In organic chemistry, the Diels–Alder reaction is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile...
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The retro-Diels–Alder reaction (rDA reaction) is the reverse of the Diels–Alder (DA) reaction, a [4+2] cycloelimination. It involves the formation of...
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The Aza-Diels–Alder reaction is a modification of the Diels–Alder reaction wherein a nitrogen replaces sp2 carbon. The nitrogen atom can be part of the...
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six-membered ring are formed. It is related to the Diels–Alder reaction, but unlike the Diels–Alder (or DA) reaction, the DAINV is a cycloaddition between an electron-rich...
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In organic chemistry, the hexadehydro-Diels–Alder (HDDA) reaction is an organic chemical reaction between a diyne (2 alkyne functional groups arranged...
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An oxo-Diels–Alder reaction (also called an oxa-Diels–Alder reaction) is an organic reaction and a variation of the Diels–Alder reaction in which a suitable...
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German chemist. His most notable work was done with Kurt Alder on the Diels–Alder reaction, a method for cyclohexene synthesis. The pair was awarded the Nobel...
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known as the Diels–Alder reaction. The lunar crater Alder is named in his honour. The insecticide aldrin, created through a Diels–Alder reaction, is also...
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Cycloaddition (redirect from Cycloaddition reaction)
the retro-Diels–Alder reaction. Reactions involving heteroatoms are known, including the aza-Diels–Alder reaction and oxo-Diels–Alder reaction. The Huisgen...
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principle.) The Diels–Alder reaction of cyclopentadiene with furan can produce two isomeric products. At room temperature, kinetic reaction control prevails...
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his work on the Diels–Alder reaction Ludwig Diels (1874–1945), German botanist whose standard author abbreviation is Diels Hermann Diels (1848–1922), German...
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Cyclopentadiene (section Diels–Alder reactions)
dimerizes over the course of hours to give dicyclopentadiene via a Diels–Alder reaction. This dimer can be restored by heating to give the monomer. The compound...
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Lewis acid catalysis (category Chemical reactions)
lowers the Diels-Alder reaction barrier. In addition, the Lewis acid catalyst also increases the asynchronicity of the Diels-Alder reaction, making the...
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Chiral Lewis acid (section Diels–Alder reaction)
common in drug synthesis. Common reaction types include Diels–Alder reactions, the ene reaction, [2+2] cycloaddition reactions, hydrocyanation of aldehydes...
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Click chemistry (redirect from Click reaction)
referred to simply as Click reactions Thiol-ene reaction Diels-Alder reaction and inverse electron demand Diels-Alder reaction [4+1] cycloadditions between...
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Cycloalkene (section Diels-Alder reaction)
aromatic compounds into cycloalkenes, specifically cyclohexadiene. The Diels-Alder reaction, also known as cycloaddition, combines a conjugated diene and an...
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reaction. The activation enthalpy for the hetero-Diels–Alder reaction is about 8 kJ/mol smaller than that for the corresponding cheletropic reaction....
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Lactam (section Diels-Alder reaction)
3-dipolar cycloaddition of alkynes and nitrones in the Kinugasa reaction Diels-Alder reaction between cyclopentadiene and chlorosulfonyl isocyanate (CSI)...
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diene that can scavenge unstable and short-lived dienophiles in a Diels-Alder reaction. It is furthermore used as a standard reagent for the determination...
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organic chemistry, the ene reaction (also known as the Alder-ene reaction by its discoverer Kurt Alder in 1943) is a chemical reaction between an alkene with...
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importance as a reagent in Diels-Alder reactions. It reacts with norbornadiene in a sequence of one DA reaction and two retro-DA reactions to cyclopentadiene...
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The Ugi reaction has been applied in combination with an intramolecular Diels-Alder reaction in an extended multistep reaction. A reaction in its own...
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Aryne (section Reactions of arynes)
induces elimination of triflate and release of benzyne: A hexadehydro Diels-Alder reaction (HDDA) involves cycloaddition of 1,3-diyne and alkyne. N-amination...
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a cyclic molecule. An important example of cycloaddition reaction is the Diels–Alder reaction (the so-called [4+2] cycloaddition) between a conjugated...
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Allylic strain (section Diels-Alder reaction)
an intramolecular Diels Alder reaction gave a mixture of diastereomers. But by installing the a bulky TMS substituent, the reaction gave the desired product...
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(intermolecular) Diels–Alder reaction effects. Intramolecular Diels-Alder cycloaddition has been used in total synthesis. Through this reaction polycyclic compounds...
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Sulfolene (section Diels-Alder reactions)
dienophile and forms the corresponding Diels-Alder adduct. As early as 1938, Kurt Alder and co-workers reported Diels-Alder adducts from the isomeric 2-sulfolene...
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Ortho effect (section Diels-Alder reactions)
3-bromo-4-nitrobenzoic acid was not detected. The ortho effect occurs in Diels-Alder reactions when the Z-substituted dienophiles react with 1-substituted butadienes...
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invention of specific organic reactions such as the Grignard reaction in 1912, the Diels–Alder reaction in 1950, the Wittig reaction in 1979 and olefin metathesis...
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even, the reaction is symmetry-allowed. This prediction agrees with experiment as the Diels-Alder reaction is a rather facile pericyclic reaction. A 4n electron...
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