Diels-Alder reactions. It reacts with norbornadiene in a sequence of one DA reaction and two retro-DA reactions to cyclopentadiene...
    3 KB (323 words) - 15:40, 5 October 2024
  • The Ugi reaction has been applied in combination with an intramolecular Diels-Alder reaction in an extended multistep reaction. A reaction in its own...
    14 KB (1,497 words) - 00:51, 7 October 2024
  • induces elimination of triflate and release of benzyne: A hexadehydro Diels-Alder reaction (HDDA) involves cycloaddition of 1,3-diyne and alkyne. N-amination...
    28 KB (3,128 words) - 04:03, 9 November 2024
  • Thumbnail for Chemical reaction
    a cyclic molecule. An important example of cycloaddition reaction is the DielsAlder reaction (the so-called [4+2] cycloaddition) between a conjugated...
    66 KB (8,043 words) - 01:08, 14 October 2024
  • Thumbnail for Allylic strain
    an intramolecular Diels Alder reaction gave a mixture of diastereomers. But by installing the a bulky TMS substituent, the reaction gave the desired product...
    21 KB (2,466 words) - 08:33, 1 September 2023
  • (intermolecular) DielsAlder reaction effects. Intramolecular Diels-Alder cycloaddition has been used in total synthesis. Through this reaction polycyclic compounds...
    4 KB (442 words) - 15:07, 19 November 2023
  • Thumbnail for Sulfolene
    dienophile and forms the corresponding Diels-Alder adduct. As early as 1938, Kurt Alder and co-workers reported Diels-Alder adducts from the isomeric 2-sulfolene...
    18 KB (1,855 words) - 22:33, 23 October 2024
  • 3-bromo-4-nitrobenzoic acid was not detected. The ortho effect occurs in Diels-Alder reactions when the Z-substituted dienophiles react with 1-substituted butadienes...
    8 KB (938 words) - 01:22, 25 October 2024
  • Thumbnail for Organic reaction
    invention of specific organic reactions such as the Grignard reaction in 1912, the DielsAlder reaction in 1950, the Wittig reaction in 1979 and olefin metathesis...
    14 KB (1,182 words) - 20:28, 22 July 2024
  • Thumbnail for Woodward–Hoffmann rules
    even, the reaction is symmetry-allowed. This prediction agrees with experiment as the Diels-Alder reaction is a rather facile pericyclic reaction. A 4n electron...
    93 KB (11,923 words) - 14:39, 12 August 2024