• Thumbnail for Tert-Butyllithium
    tert-Butyllithium is a chemical compound with the formula (CH3)3CLi. As an organolithium compound, it has applications in organic synthesis since it is...
    11 KB (1,038 words) - 23:38, 13 March 2024
  • nBuLi sec-Butyllithium, abbreviated sec-BuLi or sBuLi, has 2 stereoisomers, but is commonly used as racemate isobutyllithium tert-Butyllithium, abbreviated...
    495 bytes (83 words) - 11:36, 2 December 2016
  • Thumbnail for N-Butyllithium
    n-Butyllithium C4H9Li (abbreviated n-BuLi) is an organolithium reagent. It is widely used as a polymerization initiator in the production of elastomers...
    18 KB (1,856 words) - 04:22, 24 July 2024
  • Thumbnail for Sec-Butyllithium
    "Monomeric organolithium compounds in tetrahydrofuran: tert-butyllithium, sec-butyllithium, supermesityllithium, mesityllithium, and phenyllithium....
    8 KB (642 words) - 16:37, 19 December 2023
  • Thumbnail for 2,6-Di-tert-butylpyridine
    Golob "Alkylation of pyridine with tert-butyllithium. Convenient syntheses of 2,6-di-tert-butylpyridine and 2,4,6-tri-tert-butylpyridine" J. Org. Chem. 1971...
    3 KB (250 words) - 06:34, 31 August 2023
  • Thumbnail for Organolithium reagent
    octahedron structures. For example, methyllithium, ethyllithium and tert-butyllithium all exist in the tetramer [RLi]4. Methyllithium exists as tetramers...
    55 KB (5,971 words) - 20:35, 22 July 2024
  • plastic syringe she was using to transfer the pyrophoric reagent tert-butyllithium from one sealed container to another came apart, spilling the chemical...
    6 KB (611 words) - 05:46, 13 February 2024
  • Thumbnail for N-tert-Butylbenzenesulfinimidoyl chloride
    benzaldehyde with n-butyllithium and N-tert-butylbenzenesulfinimidoyl chloride in THF gives 1-phenyl-1-pentanone in good yield. N-tert-Butylbenzenesulfinimidoyl...
    8 KB (615 words) - 13:50, 26 August 2024
  • aluminium, gallium, indium, zinc, cadmium, etc.) Triethylborane tert-Butyllithium Diethylzinc Triethylaluminium Linseed oil; rags soaked in linseed...
    9 KB (813 words) - 18:40, 29 June 2024
  • Thumbnail for Schlenk line
    T. (13 June 2018). "Improved Safety during Transfer of Pyrophoric tert-Butyllithium from Flasks with Protective Seals". Organic Process Research & Development...
    11 KB (1,311 words) - 16:46, 27 June 2024
  • Thumbnail for Dichloromethane
    participate in reactions with certain strong nucleophiles however. Tert-butyllithium deprotonates DCM: H2CCl2 + RLi → HCCl2Li + RH Methyllithium reacts...
    29 KB (2,592 words) - 14:25, 17 July 2024
  • Thumbnail for Lithium
    aluminium hydride (LiAlH4), lithium triethylborohydride, n-butyllithium and tert-butyllithium. Metallic lithium and its complex hydrides, such as lithium...
    141 KB (13,796 words) - 01:03, 27 September 2024
  • Thumbnail for Tenofovir disoproxil
    hydroxyl group is reacted with a phosphonic acid derivative, using tert-butyllithium as base to ensure selective O-alkylation, with the formation of an...
    26 KB (2,369 words) - 04:54, 19 August 2024
  • of vinyllithium by lithium halogen exchange from vinyl bromide and tert-butyllithium. The low temperatures suppress the reaction of the strongly basic...
    2 KB (198 words) - 23:44, 10 March 2024
  • 1,3-propanedithiol. Sulfide 3 is first silylated by reaction with tert-butyllithium and then trimethylsilyl chloride 4 and then the second acyl proton...
    14 KB (1,784 words) - 14:56, 20 August 2024
  • Thumbnail for Directed ortho metalation
    n-butyllithium and (S)-tert-butyl tert-butanethiosulfinate to enantiopure an sulfoxide followed by DOM reaction initiated again by n-butyllithium with...
    9 KB (1,041 words) - 18:42, 12 September 2024
  • Thumbnail for 1-Fluoronaphthalene
    which is insoluble in water. 1-Fluoronaphthalene was used for the tert-butyllithium-mediated synthesis of 6-substituted phenanthridines. It has also been...
    3 KB (196 words) - 18:40, 8 November 2022
  • formula C4H9Li (molar mass: 64.06 g/mol) may refer to: n-Butyllithium sec-Butyllithium tert-Butyllithium This set index page lists chemical structure articles...
    347 bytes (54 words) - 14:41, 6 July 2019
  • reacts with butyllithium to give 1,1′-dilithioferrocene, which is a versatile nucleophile. In combination with butyllithiium, tert-butyllithium produces...
    53 KB (5,136 words) - 16:12, 20 August 2024
  • Buffer solution Bunsen burner Burette Burmite Butane n-Butyllithium tert-Butyllithium sec-Butyllithium Bytownite cadmium Calamine Calcite Calcium Calcium...
    23 KB (1,949 words) - 12:24, 30 July 2024
  • T. (13 June 2018). "Improved Safety during Transfer of Pyrophoric tert-Butyllithium from Flasks with Protective Seals". Organic Process Research & Development...
    16 KB (1,929 words) - 00:55, 2 April 2024
  • Thumbnail for Di-tert-butylzinc
    N-dimethyl-3-iodoaniline from N,N-dimethylaniline. Di-tert-butylzinc is obtained from the reaction between tert-butyllithium and zinc chloride. 2 (CH3)3CLi + ZnCl2 →...
    3 KB (135 words) - 12:22, 11 December 2023
  • Thumbnail for Holton Taxol total synthesis
    3.1]undecane AB ring system of Taxol. Reaction of epoxide 1 with tert-butyllithium removed the acidic α-epoxide proton, leading to an elimination reaction...
    16 KB (1,478 words) - 18:34, 27 September 2023
  • Thumbnail for Persistent carbene
    types of salts, providing that not too much LiOH is present in the n-butyllithium used to make the lithium amide. Titration of lithium amide can be used...
    62 KB (6,933 words) - 11:59, 13 August 2024
  • 2,2,4,4-Tetramethyl-3-t-butyl-pentane-3-ol (category Tert-butyl compounds)
    (81%) by addition of tert-butyllithium to hexamethylacetone. Z. Malarski (1974). "Solid rotator phases in 2,2,4,4-tetramethyl-3-tert-butyl-3-pentanol (t-Bu3COH)"...
    4 KB (375 words) - 21:47, 22 February 2024
  • course of these studies, the kinetics of the rate-determining step of tert-butyllithium dissociation from tetramer to a dimer were analyzed. Using 7Li nuclear...
    19 KB (2,095 words) - 05:58, 27 May 2024
  • with one equivalent of butyllithium mainly affords dilithioferrocene. Monolithioferrocene can be obtained using tert-butyllithium. Butler, Ian R.; Cullen...
    4 KB (323 words) - 13:53, 11 January 2024
  • polymer chain. In Tagami's article, PPA was prepared by utilizing tert-butyllithium as an initiator and acetic anhydride as a terminator. However, the...
    40 KB (4,687 words) - 02:54, 20 July 2024
  • Thumbnail for Tetralithiomethane
    by the lithiation of tetrakis(chloromercurio)methane (C(HgCl)4) by tert-butyllithium. It can also be produced by the reaction of lithium metal and carbon...
    4 KB (300 words) - 06:54, 30 July 2024
  • mixture called Schlosser's base is produced by combining n-butyllithium and potassium tert-butoxide in a one-to-one ratio. The high reactivity of Schlosser's...
    3 KB (372 words) - 09:06, 12 April 2020