Organopalladium chemistry is a branch of organometallic chemistry that deals with organic palladium compounds and their reactions. Palladium is often...
9 KB (1,043 words) - 18:27, 21 March 2024
organomolybdenum chemistry, organotechnetium chemistry, organoruthenium chemistry, organorhodium chemistry, organopalladium chemistry, organosilver chemistry, organocadmium...
31 KB (3,157 words) - 20:03, 24 September 2024
mercury(II) salts. In this regard, organomercury chemistry more closely resembles organopalladium chemistry and contrasts with organocadmium compounds. Electron-rich...
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(Google Books excerpt). In Ei-ichi Negishi (ed.). Handbook of Organopalladium Chemistry for Organic Synthesis. John Wiley & Sons, Inc. ISBN 0-471-31506-0...
11 KB (973 words) - 14:04, 19 April 2024
strength is Pt-C (sp) > Pt-O > Pt-N > Pt-C (sp3). Organoplatinum and organopalladium chemistry are similar, but organoplatinum compounds are more stable and...
10 KB (1,121 words) - 13:42, 26 September 2023
Wacker process (category Organometallic chemistry)
chemical reaction was one of the first homogeneous catalysis with organopalladium chemistry applied on an industrial scale. The Wacker reaction was first...
30 KB (3,872 words) - 18:46, 1 June 2024
(Google Books excerpt). In Ei-ichi Negishi (ed.). Handbook of Organopalladium Chemistry for Organic Synthesis. John Wiley & Sons, Inc. ISBN 0-471-31506-0...
13 KB (1,440 words) - 21:35, 4 September 2024
oxidative addition of palladium to the halide reagent 1 to form the organopalladium intermediate B. Reaction (metathesis) with base gives intermediate...
34 KB (3,845 words) - 17:47, 26 September 2024
(Google Books excerpt). In Ei-ichi Negishi (ed.). Handbook of Organopalladium Chemistry for Organic Synthesis. John Wiley & Sons, Inc. ISBN 0-471-31506-0...
3 KB (208 words) - 20:00, 15 April 2024
List of chemists (category Chemistry-related lists)
Russian chemists Tsuji, J. (November 23, 1999). Perspectives in Organopalladium Chemistry for the 21st Century. Elsevier Science. p. 125. ISBN 0-444-50197-5...
60 KB (7,565 words) - 19:07, 21 September 2024
thus acrylates are ideal. The mechanism of this vinylation involves organopalladium intermediates. The required palladium(0) compound is often generated...
13 KB (1,355 words) - 19:29, 15 December 2023
Cross-coupling reaction (category Organometallic chemistry)
which is frequently selected due to high functional group tolerance. Organopalladium compounds are generally stable towards water and air. Palladium catalysts...
17 KB (1,499 words) - 13:48, 28 July 2024
peroxide: Organoboron compounds also transmetalate easily, especially to organopalladium compounds. In the Suzuki reaction, an aryl- or vinyl-boronic acid couples...
30 KB (2,992 words) - 19:24, 18 August 2024
Herrmann's catalyst (category Organopalladium compounds)
Herrmann's catalyst is an organopalladium compound that is a popular catalyst for the Heck reaction. It is a yellow air-stable solid that is soluble in...
2 KB (177 words) - 17:18, 18 June 2024
Tris(dibenzylideneacetone)dipalladium(0) (category Organopalladium compounds)
Tris(dibenzylideneacetone)dipalladium(0) or [Pd2(dba)3] is an organopalladium compound. The compound is a complex of palladium(0) with dibenzylideneacetone...
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2658J. doi:10.1021/ma802625d. Kotora, M. (2002). Handbook of Organopalladium Chemistry for Organic Synthesis. New York: Wiley Interscience. p. 973....
18 KB (2,163 words) - 05:45, 29 April 2024
Negishi, Ei-ichi; Meijere, Armin de (24 November 2003). Handbook of Organopalladium Chemistry for Organic Synthesis. John Wiley & Sons. p. 2385. ISBN 978-0-471-47381-7...
4 KB (289 words) - 19:36, 28 January 2023
and Catalysis". Higher Oxidation State Organopalladium and Platinum Chemistry. Topics in Organometallic Chemistry. Vol. 35. pp. 129–156. doi:10.1007/978-3-642-17429-2_6...
59 KB (6,283 words) - 17:25, 19 August 2024
Concerted metalation deprotonation (category Organometallic chemistry)
biphenyl, palladium(0), and 2 equivalents of acetic acid through an organopalladium intermediate. Early mechanistic studies found that palladium acetate...
13 KB (1,453 words) - 03:25, 19 August 2024
Tetsuro Murahashi, Hideo Kurosawa "Organopalladium complexes containing palladium/palladium bonds" Coordination Chemistry Reviews 2002, volume 231, pp. 207-228...
2 KB (257 words) - 19:40, 27 October 2022
Allan J. (ed.). Higher Oxidation State Organopalladium and Platinum Chemistry. Topics in Organometallic Chemistry. Vol. 503. Springer Berlin Heidelberg...
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609. Fritz Weber, August Rüttimann "Vitamin K" Ullmann's Encyclopedia Of Industrial Chemistry, 2012, Wiley-VCH, Weinheim. doi:10.1002/14356007.o27_o08...
3 KB (387 words) - 01:08, 28 August 2024
Oxidation state (category Coordination chemistry)
Catalysis" (PDF). Higher Oxidation State Organopalladium and Platinum Chemistry. Topics in Organometallic Chemistry. Vol. 35. pp. 129–156. Bibcode:2011hoso...
45 KB (14,045 words) - 17:32, 4 September 2024
PEPPSI (category Organopalladium compounds)
were presented in 2005 and published in 2006. PEPPSI catalysts are organopalladium complexes containing N-heterocyclic carbene (NHC) ligands. They can...
14 KB (1,406 words) - 10:53, 26 April 2023
Simultaneously, a palladium catalyst reacts with an aryl bromide to give an organopalladium intermediate (Ar'PdB), which undergoes transmetallation to give ArPdAr'...
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professor in 2013. Sanford is best known for her studies of high-valent organopalladium species, particularly those implicated in Pd-catalyzed C–H functionalization...
29 KB (2,626 words) - 11:55, 17 May 2024
Richard F. Heck (category Nobel laureates in Chemistry)
Tachibana, Kazuo (2007). "Site-Specific Functionalization of Proteins by Organopalladium Reactions". ChemBioChem. 8 (2): 232–238. doi:10.1002/cbic.200600432...
17 KB (1,578 words) - 12:49, 16 April 2024
Palladium–NHC complex (category Organopalladium compounds)
In organometallic chemistry, palladium-NHC complexes are a family of organopalladium compounds in which palladium forms a coordination complex with N-heterocyclic...
9 KB (915 words) - 09:34, 26 September 2024
hydrogenation in organic synthesis. Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. pp. 1336–37. ISBN 978-0-08-022057-4...
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indicate competing equilibriums exist between cis- and trans- bis alkyl organopalladium complexes, but that the only productive intermediate is the cis complex...
34 KB (3,954 words) - 20:12, 15 June 2024