Phosphorus sulfides comprise a family of inorganic compounds containing only phosphorus and sulfur. These compounds have the formula P4Sn with n ≤ 10...
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White phosphorus is widely used to make organophosphorus compounds through intermediate phosphorus chlorides and two phosphorus sulfides, phosphorus pentasulfide...
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(empirical) or P4S10 (molecular). This yellow solid is the one of two phosphorus sulfides of commercial value. Samples often appear greenish-gray due to impurities...
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pose the health hazards of white phosphorus. This yellow solid is one of two commercially produced phosphorus sulfides. It is a component of "strike anywhere"...
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Organophosphorus chemistry (redirect from Carbon-phosphorus bond)
thiophosphoryl halides:: 73 R3PO + X3PS → R3P+–O–P+X2–S− + X− Some phosphorus sulfides can undergo a reverse Arbuzov rearrangement to a dialkylthiophosphinate...
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It reduces sulfoxides to sulfides, even at −78 °C. Meanwhile, heating a 1-iodobutane solution of PI3 with red phosphorus causes reduction to P2I4. The...
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(such as dichalcogenoimidodiphosphates). Phosphorus selenides are typically harder to handle that phosphorus sulfides, and compounds in the form PxTey have...
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Thioamides are typically prepared by treating amides with phosphorus sulfides such as phosphorus pentasulfide, a reaction first described in the 1870s. An...
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can abstract the oxygen: thus activated isocyanates effect imines; phosphorus sulfides or activated thioic acids effect the thione, and a wide variety of...
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monovinyl sulfides are known. They can arise by the dehydrohalogenation of -2-haloethyl phenyl sulfides. One example is phenyl vinyl sulfide. Alkyl ketones...
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Arsenic sulfide may refer to: Arsenic trisulfide, As2S3, the mineral orpiment Arsenic pentasulfide, As2S5, similar structure to phosphorus pentasulfide...
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of phosphorus, because phosphorus and phosphorus-based materials do not enter the gaseous phase readily, as the main source of gaseous phosphorus, phosphine...
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Diphosphorus trisulfide (category Sulfides)
Diphosphorus trisulfide (sometimes called phosphorus trisulfide) is a phosphorus sulfide with the formula of P2S3. The substance is highly unstable and...
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convert oxides to sulfides but is also related to corrosion and surface modification. Sulfidation is relevant to the formation of sulfide minerals. A large...
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Many metal and nonmetal sulfides, e.g. aluminium sulfide, phosphorus pentasulfide, silicon disulfide liberate hydrogen sulfide upon exposure to water:...
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Mamoru; Aoki, Masao; Zheng, Xiao-Qi; Noyori, Ryoji (2001). "Oxidation of Sulfides to Sulfoxides and Sulfones with 30% Hydrogen Peroxide under Organic Solvent-...
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Pararealgar (category Sulfide minerals)
analogous pair of isomers is also recognized for the corresponding phosphorus sulfides P4S4. Pararealgar occurs as an alteration product of realgar in stibnite-bearing...
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O → H2O + (MeAs)n These compounds have structures similar to the phosphorus sulfides. Arsenic-arsenic bonds are very weak, and oligomeric arsenic compounds...
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In the carbon-free battery, the SEI stabilized quickly. Lithium phosphorus sulfide chloride forms less-reactive products. Li 6 PS 5 Cl ⟶ Li 2 S + Li...
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Pnictogen (section Phosphorus)
ores with mixed sulfides and oxides are smelted in a blast furnace. Bismuth minerals do occur, in particular in the form of sulfides and oxides, but it...
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produced from chloroethanol and potassium sulfide, and the resulting diol is then treated with phosphorus trichloride: 3 (HOC2H4)2S + 2 PCl3 → 3 (ClC2H4)2S...
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ethers and sulfides are somewhat similar, though the extent to which this is true in practice varies depending on the application. Sulfides are sometimes...
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Match (section Replacement of white phosphorus)
Frenchman Charles Sauria, who substituted white phosphorus for the antimony sulfide. These new phosphorus matches had to be kept in airtight metal boxes...
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Sulfur (section Metal sulfides)
metal sulfides are known, most are prepared by high temperature reactions of the elements. Geoscientists also study the isotopes of metal sulfides in rocks...
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Sulfur compounds (section Metal sulfides)
Although many metal sulfides are known, most are prepared by high temperature reactions of the elements. Sulfide minerals contain the sulfide (S2-) or disulfide...
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"The chlorides of tin and phosphorus were all soluble, and slow decomposition resulted in the formation of the respective sulfides." See also Table 1, wherein...
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Phosphine (redirect from Phosphorus hydride)
heating white phosphorus in an aqueous solution of potash (potassium carbonate). Perhaps because of its strong association with elemental phosphorus, phosphine...
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Iron ore (section Phosphorus)
oxidize the sulfides to sulfuric acid and sulfates, which are water-soluble and leached out. However, historically (at least), iron sulfide (iron pyrite...
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ingestion and elimination. Antimony(III) sulfide is used in the heads of some safety matches. Antimony sulfides help to stabilize the friction coefficient...
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Photoresistor (redirect from Cadmium sulfide photocell)
the device. If a sample of silicon has some of its atoms replaced by phosphorus atoms (impurities), there will be extra electrons available for conduction...
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