Raney nickel /ˈreɪniː ˈnɪkəl/, also called spongy nickel, is a fine-grained solid composed mostly of nickel derived from a nickel–aluminium alloy. Several...
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Thiophene (section Desulfurization by Raney nickel)
chloroethyl species gives 2-vinylthiophene. Desulfurization of thiophene with Raney nickel affords butane. When coupled with the easy 2,5-difunctionalization of...
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imine using a Raney nickel catalyst, a popular heterogeneous catalyst. Partial hydrogenation of a resorcinol derivative using a Raney-Nickel catalyst. Hydrogenation...
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politician and businessman Murray Raney (1885–1966), American mechanical engineer; inventor of Raney nickel Paul Hartley Raney (1892–1917), Canadian fighter...
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dithioacetal structure is then hydrogenolyzed using Raney nickel. Raney nickel is converted irreversibly to nickel sulfide. This method is milder than either the...
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Murray Raney (October 14, 1885 – March 3, 1966) was an American mechanical engineer born in Carrollton, Kentucky. He was the developer of a nickel catalyst...
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reactions. Raney nickel, a finely divided nickel-aluminium alloy, is one common form, though related catalysts are also used, including Raney-type catalysts...
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They are claimed to be more effective hydrogenation catalysts than Raney nickel. These catalysts originate during World War II with the work of a research...
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as: Catalytic hydrogenation using: Raney nickel or palladium-on-carbon, platinum(IV) oxide, or Urushibara nickel. Iron in acidic media. Sodium hydrosulfite...
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Urushibara nickel is a nickel-based hydrogenation catalyst. It is a heterogeneous catalyst, comparable to Raney nickel. Urushibara nickel is however not...
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alumina. Pyrolysis of the resulting material gives forms of Raney nickel and Urushibara nickel. In homogeneous catalysis, the hexahydrate is a precatalyst...
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lithium aluminium hydride (LAH), sodium borohydride,aluminum amalgam or Raney nickel are used in suitable solvents like isopropyl alcohol or tetrahydrofuran...
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amines. Catalysts for the reaction often include group 10 metals such as Raney nickel, palladium black, or platinum dioxide. However, other catalysts, such...
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sorbitol and mannitol are obtained by hydrogenation of sugars, using Raney nickel catalysts. The conversion of glucose and mannose to sorbitol and mannitol...
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Purified xylose is catalytically hydrogenated into xylitol using a Raney nickel catalyst. The conversion changes the sugar (xylose, an aldehyde) into...
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issue is the formation of MIBK and other self-condensation products. Raney nickel was one of the original industrial catalysts, modern catalysts are often...
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form RMgX) Used hydrogenation catalysts such as palladium on carbon or Raney nickel (especially hazardous because of the adsorbed hydrogen) Iron(II) sulfide:...
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R'NH− → RR'NH + NH2− Symmetric secondary amines can be prepared using Raney nickel (2RNH2 → R2NH + NH3). And finally, quaternary ammonium salts can be dealkylated...
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cyclisation. In the above scheme, the reductive cyclisation is effected by Raney nickel and hydrazine. Palladium-on-carbon and hydrogen, stannous chloride, sodium...
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bipyridines. Radical dimerization of pyridine with elemental sodium or Raney nickel selectively yields 4,4'-bipyridine, or 2,2'-bipyridine, which are important...
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Nitrocaine. Finally, the nitro group is reduced by hydrogenation over Raney nickel catalyst. Chloroprocaine Peter DeMarco Procaine blockade "How long does...
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isomaltulose synthase. The isomaltulose is then hydrogenated using a Raney nickel catalyst, producing 1,1-GPM and 1,6-GPS. The product consists of a mixture...
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the triamine bis(hexamethylenetriamine). An alternative process uses Raney nickel as the catalyst and adiponitrile that is diluted with hexamethylenediamine...
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carbon Platinum dioxide Rhodium-platinum oxide Lindlar catalyst Raney nickel Urushibara nickel Nishimura, Shigeo (2001). Handbook of Heterogeneous Catalytic...
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2 CO2 + ... It is prepared by the dehydrogenation of pyridine using Raney nickel: 2 C5H5N → (C5H4N)2 + H2 Unsymmetrically substituted 2,2'-bipyridines...
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catalytic hydrogenation of isobutylacetophenone is performed with either Raney nickel or palladium on carbon to lead into the key-step, the carbonylation of...
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ethylenediamine and acetic acid, followed by treatment with lime, then Raney nickel. 2-Methylimidazole is nitrated to give 2-methyl-4(5)-nitroimidazole (2)...
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4-nitrophenol, which is reduced to 4-aminophenol by hydrogenation over Raney nickel. In another method, nitrobenzene is reduced electrolytically giving 4-aminophenol...
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achieved by dealloying of Nickel-Zinc or Nickel-Aluminium alloys in alkaline solution, commonly referred to as Raney nickel. In cell tests the best performing...
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below. Reduction of nitriles in the synthesis of phenethylamine with Raney nickel catalyst and hydrogen in ammonia: The cracking, isomerisation, and reformation...
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