Isotope fractionation describes fractionation processes that affect the relative abundance of isotopes, phenomena which are taken advantage of in isotope...
3 KB (316 words) - 18:27, 14 May 2024
Mass-independent isotope fractionation or Non-mass-dependent fractionation (NMD), refers to any chemical or physical process that acts to separate isotopes, where...
11 KB (1,220 words) - 20:53, 13 June 2024
expression stable-isotope ratio is preferably used to refer to isotopes whose relative abundances are affected by isotope fractionation in nature. This...
15 KB (1,834 words) - 06:16, 3 November 2024
T in K Different researchers have also used other fractionation factors like dolomite fractionation factor. While measuring samples of unknown composition...
34 KB (3,834 words) - 00:28, 6 November 2024
natural radioactivity. For most stable isotopes, the magnitude of fractionation from kinetic and equilibrium fractionation is very small; for this reason, enrichments...
21 KB (2,408 words) - 19:03, 1 April 2024
and conditions that favor this fractionation. The table below summarizes the reported fractionations of oxygen isotopes from MSO in different organisms...
59 KB (6,037 words) - 21:56, 22 September 2024
3-phosphoglyceraldehyde. Isotope fractionation due to Rubisco (form I) carboxylation alone is predicted to be a 28‰ depletion, on average. However, fractionation values...
36 KB (4,271 words) - 20:26, 19 June 2024
Fractionation is a separation process in which a certain quantity of a mixture (of gasses, solids, liquids, enzymes, or isotopes, or a suspension) is divided...
5 KB (483 words) - 04:39, 30 October 2024
The isotopic fractionation of a natural process can be calculated from measured isotope abundances. The calculated value is called a "fractionation factor...
76 KB (8,512 words) - 21:55, 22 September 2024
49 (indium). A 2021 study has shown at high ionic strengths, Cd isotope fractionation mainly depends on its complexation with carboxylic sites. At low...
15 KB (912 words) - 01:45, 10 October 2024
isotope effect Reaction mechanism Transient kinetic isotope fractionation Urey–Bigeleisen–Mayer equation Westaway KC (2006). "Using kinetic isotope effects...
99 KB (13,885 words) - 23:32, 1 September 2024
When these isotope ratios are measured by TIMS, mass-dependent fractionation occurs as species are emitted by the hot filament. Fractionation occurs due...
20 KB (2,547 words) - 22:52, 26 August 2024
Kinetic fractionation is an isotopic fractionation process that separates stable isotopes from each other by their mass during unidirectional processes...
4 KB (463 words) - 21:38, 30 September 2024
as polar ice or calcite in ocean core samples, measured with the isotope fractionation. The ratio is linked to ancient ocean temperature which in turn...
10 KB (1,104 words) - 00:14, 19 June 2024
particular to describe isotopic enrichment or depletion as material moves between reservoirs in an equilibrium process. Rayleigh fractionation holds particular...
3 KB (368 words) - 12:34, 24 August 2021
Natural abundance (redirect from Isotope abundance)
began, can generally be accounted for by mass fractionation (see the article on mass-independent fractionation) plus a limited number of nuclear decay and...
7 KB (727 words) - 16:32, 11 August 2024
Moreover, oil is also affected by isotope fractionation from phase changes. However, the behavior of oil gas-liquid fractionation differs from water as the vapor...
236 KB (30,181 words) - 15:38, 15 November 2024
partial separation of isotopes between different pools is termed isotope fractionation, and is mathematically described by fractionation factors α or ε (which...
110 KB (13,535 words) - 15:58, 2 November 2024
therefore isotopic effects cannot be described with the classical equilibrium fractionation equations or with steady-state kinetic fractionation equations...
25 KB (4,891 words) - 20:01, 7 August 2024
S; Canfield, Donald E; Rethmeier, J̈org (August 1998). "Sulfur isotope fractionation during bacterial reduction and disproportionation of thiosulfate...
17 KB (1,894 words) - 00:13, 14 November 2024
Martin J.; Jolis, Ester M.; Freda, Carmela (2016-08-04). "Boron isotope fractionation in magma via crustal carbonate dissolution". Scientific Reports...
48 KB (6,001 words) - 03:30, 13 November 2024
Urey–Bigeleisen–Mayer equation (category Isotopes)
model, is a model describing the approximate equilibrium isotope fractionation in an isotope exchange reaction. While the equation itself can be written...
25 KB (2,369 words) - 15:00, 20 May 2024
Equilibrium isotope fractionation is the partial separation of isotopes between two or more substances in chemical equilibrium. Equilibrium fractionation is strongest...
6 KB (822 words) - 21:45, 21 September 2023
underwent hydrodynamic escape, which accounts for the noble gas isotope fractionation present in their atmospheres. Irwin, Patrick G. J. (2006). Giant...
11 KB (1,326 words) - 08:07, 24 April 2023
carbonates shows little isotopic fractionation, while carbon in materials originated by photosynthesis is depleted of the heavier isotopes. In addition, there...
41 KB (4,710 words) - 04:25, 11 November 2024
induced the sulfur isotope mass-independent fractionation (Δ33S ≠ 0). The preservation of sulfur isotope mass-independent fractionation signals requires...
61 KB (7,395 words) - 23:39, 3 November 2024
The kinetic isotope effect (KIE) of ribulose-1,5-bisphosphate carboxylase oxygenase (RuBisCO) is the isotopic fractionation associated solely with the...
21 KB (2,412 words) - 11:33, 18 August 2023
Δ34S (category Isotopes of sulfur)
unsuitability as a reference standard. Two mechanisms of fractionation occur that alter sulfur stable isotope ratios: kinetic effects, especially due to the metabolism...
12 KB (1,405 words) - 22:28, 18 October 2024
C/12 C ratio in the atmosphere, both geographically and over time Isotopic fractionation Variations in the 14 C/12 C ratio in different parts of the reservoir...
28 KB (3,949 words) - 07:17, 15 January 2024