In the nomenclature of organic chemistry, a locant is a term to indicate the position of a functional group or substituent within a molecule. The International...
7 KB (866 words) - 20:00, 2 April 2024
recommendations of the IUPAC. Stereodescriptors are often used in combination with locants to clearly identify a chemical structure unambiguously. The descriptors...
21 KB (2,421 words) - 20:00, 4 June 2024
skipped if they do not apply. Has the lowest-numbered locant (or locants) for heteroatoms. Locants are the numbers on the carbons to which the substituent...
40 KB (4,496 words) - 10:59, 10 July 2024
indicated by a numerical locant immediately preceding the "-yne" suffix, or locants in the case of multiple triple bonds. Locants are chosen to be as low...
2 KB (248 words) - 22:09, 26 October 2023
three carbon atoms, the preferred IUPAC name is 2-methylpropane but the locant (2-) is typically omitted in general nomenclature as redundant; C2 is the...
14 KB (977 words) - 17:22, 19 March 2024
coefficients of a set of linear equations (see Cramer's rule). That an associated locant number represents the location of a covalent bond in an organic compound...
11 KB (1,159 words) - 12:43, 28 July 2024
mistake fixed in the errata Archived 2019-08-01 at the Wayback Machine. The locant is omitted according to P-14.3.4.2 (d), p. 31. "Front Matter". Nomenclature...
8 KB (721 words) - 18:42, 5 May 2024
terminology, n (or ω) represents the locant of the methyl end of the molecule, while the number n−x (or ω−x) refers to the locant of its nearest double bond. Thus...
114 KB (12,679 words) - 11:51, 2 August 2024
Δ4-androstene-3,11,17-trione). However, the Nomenclature of Steroids recommends the locant of a double bond to be always adjacent to the syllable designating the unsaturation...
82 KB (8,473 words) - 23:42, 9 July 2024
numbered in the name. The IUPAC 2013 Rules however do require an explicit locant for most substituents in a preferred IUPAC name. The substituent name is...
13 KB (1,463 words) - 21:51, 7 October 2023
1039/9781849733069-FP001. ISBN 978-0-85404-182-4. For example, the omission of the locant '1' in 2-chloroethanol, while permissible in general usage, is not allowed...
9 KB (627 words) - 14:40, 25 January 2023
tetranor, etcetera is used. The prefix is preceded by the position number (locant) of the carbon atoms that disappear (for example 2,3-dinor). The original...
10 KB (1,135 words) - 18:47, 27 August 2023
has the retained name 'urea', which is the preferred IUPAC name, with locants N and N′, as shown above the structure below. The systematic name is 'carbonic...
60 KB (6,991 words) - 20:00, 24 July 2024
indicated by a numerical locant immediately preceding the "-yne" suffix, or 'locants' in the case of multiple triple bonds. Locants are chosen so that the...
21 KB (2,694 words) - 15:06, 25 July 2024
Left: The structure of pyrimidine with the locants for ring atoms marked. Right: 5-Fluorouracil, a fluoropyrimidine formally named as 5-fluoro-1H,3H-pyrimidine-2...
2 KB (125 words) - 23:15, 30 March 2024
have been used to distinguish isomers, and 'xylidine' for which numerical locants, such as 2,3-, have been used, are no longer recommended, nor are the corresponding...
6 KB (410 words) - 21:43, 23 April 2023
order: {[( )]}. Locants indicate the position of structural features, e.g., poly(4-chlorostyrene). If the name is one word and has no locants, then the enclosing...
18 KB (1,716 words) - 15:09, 13 February 2024
tropane-ring, with only its tropane locants given. Middle: Cocaine with its numerical substitution position locants. 2′ (6′) = ortho, 3′ (5′) = meta &...
111 KB (5,555 words) - 16:59, 8 June 2024
retain a definite volume but no fixed shape. liquid–liquid extraction (LLE) locant London dispersion forces A type of weak intermolecular force. Contents: ...
171 KB (18,187 words) - 16:16, 23 May 2024
have been used to distinguish isomers, and 'xylidine' for which numerical locants, such as 2,3-, have been used, are no longer recommended, nor are the corresponding...
17 KB (1,729 words) - 19:05, 22 June 2024
compounds is known as the silicon α and β effects, after the corresponding locants. These stabilities occur because of a partial overlap between the C–Si...
11 KB (1,170 words) - 21:01, 11 March 2024
general nomenclature. The structure is substitutable at any position. Locants 2, 3, and 4 are recommended, not o, m, and p. "TOXNET". toxnet.nlm.nih...
9 KB (935 words) - 12:50, 5 February 2024
general nomenclature. The structure is substitutable at any position. Locants 2, 3, and 4 are recommended, not o, m, and p. Haynes, William M., ed. (2016)...
4 KB (266 words) - 16:10, 8 June 2024
multiplicative prefix if there are several heteroatoms of the same type; and locants to indicate the relative positions of the different atoms. Hantzsch–Widman...
8 KB (727 words) - 23:30, 19 March 2024
same. Dimers of phenyltropanes, connected in their dual form using the C2 locant as altered toward a carboxamide structural configuring (in contrast and...
168 KB (5,647 words) - 19:32, 1 June 2024
general nomenclature. The structure is substitutable at any position. Locants 2, 3, and 4 are recommended, not o, m, and p. Haynes, p. 3.116 Haynes,...
4 KB (191 words) - 14:27, 2 May 2024
triplet state is named ethane-1,1,1,2-tetrayl. Ethenylidene (without the -1- locant) or vinylidene, is used, systematically, to refer to the substituent group...
5 KB (497 words) - 21:54, 17 June 2024
along with the locants. Short form: It is usually desirable to shorten the notation by eliminating the anomeric carbon atoms locants, the parentheses...
21 KB (2,602 words) - 19:12, 8 June 2024